The name of the given structure needs to be determined. Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows: Here, the substituted groups in the chair conformation are represented as follows: The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial. The axial and equatorial groups are represented in the chair conformation as A and E:

Question

A. Draw the major resonance structure, then draw curved arrows to show how this can be converted to the Lewis structure given. B. Thionitromethane is redrawn for you. Draw curved arrows to show how this can be converted to the resonance structure you drew in part A.

Answer 1

Question

Chapter 7, Problem 18CTQ

(a)

Interpretation Introduction

Interpretation: The name of the given structure needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(b)

Interpretation Introduction

Interpretation: The given structure on the right needs to be completed which is obtained by chair flip.

Concept Introduction:After a chair flip, all the axial bonds become equatorial and all the equatorial bonds become axial. But, the groups in the up direction remains upward and groups in down direction remain downward.

Also, if the molecule is cis, it remains cis even after chair flip. The same is the case with trans molecule.

(c)

Interpretation Introduction

Interpretation: The name of the structure formed after the chair flip in part (b) needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(d)

Interpretation Introduction

Interpretation: Whether the two structures are consistent with the given facts about chair flip or not needs to be determined.

Concept Introduction:

The chair conformation of cyclohexane is represented as follows:

During the flipping, no bond is break. The numbering in the chair form is represented as follows:

During ring flipping, mirror image of the chair conformation is formed.

It is represented as follows:

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A. Draw the major resonance structure, then draw curved arrows to show how this can be converted to the Lewis structure given. B. Thionitromethane is redrawn for you. Draw curved arrows to show how this can be converted to the resonance structure you drew in part A.

Chemistry Question

Complete the following statements so that they are true. Ry value. Ry value. R; value. Ry value. a. A more polar compound has a b. A less polar compound has a c. A more polar solvent causes a d. A less polar solvent causes a e. To increase the Ry of a spot, you should add more of which solvent, hexanes or ethyl acetate?

Answer 2

Question

Chapter 7, Problem 18CTQ

(a)

Interpretation Introduction

Interpretation: The name of the given structure needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(b)

Interpretation Introduction

Interpretation: The given structure on the right needs to be completed which is obtained by chair flip.

Concept Introduction:After a chair flip, all the axial bonds become equatorial and all the equatorial bonds become axial. But, the groups in the up direction remains upward and groups in down direction remain downward.

Also, if the molecule is cis, it remains cis even after chair flip. The same is the case with trans molecule.

(c)

Interpretation Introduction

Interpretation: The name of the structure formed after the chair flip in part (b) needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(d)

Interpretation Introduction

Interpretation: Whether the two structures are consistent with the given facts about chair flip or not needs to be determined.

Concept Introduction:

The chair conformation of cyclohexane is represented as follows:

During the flipping, no bond is break. The numbering in the chair form is represented as follows:

During ring flipping, mirror image of the chair conformation is formed.

It is represented as follows:

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Answer 3

Question

Chapter 7, Problem 18CTQ

(a)

Interpretation Introduction

Interpretation: The name of the given structure needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(b)

Interpretation Introduction

Interpretation: The given structure on the right needs to be completed which is obtained by chair flip.

Concept Introduction:After a chair flip, all the axial bonds become equatorial and all the equatorial bonds become axial. But, the groups in the up direction remains upward and groups in down direction remain downward.

Also, if the molecule is cis, it remains cis even after chair flip. The same is the case with trans molecule.

(c)

Interpretation Introduction

Interpretation: The name of the structure formed after the chair flip in part (b) needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(d)

Interpretation Introduction

Interpretation: Whether the two structures are consistent with the given facts about chair flip or not needs to be determined.

Concept Introduction:

The chair conformation of cyclohexane is represented as follows:

During the flipping, no bond is break. The numbering in the chair form is represented as follows:

During ring flipping, mirror image of the chair conformation is formed.

It is represented as follows:

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Answer 4

Question

Chapter 7, Problem 18CTQ

(a)

Interpretation Introduction

Interpretation: The name of the given structure needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(b)

Interpretation Introduction

Interpretation: The given structure on the right needs to be completed which is obtained by chair flip.

Concept Introduction:After a chair flip, all the axial bonds become equatorial and all the equatorial bonds become axial. But, the groups in the up direction remains upward and groups in down direction remain downward.

