Thermodynamics, Statistical Thermodynamics, & Kinetics
Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321766182
Author: Thomas Engel, Philip Reid
Publisher: Prentice Hall
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Chapter 3, Problem 3.2NP
Interpretation Introduction

Interpretation:

The expression ( δCvδT )T for the Vander Waals gas needs to be proved equal to zero.

Concept Introduction:

The First Law of Thermodynamics explains that heat is a type of thermodynamic process and a form of energy, thus, it follows the principle of conservation of energy. According to this, heat energy can’t be created or destroyed it can be transformed from one form to another.

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2. Evaluate the following integrals. ● -5 dx 5x • S√1 + x dx 3. The pressure of one mole of a van der Waals gas is a function of volume and temperature. Determine if dP is an exact or inexact differential. P ---- RT V-b a V2
Given A ≡ U – TS, derive the corresponding Maxwell relation.
(*), (*): P Use the Euler and reciprocal relations to show that it is equivalent to Cp - Cy = T Ср - Cv = −T. Сү = -Т. Әр ат av 2 T (1) (2) Use this expression to evaluate Cр - Cv for (1) an ideal gas, and (2) for a van der Waals gas.

Chapter 3 Solutions

Thermodynamics, Statistical Thermodynamics, & Kinetics

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