Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 7, Problem 13CTQ
Interpretation Introduction
Interpretation: The cyclic alkane which is most commonly found in nature needs to be determined and explained.
Concept Introduction: The stability of the cyclic alkane depends on the ring strain energy. For cyclic
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1) In this problem, you will compare Lewis/VSEPR theory and Covalent Bond theory to
experimental data. The experimental photoelectron data for Ne, HF, H.O, NH,, and CH. are
shown below. Photoelectron spectroscopy measures the filled Orbitals of a molecule. For
each molecule, draw the structure using Lewis formalisms and give the geometry using
VSEPR structure. Answer questions regarding Lewis/VSEPR prediction using this structure
combined with your assigned point group for the structure.
10
18
NH3
CH₂
H₂O
Ne
26
HF
34
Ionisation energy (eV)
Neon
a) Draw the Lewis/VSEPR structure for Ne.
42
b) How many separate electron energy levels does the Lewis/VSEPR structure predict?
c) Write down the electron configuration for Neon.
d) For each major feature observed in the spectrum, give the energy of the transition and
assign the orbital(s) from which the electron comes.
So I cant see any of the answers on section 4.41 D, F, G In the
Organic Chemistry: Principles And Mechanisms (second Edition)
2nd Edition
Textbook. Would you be able to just send me the answers and images. I have already done them and I am practicing for class but I dont know if I am correct.
a) Draw Lewis structures for each of the compounds below. Be sure to show
all bonding and non-bonding valence electrons. Also, clearly indicate any
formal charges on atoms.
b) Consider the molecular geometry information given for each compound
below: based on this information, specify the orbitals that each atom could
use in σ- and à-bonding (sp², sp³, p, etc.) and for holding non-bonding
electron pairs. Explain how your orbital assignments are consistent with
the observed geometries.
H₂CO (formaldehyde)
HCO-angle 120⁰
CH3CO₂ (acetate anion)
HCC-angle ≈ 109⁰
CCO-angle OCO≈ 120°
DCH=CHBr(1-bromo-2-deuterioethylene)
(two isomers)
(all atoms are coplanar)
(CH3)2SO (dimethylsulfoxide, DMSO)
HCS-angle CSO CSC≈ 109⁰
≈
Chapter 7 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 7 - Prob. 1CTQCh. 7 - Prob. 2CTQCh. 7 - Prob. 3CTQCh. 7 - Draw wedge and dash skeletal representations of...Ch. 7 - Label each ring in Figure 7.2 cis or trans.Ch. 7 - Prob. 6CTQCh. 7 - Prob. 7CTQCh. 7 - Prob. 8CTQCh. 7 - a model of cyclohexane in a chair conformation,...Ch. 7 - Prob. 10CTQ
Ch. 7 - Prob. 11CTQCh. 7 - Fill in the blanks: cis-1,3-Dimethylcyclohexane...Ch. 7 - Prob. 13CTQCh. 7 - Prob. 14CTQCh. 7 - Prob. 15CTQCh. 7 - Prob. 16CTQCh. 7 - Prob. 17CTQCh. 7 - Prob. 18CTQCh. 7 - Draw chair representations of...Ch. 7 - Which stereoisomer in the previous question is...Ch. 7 - Prob. 21CTQCh. 7 - Prob. 1ECh. 7 - Label each of the following as cis, trans or...Ch. 7 - Which pair has more in common with one another?Ch. 7 - Prob. 4ECh. 7 - Prob. 5ECh. 7 - Prob. 6ECh. 7 - Fill in the table by drawing a representation of a...Ch. 7 - Prob. 9ECh. 7 - True or False: If you perform a chair flip on...Ch. 7 - Prob. 11ECh. 7 - Prob. 12ECh. 7 - Prob. 13ECh. 7 - Prob. 14ECh. 7 - Prob. 15ECh. 7 - Draw trans-1-tert-butyl-3-methylcyclohexane in its...Ch. 7 - Build a model of methylcyclohexane, and use the...
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