Also, if the molecule is cis, it remains cis even after chair flip. The same is the case with trans molecule.

(c)

Interpretation Introduction

Interpretation: The name of the structure formed after the chair flip in part (b) needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(d)

Interpretation Introduction

Interpretation: Whether the two structures are consistent with the given facts about chair flip or not needs to be determined.

Concept Introduction:

The chair conformation of cyclohexane is represented as follows:

During the flipping, no bond is break. The numbering in the chair form is represented as follows:

During ring flipping, mirror image of the chair conformation is formed.

It is represented as follows:

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Answer 5

Chapter 7, Problem 18CTQ

(a)

Interpretation Introduction

Interpretation: The name of the given structure needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(b)

Interpretation Introduction

Interpretation: The given structure on the right needs to be completed which is obtained by chair flip.

Concept Introduction:After a chair flip, all the axial bonds become equatorial and all the equatorial bonds become axial. But, the groups in the up direction remains upward and groups in down direction remain downward.

Also, if the molecule is cis, it remains cis even after chair flip. The same is the case with trans molecule.

(c)

Interpretation Introduction

Interpretation: The name of the structure formed after the chair flip in part (b) needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(d)

Interpretation Introduction

Interpretation: Whether the two structures are consistent with the given facts about chair flip or not needs to be determined.

Concept Introduction:

The chair conformation of cyclohexane is represented as follows:

During the flipping, no bond is break. The numbering in the chair form is represented as follows:

During ring flipping, mirror image of the chair conformation is formed.

It is represented as follows:

Answer 6

Chapter 7, Problem 18CTQ

(a)

Interpretation Introduction

Interpretation: The name of the given structure needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

Answer 7

Chapter 7, Problem 18CTQ

(a)

Interpretation Introduction

Interpretation: The name of the given structure needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

Answer 8

(b)

Interpretation Introduction

Interpretation: The given structure on the right needs to be completed which is obtained by chair flip.

Concept Introduction:After a chair flip, all the axial bonds become equatorial and all the equatorial bonds become axial. But, the groups in the up direction remains upward and groups in down direction remain downward.

Also, if the molecule is cis, it remains cis even after chair flip. The same is the case with trans molecule.

Answer 9

(b)

Interpretation Introduction

Interpretation: The given structure on the right needs to be completed which is obtained by chair flip.

Concept Introduction:After a chair flip, all the axial bonds become equatorial and all the equatorial bonds become axial. But, the groups in the up direction remains upward and groups in down direction remain downward.

Also, if the molecule is cis, it remains cis even after chair flip. The same is the case with trans molecule.

Answer 10

(c)

Interpretation Introduction

Interpretation: The name of the structure formed after the chair flip in part (b) needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

Answer 11

(c)

Interpretation Introduction

Interpretation: The name of the structure formed after the chair flip in part (b) needs to be determined.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

Answer 12

(d)

Interpretation Introduction

Interpretation: Whether the two structures are consistent with the given facts about chair flip or not needs to be determined.

Concept Introduction:

The chair conformation of cyclohexane is represented as follows:

During the flipping, no bond is break. The numbering in the chair form is represented as follows:

During ring flipping, mirror image of the chair conformation is formed.

It is represented as follows:

Answer 13

(d)

Interpretation Introduction

Interpretation: Whether the two structures are consistent with the given facts about chair flip or not needs to be determined.

Concept Introduction:

The chair conformation of cyclohexane is represented as follows:

During the flipping, no bond is break. The numbering in the chair form is represented as follows:

During ring flipping, mirror image of the chair conformation is formed.

It is represented as follows:

Answer 14

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Answer 25

Ch. 7 - Prob. 1CTQ Ch. 7 - Prob. 2CTQ Ch. 7 - Prob. 3CTQ Ch. 7 - Draw wedge and dash skeletal representations of...Ch. 7 - Label each ring in Figure 7.2 cis or trans.Ch. 7 - Prob. 6CTQ Ch. 7 - Prob. 7CTQ Ch. 7 - Prob. 8CTQ Ch. 7 - a model of cyclohexane in a chair conformation,...Ch. 7 - Prob. 10CTQ

Solution Summary: The author explains that the name of the structure formed after the chair flip in part (b) needs to be determined.

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Chapter 7 Solutions