Videos
Calculate w, q,
Want to see the full answer?
Check out a sample textbook solution
Chapter 3 Solutions
Thermodynamics, Statistical Thermodynamics, & Kinetics
- What is the sign of the standard Gibbs free-energy change at low temperatures and at high temperatures for the explosive decomposition of TNT? Use your knowledge of TNT and the chemical equation, particularly the phases, to answer this question. (Thermodynamic data for TNT are not in Appendix G.) 2C7H5N3O6(s) 3N2(g) + 5H2O() + 7C(s) + 7CO(g)arrow_forwardWhich of the following quantities can be taken to be independent of temperature? independent of pressure? (a) H for a reaction (b) S for a reaction (c) G for a reaction (d) S for a substancearrow_forwardCalculate the standard Gibbs free-energy change when SO3 forms from SO2 and O2 at 298 K. Why is sulfur trioxide an important substance to study? (Hint: What happens when it combines with water?)arrow_forward
- Calculate the enthalpy of vaporization of SO2 at –25°C if the same at its boiling point (i.e. –10°C) be 5950 cal mol–1. Given for SO2, molar heat capacities in liquid and vapor phase are 206 cal K–1 mol–1 and 9.3 cal K–1 mol–1 respectively.arrow_forwarda chemist carefully measure the amount of heat needed to raise the temperature of a 0.60 kg sample of a pure substance from 47.3 c tp 53.3c. the experiment shows that 15. kj of heat are needed. what can the chemist report for the specific heat capacity of the substance? round to 2 sig figs.arrow_forwardCalculate ΔS (for the system) when the state of 2.00 mol of gas molecules, for which Cp,m = R, is changed from 25 °C and 1.50 atm to 135 °C and 7.00 atm.arrow_forward
- Estimate the enthalpy of vaporization of water at 100 °c from its value at 25 °c, 44.01 kJ mol-1, given the constant pressure molar heat capacities of 75.29 J K-1 mol-1 and 33.58 J K-1 mol-1 for liquid and gas, respectively.arrow_forwardCalculate the change in internal energy (in kcal) for the reaction Cl2(g) + 7/2 O2(g) = Cl₂O7(g) at 25 °C, given that the gases are ideal. The enthalpy, AH, for the formation of Cl₂O7(g) is 63.4 kcal mol- ¹ at 25 °C.arrow_forwardThe French chemists, Pierre L. Dulong and Alexis T. Petit, noted in 1819 that the molar heat capacity of many solids at ordinary temperatures is proportional to the number of atoms per formula unit of the solid. They quantified their observations in what is known as Dulong and Petit's rule, which says that the molar heat capacity, Cp, of a solid can be expressed as Cp = N. 3R where N is the number of atoms per formula unit and R is the universal gas constant. -1 The observed heat capacity per gram of a compound containing rubidium and oxygen is 0.64 J · K¯¹ . g¯¹. Use Dulong and Petit's rule to determine the empirical formula of the compound. empirical formula: Rb5O Incorrectarrow_forward
- The French chemists, Pierre L. Dulong and Alexis T. Petit, noted in 1819 that the molar heat capacity of many solids at ordinary temperatures is proportional to the number of atoms per formula unit of the solid. They quantified their observations in what is known as Dulong and Petit's rule, which says that the molar heat capacity, Cp, of a solid can be expressed as Cp = N. 3R where N is the number of atoms per formula unit and R is the universal gas constant. The observed heat capacity per gram of a compound containing rubidium and oxygen is 0.64 J · K¯¹ · g¯¹. Use Dulong and Petit's rule to determine the empirical formula of the compound. empirical formula: Rb5O Incorrectarrow_forwardFor the reaction C2H5OH(l) + 3 O2(g) → 2 CO2(g) + 3 H2O(g), ΔrU⦵ = −1373 kJ mol−1 at 298 K. Calculate ΔrH⦵.arrow_forwardLithium bromide has several applications, including air-conditioning systems, organic synthesis, and early 20th century sedatives. Lithium bromide vapour dissociates according to LiBr(g) →Li(g) + ½ Br2(g). At what temperature does the partial pressure of Li reach the value of 105 atm when the gas is heated at a constant total pressure of 1 atm? The expression for Gibbs free energy is AG (J) = 333,900-42.09T.arrow_forward
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co