The one which changes during a chair flip in case of cyclohexane and the one which remains the same needs to be explained. Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows: Here, the substituted groups in the chair conformation are represented as follows: The groups showing in straight upward and downward directions are axial, and the groups bend slightly right or left are equatorial. The axial and equatorial groups are represented in the chair conformation as A and E:

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Answer 1

Question

Chapter 7, Problem 11E

(a)

Interpretation Introduction

Interpretation: The one which changes during a chair flip in case of cyclohexane and the one which remains the same needs to be explained.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial, and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(b)

Interpretation Introduction

Interpretation: The change in the group that is up and in axial position in the cyclohexane needs to be explained after the chair flip.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

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Consider 1,2-dimethylcyclohexane. a.Draw structures for the cis and trans isomers using a hexagon for the sixmembered ring. b. Draw the two possible chair conformations for the cis isomer. Which conformation, if either, is more stable? c. Draw the two possible chair conformations for the trans isomer. Which conformation, if either, is more stable? d.Which isomer, cis or trans, is more stable and why?

41. Draw the structure of a hydrocarbon that has six carbon atoms and a. three vinylic hydrogens and two allylic hydrogens. b. three vinylic hydrogens and one allylic hydrogen. c. three vinylic hydrogens and no allylic hydrogens.

Consider 1,2-dimethylcyclohexane.a. Draw structures for the cis and trans isomers using a hexagon for the six-membered ring.b. Draw the two possible chair conformations for the cis isomer. Which conformation, if either, is more stable?c. Draw the two possible chair conformations for the trans isomer. Which conformation, if either, is more stable?d. Which isomer, cis or trans, is more stable and why?

Answer 2

Question

Chapter 7, Problem 11E

(a)

Interpretation Introduction

Interpretation: The one which changes during a chair flip in case of cyclohexane and the one which remains the same needs to be explained.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial, and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(b)

Interpretation Introduction

Interpretation: The change in the group that is up and in axial position in the cyclohexane needs to be explained after the chair flip.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

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Answer 3

Question

Chapter 7, Problem 11E

(a)

Interpretation Introduction

Interpretation: The one which changes during a chair flip in case of cyclohexane and the one which remains the same needs to be explained.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial, and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(b)

Interpretation Introduction

Interpretation: The change in the group that is up and in axial position in the cyclohexane needs to be explained after the chair flip.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

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Answer 4

Question

Chapter 7, Problem 11E

(a)

Interpretation Introduction

Interpretation: The one which changes during a chair flip in case of cyclohexane and the one which remains the same needs to be explained.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial, and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(b)

Interpretation Introduction

Interpretation: The change in the group that is up and in axial position in the cyclohexane needs to be explained after the chair flip.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

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Answer 5

Chapter 7, Problem 11E

(a)

Interpretation Introduction

Interpretation: The one which changes during a chair flip in case of cyclohexane and the one which remains the same needs to be explained.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial, and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

(b)

Interpretation Introduction

Interpretation: The change in the group that is up and in axial position in the cyclohexane needs to be explained after the chair flip.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

Answer 6

Chapter 7, Problem 11E

(a)

Interpretation Introduction

Interpretation: The one which changes during a chair flip in case of cyclohexane and the one which remains the same needs to be explained.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial, and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

Answer 7

Chapter 7, Problem 11E

(a)

Interpretation Introduction

Interpretation: The one which changes during a chair flip in case of cyclohexane and the one which remains the same needs to be explained.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial, and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

Answer 8

(b)

Interpretation Introduction

Interpretation: The change in the group that is up and in axial position in the cyclohexane needs to be explained after the chair flip.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

Answer 9

(b)

Interpretation Introduction

Interpretation: The change in the group that is up and in axial position in the cyclohexane needs to be explained after the chair flip.

Concept Introduction: Chair conformation is the most stable conformation of cyclohexane. It is represented as follows:

Here, the substituted groups in the chair conformation are represented as follows:

The groups showing in straight upward and downward directions are axial and the groups bend slightly right or left are equatorial.

The axial and equatorial groups are represented in the chair conformation as A and E:

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 7 - Prob. 1CTQ Ch. 7 - Prob. 2CTQ Ch. 7 - Prob. 3CTQ Ch. 7 - Draw wedge and dash skeletal representations of...Ch. 7 - Label each ring in Figure 7.2 cis or trans.Ch. 7 - Prob. 6CTQ Ch. 7 - Prob. 7CTQ Ch. 7 - Prob. 8CTQ Ch. 7 - a model of cyclohexane in a chair conformation,...Ch. 7 - Prob. 10CTQ

Solution Summary: The author explains that the change in the group that is up and in axial position needs to be explained after the chair flip.

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