Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321766182
Author: Thomas Engel, Philip Reid
Publisher: Prentice Hall
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Chapter 3, Problem 3.13CP
Interpretation Introduction
Interpretation:The reason for equation
Concept Introduction:
Different thermodynamic properties like enthalpy, entropy, free energy etc. are used to define different properties like volume, pressure and heat capacity.
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Thermodynamics, Statistical Thermodynamics, & Kinetics
Ch. 3 - Prob. 3.1CPCh. 3 - Prob. 3.2CPCh. 3 - Prob. 3.3CPCh. 3 - Prob. 3.4CPCh. 3 - Why can qv be equated with a state function if q...Ch. 3 - Prob. 3.6CPCh. 3 - Prob. 3.7CPCh. 3 - Prob. 3.8CPCh. 3 - Prob. 3.9CPCh. 3 - Why is qv=U only for a constant volume process? Is...
Ch. 3 - Prob. 3.11CPCh. 3 - Why are q and w not state functions?Ch. 3 - Prob. 3.13CPCh. 3 - What is the relationship between a state function...Ch. 3 - Prob. 3.15CPCh. 3 - Is the following statement always, never, or...Ch. 3 - Is the following statement always, never, or...Ch. 3 - Prob. 3.18CPCh. 3 - Prob. 3.19CPCh. 3 - Is the expression UV=T2T1CVdT=nT1T2CV,mdT only...Ch. 3 - Prob. 3.1NPCh. 3 - Prob. 3.2NPCh. 3 - Prob. 3.3NPCh. 3 - Prob. 3.4NPCh. 3 - Prob. 3.5NPCh. 3 - Prob. 3.6NPCh. 3 - Integrate the expression =1/VV/TP assuming that ...Ch. 3 - Prob. 3.8NPCh. 3 - Prob. 3.9NPCh. 3 - Prob. 3.10NPCh. 3 - Prob. 3.11NPCh. 3 - Calculate w, q, H, and U for the process in which...Ch. 3 - Prob. 3.13NPCh. 3 - Prob. 3.14NPCh. 3 - Prob. 3.15NPCh. 3 - Prob. 3.16NPCh. 3 - Prob. 3.17NPCh. 3 - Prob. 3.18NPCh. 3 - Prob. 3.19NPCh. 3 - Prob. 3.20NPCh. 3 - Prob. 3.21NPCh. 3 - Prob. 3.22NPCh. 3 - Derive the following relation, UVmT=3a2TVmVm+b for...Ch. 3 - Prob. 3.24NPCh. 3 - Prob. 3.25NPCh. 3 - Prob. 3.26NPCh. 3 - Prob. 3.27NPCh. 3 - Prob. 3.28NPCh. 3 - Prob. 3.29NPCh. 3 - Prob. 3.30NPCh. 3 - Prob. 3.31NPCh. 3 - Prob. 3.32NPCh. 3 - Prob. 3.33NPCh. 3 - Prob. 3.34NPCh. 3 - Derive the equation H/TV=CV+V/k from basic...Ch. 3 - Prob. 3.36NPCh. 3 - Prob. 3.37NPCh. 3 - Show that CVVT=T2PT2VCh. 3 - Prob. 3.39NP
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- Use the data in Table 2.2 to determine Hp T for Ar at 0C and 1atm. Make any reasonable assumptions necessary.arrow_forwardUse the two appropriate values of R to determine a conversion between L. atm and J.arrow_forwardConsider 2.00 moles of an ideal gas that are taken from state A (PA = 2.00 atm, vA = 10.0 L) to state B (PB = 1.00 attn, VB = 30.0 L) by two different pathways: These pathways are summarized on the following graph of P versus V: Calculate the work (in units of J) associated with the two pathways. Is work a state function? Explain.arrow_forward
- Assume that 1.20 g of benzoicacid, C6H5COOH, is burned in a porcelain dish exposed to the air.If 31, 723 J of energy is givenoff andthe surrounding temperature is 24.6C, calculate q, w, H,and U. Compare your answers to those from the previousproblem.arrow_forwardBenzoic acid, C6H5COOH, is a common standard used in bomb calorimeters, which maintain a constant volume. If 1.20 g of benzoic acid gives off 31, 723 J of energy when burned in the presence of excess oxygen and in a water bath having a temperature of 24.6 C, calculate q, w, H, and U for the reaction.arrow_forwardWhat is the change in internal energy when a gas contracts from 377mL to 119mLundera pressure of 1550 torr, whileat the same time being cooled by removing 124.0J ofheat energy?arrow_forward
- What are the two ways that a final chemical state of a system can be more probable than its initial state?arrow_forwardThe following are values of heat capacity for nitrogen gas; Temp K Cv J/mol. K 300 20.8 400 20.9 500 21.2 600 21.8 700 22.4 800 23.1 900 23.7 1000 24.3 1100 24.9 Using the general formula Cv = A BT C/T2, find values of A, B, and C that fit the given data.arrow_forwardFor the reaction BaCO3(s) BaO(s) + CO2(g), rG = +219.7 kJ/mol-rxn. Using this value and other data available in Appendix L, calculate the value of fG for BaCO3(s).arrow_forward
- In the 1880s, Frederick Trouton noted that the enthalpy of vaporization of 1 mol pure liquid is approximately 88 times the boiling point, Tb, of the liquid on the Kelvin scale. This relationship is called Troutons rule and is represented by the thermochemical equation liquid gas H = 88 Tb, joules Combined with an empirical formula from chemical analysis, Troutons rule can be used to find the molecular formula of a compound, as illustrated here. A compound that contains only carbon and hydrogen is 85.6% C and 14.4% H. Its enthalpy of vaporization is 389 J/g, and it boils at a temperature of 322 K. (a) What is the empirical formula of this compound? (b) Use Troutons rule to calculate the approximate enthalpy or vaporization or one mole of the compound. Combine the enthalpy of vaporization per mole with that same quantity per gram to obtain an approximate molar mass of the compound. (c) Use the results of parts (a) and (b) to find the molecular formula of this compound. Remember that the molecular mass must be exactly a whole-number multiple of the empirical formula mass, so considerable rounding may be needed.arrow_forwardIf the heat capacity varies withtemperature, abetter form ofequation 2.9 isto solve q=TiTfnCT-t A 50.0-g sample of white phosphorus is heated from 298 K to 350K. If its molar heat capacity is CT- = 56.990.1202T J/mol.K, how much heat is needed?arrow_forwardDetermine an expression for V/T p, n in terms of and . Does the sign on the expression make sense in terms of what you know happens to volume as temperature changes?arrow_forward
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