Thermodynamics, Statistical Thermodynamics, & Kinetics
Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321766182
Author: Thomas Engel, Philip Reid
Publisher: Prentice Hall
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Chapter 3, Problem 3.34NP
Interpretation Introduction

Interpretation:

The equation ( P V)T=1kV needs to be derived from basic equation and definitions.

Concept Introduction :

In thermodynamics, a physical property is any property which is measurable, and whose value defines a state of a physical system.

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From the following data determined at 298 K, determine (a) A, H and A₁U for reaction (4) at 298 K; (b) AfH for HI(g) and H₂O(g) at 298 K. Assume ideal gas behavior when necessary. (1) H₂(g) + I2(g) → 2 HI(g) (2) 2H₂(g) + O₂(g) → 2H₂O (g) (3) 1₂ (s)→ I2(g) (4) 4HI(g) + O₂(g) → 21₂(g) + 2H₂O(g) ΔΗΘ = +52.96 kJ mol-¹ A₂H = -483.64 kJ mol-1 A₂H = +62.44 kJ mol-¹
At 298 K and 1 atm, the value of n for chlorine gas is 132 micro Pascal. Calculate the value of o for Cl2. Determine the value of k for chlorine gas under the same P and T conditions.
From the following data, determine A;H© for diborane, B2H6(g), at 298 K: (1) B,H(g) + 3 O2(g)→ B2O3(s) + 3 H2O(g) A,H© =-1941 kJ mol (2) 2 B(s) + 3/2 O2(g)→ B2O3(S) A,H© =-2368 kJ mol· (3) H2(g) + 1/2 O2(g) → H2O(g) A„H© = -241.8 kJ mol-

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Thermodynamics, Statistical Thermodynamics, & Kinetics

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