Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 7, Problem 16CTQ
Interpretation Introduction
Interpretation: In the given structures, each black ball needs to be labeled as up or down.
Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:
Here, the substituted groups in the chair conformation are represented as follows:
The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.
The axial and equatorial groups are represented in the chair conformation as A and E:
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Draw the structure of a branched hydrocarbon that also contains at least one atom with
trigonal planar geometry.
Draw the structure of an aromatic hydrocarbon containing two halogens.
Draw the structure of a molecule containing an aliphatic primary amine and a carboxyl group.
Draw the structure of an acyclic molecule containing a primary and a secondary alcohol group.
Draw the structure of an achiral tertiary alcohol
Replace one H on propane with Br.
Does it matter which H is replaced? Yes or No (circle)
Are isomers possible for C3H¬B1? Yes or No (circle)
Draw the expanded structures for all isomers and name
each compound. As in question 1 on the previous page, use
a number in front of the name to indicate the position for
the bromine atom on the carbon chain. Consult with your
instructor to make sure you've correctly drawn and named
the structure(s) here.
3. Complete the following for compounds derived from butane, C4H10.
Butane, C4H10
Lewis Structures & Name
Are isomers possible? Yes or No (circle)
Build a model & draw the line structures for all potential
structural isomers of C4H10.
Using your molecular models for the butane isomers as a guide, draw line structures
for all monoiodo-derivatives of each of your isomers of butane having the molecular
formula C4H9I. Give the IUPAC name for each compound.
Question #2 - Start with a cyclohexane. Add a methyl to one of the carbons. Add a single oxygen to the carbon opposite the methyl. Add a 2 carbon chain to that lone oxygen.
Chapter 7 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 7 - Prob. 1CTQCh. 7 - Prob. 2CTQCh. 7 - Prob. 3CTQCh. 7 - Draw wedge and dash skeletal representations of...Ch. 7 - Label each ring in Figure 7.2 cis or trans.Ch. 7 - Prob. 6CTQCh. 7 - Prob. 7CTQCh. 7 - Prob. 8CTQCh. 7 - a model of cyclohexane in a chair conformation,...Ch. 7 - Prob. 10CTQ
Ch. 7 - Prob. 11CTQCh. 7 - Fill in the blanks: cis-1,3-Dimethylcyclohexane...Ch. 7 - Prob. 13CTQCh. 7 - Prob. 14CTQCh. 7 - Prob. 15CTQCh. 7 - Prob. 16CTQCh. 7 - Prob. 17CTQCh. 7 - Prob. 18CTQCh. 7 - Draw chair representations of...Ch. 7 - Which stereoisomer in the previous question is...Ch. 7 - Prob. 21CTQCh. 7 - Prob. 1ECh. 7 - Label each of the following as cis, trans or...Ch. 7 - Which pair has more in common with one another?Ch. 7 - Prob. 4ECh. 7 - Prob. 5ECh. 7 - Prob. 6ECh. 7 - Fill in the table by drawing a representation of a...Ch. 7 - Prob. 9ECh. 7 - True or False: If you perform a chair flip on...Ch. 7 - Prob. 11ECh. 7 - Prob. 12ECh. 7 - Prob. 13ECh. 7 - Prob. 14ECh. 7 - Prob. 15ECh. 7 - Draw trans-1-tert-butyl-3-methylcyclohexane in its...Ch. 7 - Build a model of methylcyclohexane, and use the...
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