Foundations of Materials Science and Engineering
6th Edition
ISBN: 9781259696558
Author: SMITH
Publisher: MCG
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Chapter 5.7, Problem 16AAP
To determine
The time necessary to increase the carbon content.
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An FCC iron-carbon alloy initially containing 0.35 wt% C is exposed to an oxygen-rich and virtually carbon-free atmosphere at 1400 K (1127°C). Under these circumstances the carbon diffuses from the alloy and reacts at the surface
with the oxygen in the atmosphere; that is, the carbon concentration at the surface position is maintained essentially at 0 wt% C. (This process of carbon depletion is termed decarburization.) At what position will the carbon concentration he 0.15 wt% after a 10-h treatment? The value of D at 1400 K is 6.9 x 10m²'s
Determine the carburizing time necessary to achieve a carbon concentration of 0.50 wt% at a position 3.1 mm into an iron-carbon
alloy that initially contains 0.12 wt% C. The surface concentration is to be maintained at 1.2 wt% C, and the treatment is to be
conducted at 1080°C. Assume that Do = 5.8 x 10-5 m²/s and Qd = 156 kJ/mol. The table Tabulation Error Function Values may be
useful.
Decarburization of a steel occurs when carbon diffuses from the steel to the surface and enters the atmosphere. How long will it take for a 0.6 % C steel surface to decarburize below 0.1 % C for a depth of 2 mm if the FCC steel is held at 1250 °C in an atmosphere containing zero carbon? I need this question's answer. It's important for me.
Chapter 5 Solutions
Foundations of Materials Science and Engineering
Ch. 5.7 - Prob. 1KCPCh. 5.7 - Write an equation for the number of vacancies...Ch. 5.7 - Prob. 3KCPCh. 5.7 - Prob. 4KCPCh. 5.7 - Describe the substitutional and interstitial...Ch. 5.7 - Prob. 6KCPCh. 5.7 - What factors affect the diffusion rate in solid...Ch. 5.7 - Write the equation for Ficks second law of...Ch. 5.7 - Prob. 9KCPCh. 5.7 - Prob. 10KCP
Ch. 5.7 - (a) Calculate the equilibrium concentration of...Ch. 5.7 - Prob. 12AAPCh. 5.7 - Determine the diffusion flux of zinc atoms in a...Ch. 5.7 - The diffusion flux of copper solute atoms in...Ch. 5.7 - Prob. 15AAPCh. 5.7 - Prob. 16AAPCh. 5.7 - Prob. 17AAPCh. 5.7 - A gear made of 1020 steel (0.20 wt% C) is to be...Ch. 5.7 - Prob. 19AAPCh. 5.7 - The surface of a steel gear made of 1020 steel...Ch. 5.7 - Prob. 21AAPCh. 5.7 - If boron is diffused into a thick slice of silicon...Ch. 5.7 - Prob. 23AAPCh. 5.7 - Prob. 24AAPCh. 5.7 - Prob. 25AAPCh. 5.7 - Prob. 26AAPCh. 5.7 - Prob. 27AAPCh. 5.7 - Prob. 28AAPCh. 5.7 - Prob. 29AAPCh. 5.7 - Prob. 30AAPCh. 5.7 - The diffusivity of copper atoms in the aluminum...Ch. 5.7 - Prob. 32AAPCh. 5.7 - Prob. 33SEPCh. 5.7 - Prob. 34SEPCh. 5.7 - Prob. 37SEPCh. 5.7 - Prob. 38SEPCh. 5.7 - The activation energy of nickel atoms in FCC iron...Ch. 5.7 - Prob. 40SEPCh. 5.7 - The self-diffusion of iron atoms in BCC iron is...Ch. 5.7 - Would you expect the diffusion rate of copper...Ch. 5.7 - Would you expect the diffusion rate of copper...Ch. 5.7 - Prob. 44SEPCh. 5.7 - Prob. 45SEPCh. 5.7 - Prob. 46SEPCh. 5.7 - Prob. 47SEPCh. 5.7 - Prob. 48SEPCh. 5.7 - Prob. 49SEPCh. 5.7 - Prob. 50SEP
