Thermodynamics, Statistical Thermodynamics, & Kinetics
Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321766182
Author: Thomas Engel, Philip Reid
Publisher: Prentice Hall
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Chapter 3, Problem 3.31NP
Interpretation Introduction

Interpretation:

The ideal gas law should be used to obtain the three functions P = f (V, T), V = g (P, T), and T = h (P, V). This is to be proved that cyclic rule (P/V)T(V/T)P(T/P)V=1.

Concept Introduction :

The ideal gas law is,

PV = nRT

Here,

P = pressure of the gas

R = gas constant

T = temperature

V = molar volume

n = number of moles

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2.00-mol of a monatomic ideal gas goes from State A to State D via the path A→B→C→D:   State A PA=13.0atm, VA=11.50L State B PB=13.0atm, VB=6.00L State C PC=21.5atm, VC=6.00L State D PD=21.5atm, VD=21.50L Assume that the external pressure is constant during each step and equals the final pressure of the gas for that step. Calculate q for this process. Calculate w for this process. Calculate ΔE for this process Calculate ΔH for this process.
2.00-mol of a monatomic ideal gas goes from State A to State D via the path A- > B-> C-> D: State A PA = 11.0atm, VA = 13.50L State B PB = 11.0atm, VB = 6.00L State C PC = 25.0atm, VC = 6.00L State D PD = 25.0atm, VD = 20.50L Assume that the external pressure is constant during each step and equals the final pressure of the gas for that step. Calculate q for this process.
Calculate V−1(∂V/∂T)p,n for an ideal gas?

Chapter 3 Solutions

Thermodynamics, Statistical Thermodynamics, & Kinetics

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