Thermodynamics, Statistical Thermodynamics, & Kinetics
Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321766182
Author: Thomas Engel, Philip Reid
Publisher: Prentice Hall
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Chapter 3, Problem 3.13NP
Interpretation Introduction

Interpretation:

From equation Cp= Cv+ TV(β2/K)  , the relation between Cp − Cv for an ideal gas needs to be identified.

Concept Introduction :

The relationship between Cp and Cv with β and K

is represented as follows:

Cp= Cv+ TV(β2/κ) 

Here, Cp is the specific heat capacity at constant pressure, Cv is the specific heat capacity at constant volume, T is temperature, V is volume, β is the coefficient of volumetric thermal expansion at constant pressure.

and κ is isothermal compressibility.

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the ionic compound L2O3(s) is the ionic compound formed from oxygen and a metal with the form L(s) at 1.00 bar and 298 K. (a) Draw the Lewis structure for L2O3. Assume that all the valence electrons from L are required. (b) Use the following information to determine the enthalpy of formation for L2O3(s). Express your answer in kJZ(mol L2O3(s)). Lattice energy for L2O3(s) = -14836 kJ mol1 AHsub for L(s) = 358 kJ mol 1 First ionization energy for L(g) = 577 kJ mol 1 Second ionization energy for L(g) = 1794 kJ mol 1 Third ionization energy for L(g) = 3820 kJ mol 1 Bond dissociation energy for O2(g) = 498 kJ mol 1 %3D First electron affinity for O = -141 kJ mol 1 Second electron affinity for O = 744 kJ mol 1
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Chapter 3 Solutions

Thermodynamics, Statistical Thermodynamics, & Kinetics

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