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- Determine the carburizing time necessary to achieve a carbon concentration of 0.50 wt% at a position 1.2 mm into an iron-carbon alloy that initially contains 0.18 wt% C. The surface concentration is to be maintained at 1.1 wt% C, and the treatment is to be conducted at 1200°C. Assume that Do 6.5 x 10-5 m2/s and Qd = 168 kJ/mol. The following table may be useful. %3D Table 5.1 Tabulation of Error Function Values erf(z) erf(z) erf(z) 0.55 0.5633 1.3 0.9340 0.0282 0.0564 0.025 0.60 0.6039 1.4 0.9523 0.05 0.10 0.65 0.70 0.75 0.6420 1.5 0.9661 0.1125 0.6778 1.6 0.9763 0.15 0.1680 0.7112 1.7 0.9838 0.20 0.2227 0.80 0.7421 1.8 0.9891 0.85 0.90 0.25 0.2763 0.7707 1.9 0.9928 0.9953 0.9981 0.30 0.3286 0.7970 2.0 0.35 0.3794 0.95 0.8209 2.2 0.8427 0.8802 0.40 0.4284 1.0 2.4 0.9993 0.45 0.4755 1.1 2.6 0.9998 0.50 0.5205 1.2 0.9103 2.8 0.9999arrow_forwardGiven that a component is made of 0.1 wt.%C steel is carburized by introducing 1.0 wt.% carbon at its surface at 980ºC. Calculate the carbon content at 0.5 mm below the surface of this component after 1 hour.Do= 0.2 cm^2/s and Qd=40,000 cal/mol.arrow_forward•You are case-hardening a tool made of BCC (α) iron in the presence of a carbonaceous material. A heat treatment at 600 oC for 100 minutes results in a carbon concentration of 0.75 wt% at a position 0.5mm below the surface. How long would it take to obtain the same concentration at the same position if the heat treatment were conducted at 900 oC? x12/D1t1= x22/D2t2 Arrhenius equation: D=D0e^(〖-Qd〗∕RT) Qd = Activation energy of diffusion D0 = Pre-exponential diffusion factor R = gas constant = 8.314 J/(mol*K) Use the Arrhenius equation to calculate D1 and D2. Calculate the time to satisfy the problem statement.arrow_forward
- In a binary Fe-Fe3C system, what is a transformation that occurs when cooling an austenistic mixture of 2% C by weight from 1100°C to below the eutectoid temperature? What is the microstructure, and how is it formed? What are the total and partial phases? Given:Eutectoid temperature=723°C; Eutectoid concentration=0.76% C; Limit concentration of ferrite=0.022%; Limiting concentration of cementite: 6.7%.arrow_forwardA mechanism for hardening steel is called carburization. To achieve this process, the piece of steel is exposed to an atmosphere rich in hydrocarbon such as methane (CH4). Consider a steel with a carbide concentration of 0.25wt%, which must be treated at 950˚C. If the carbon concentration at the surface is suddenly increased to 1.20wt%, how long does it take for a penetration of 0.5mm from the surface to reach a concentration of 0.80wt%? . The diffusion coefficient for carbon in iron at this temperature is 1.6 x 10-11 m2s-1. Assume that the piece of steel is semi-finite. Use the table below.arrow_forwardProblem 3 An FCC iron-carbon alloy initially containing 0.35 wt% C is exposed to an oxygen-rich and virtually carbon- free atmosphere at 1400 K (1127 °C). Under these circumstances the carbon diffuses from the alloy and reacts at the surface with the oxygen in the atmosphere; that is, the carbon concentration at the surface position is maintained essentially at 0 wt% C. (This process of carbon depletion is termed decarburization.) At what position will the carbon concentration be 0.15 wt% after a 10-h treatment? The value of D at 1400 K is 6.9 x 10¹¹ m²/s.arrow_forward
- An FCC iron-carbon alloy initially containing 0.20 wt% C is carburized at an elevated temperature and in an atmosphere wherein the surface carbon concentration is maintained at 1.0 wt%. If after 51 h the concentration of carbon is 0.35 wt% at a position 3.5 mm below the surface, determine the temperature at which the treatment was carried out. You will need to use data in the two tables below to solve this problem. Diffusing Species Fe Table 5.1 Tabulation of Error Function Values erf(z) 0 0.0282 0.0564 0.1125 Fe Z 0 0.025 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 Table 5.2 A Tabulation of Diffusion Data Host Metal a-Fe (BCC) y-Fe (FCC) a-Fe 0.1680 0.2227 0.2763 0.3286 0.3794 y-Fe 0.4284 0.4755 0.5205 Z 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.0 1.1 1.2 Do(m²/s) 2.8 x 10-4 5.0 x 10-5 6.2 x 10-7 2.3 x 10-5 erf(z) 0.5633 0.6039 0.6420 0.6778 0.7112 0.7421 0.7707 0.7970 0.8209 0.8427 0.8802 0.9103 80 284 Z 1.3 1.4 1.5 1.6 1.7 1.8 1.9 Activation Energy Qa kJ/mol eVlatom 251…arrow_forwardAn FCC iron-carbon alloy initially containing 0.20 wt% C is carburized at an elevated temperature and in an atmosphere that gives a surface carbon concentration constant at 1.0 wt%. If after 49.5 h, the concentration of carbon is 0.35 wt% at a position 4.0 mm below the surface, determine the temperature at which the treatment was carried out.arrow_forwardAn iron-carbon alloy initially containing 0.268 wt% C is exposed to an oxygen-rich and virtually carbon-free atmosphere at 1040°C. Under these circumstances the carbon diffuses from the alloy and reacts at the surface with the oxygen in the atmosphere; that is, the carbon concentration at the surface position is maintained essentially at 0.0 wt% C. At what position will the carbon concentration be 0.201 wt% after a 7 h treatment? The value of D at 1040°C is 2.5 × 10-¹1 m²/s. erf(z) erf(z) 0.55 0.5633 1.3 0.025 0.0282 0.60 0.6039 1.4 0.9523 0.0564 0.65 0.6420 1.5 Z 0.00 0.05 0.15 0.0000 0.10 0.1125 0.70 0.6778 0.20 Z 0.1680 0.75 0.7112 1.7 0.2227 0.80 0.7421 1.8 0.45 0.4755 1.1 0.50 0.5205 Z 1.6 1.2 0.9103 erf(z) 0.9340 2.8 0.9661 0.25 0.2763 0.85 0.7707 1.9 0.9928 0.30 0.3286 0.90 0.7970 2.0 0.9953 0.35 0.3794 0.95 0.8209 2.2 0.40 0.4284 1.0 0.8427 2.4 0.9763 0.9838 0.9891 0.9981 0.8802 2.6 0.9998 0.9993 0.9999arrow_forward
- An iron-carbon alloy initially containing 0.240 wt% C is exposed to an oxygen-rich and virtually carbon-free atmosphere at 1100°C. Under these circumstances the carbon diffuses from the alloy and reacts at the surface with the oxygen in the atmosphere; that is, the carbon concentration at the surface position is maintained essentially at 0.0 wt% C. At what position will the carbon concentration be 0.180 wt% after a 7 h treatment? The value of D at 1100°C is 3.7 × 10-11 m2/s.arrow_forward(c) A 1020 steel gear is carburized at 927°C and gives the surface carbon concentration maintained at 1.2 wt%. After 8 hours, the concentration of carbon is 0.4 wt%. Note: D (C in y iron) at 927°C = 1.28 × 10*1" m²/s. Determine the depth of the carbon diffuse to the gear steel after 8 hours. (d) State the importance of case hardening in gear steel components in the steel metal industry.arrow_forwardAn FCC iron–carbon alloy initially containing 0.25wt% C is carburized at an elevated temperature and in an atmosphere wherein thesurface carbon concentration is maintained at 1.0 wt%. If after 55.0 h the concentrationof carbon is 0.35 wt% at a position 5.0 mm below the surface, determine thetemperature at which the treatment was carried out.arrow_forward
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