Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 7, Problem 6CTQ
Interpretation Introduction
Interpretation:
The given disubstituted cyclohexane rings needs to be labeled as cis, trans or neither.
Concept Introduction:
In a molecule, if similar groups are on the same side of the plane then it is known as cis isomer and if similar groups are on the opposite sides, it is known as trans isomers.
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a
HỘ
CH2OH
H
H
CÓH
In its most stable chair conformation, indicate the orientation of each
of the labeled groups in this substituted cyclohexane.
Group a:
Group b:
Group c:
Determine which cyclohexane structure has the MOST energy (is the LEAST stable)?
Draw both the condensed and line-bond structure of the following compounds:
* bromocyclobutane (Br-, Bromo branch)
* 5-sec-butylnonane
* 4-t-butylheptane
* 4-ethylcycloheptene
* 4,4-dimethylpent-2-ene
* 3-chloro-2,7-dimethylnon-4-yne (Cl- Chloro branch)
* 1-cyclohexylbut-2-yne
Chapter 7 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 7 - Prob. 1CTQCh. 7 - Prob. 2CTQCh. 7 - Prob. 3CTQCh. 7 - Draw wedge and dash skeletal representations of...Ch. 7 - Label each ring in Figure 7.2 cis or trans.Ch. 7 - Prob. 6CTQCh. 7 - Prob. 7CTQCh. 7 - Prob. 8CTQCh. 7 - a model of cyclohexane in a chair conformation,...Ch. 7 - Prob. 10CTQ
Ch. 7 - Prob. 11CTQCh. 7 - Fill in the blanks: cis-1,3-Dimethylcyclohexane...Ch. 7 - Prob. 13CTQCh. 7 - Prob. 14CTQCh. 7 - Prob. 15CTQCh. 7 - Prob. 16CTQCh. 7 - Prob. 17CTQCh. 7 - Prob. 18CTQCh. 7 - Draw chair representations of...Ch. 7 - Which stereoisomer in the previous question is...Ch. 7 - Prob. 21CTQCh. 7 - Prob. 1ECh. 7 - Label each of the following as cis, trans or...Ch. 7 - Which pair has more in common with one another?Ch. 7 - Prob. 4ECh. 7 - Prob. 5ECh. 7 - Prob. 6ECh. 7 - Fill in the table by drawing a representation of a...Ch. 7 - Prob. 9ECh. 7 - True or False: If you perform a chair flip on...Ch. 7 - Prob. 11ECh. 7 - Prob. 12ECh. 7 - Prob. 13ECh. 7 - Prob. 14ECh. 7 - Prob. 15ECh. 7 - Draw trans-1-tert-butyl-3-methylcyclohexane in its...Ch. 7 - Build a model of methylcyclohexane, and use the...
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- Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This group is called an ethyl group and can be considered a sphere about twice the sizeof a methyl group. Draw the following Newman projections sighting down the C1C2 bond... a. The lowest potential energy conformation. b. The highest potential energy staggered conformation.arrow_forwardFill in the blanks: cis-1,3-Dimethylcyclohexane has two different chair conformations: one withboth methyl groups in __________ positions and one with both methyl groups in ____________ positions.arrow_forward4. Draw the most and least stable conformations of the following substituted cyclohexanes in the chair format (excluding transient conformations like half chair, twist boat and boat). Br BL Br Brarrow_forward
- NAME: 1. Draw the 2 chai conformations of cis-1-tert-butyl-2-ethylcyclohexane. Circle the most stable conformation of the moleculearrow_forwardWhich of the following is the most stable conformation of bromocyclohexane? IV.arrow_forwardWhat is the molecular formula (C before H) for methylbut ane?arrow_forward
- Provide the correct common name for the skeletal (line-bond) structure shown here. 2- 1- 6- 4- 3- 5- cyclo di oct sec- tri iso tert- prop pentarrow_forwardCreate Newman projections depicting conformations along the carbon-carbon bond described above in the lowest energy staggered conformation, gauche conformation, and highest energy eclipsed conformation. Appropriately label these conformations Please draw each out separately and do not just draw arrows on the molecule. OH HO HO. ОН ОНarrow_forwardDraw the most stable conformation for each of the following substituted cyclohexanes. Show all conformation in Newman projections. Fill in hydrogens to indicate unsubstituted carbons.arrow_forward
- Place the methyl groups by drawing the axial and equatorial positions on the cyclohexane structure in the chair conformations next to the cyclohexane derivatives named below.arrow_forwardDraw the most and least stable conformations of the following substituted cyclohexanes in the chair format (excluding transient conformations like half chair, twist boat and boat).arrow_forwardDraw both the condensed and line-bond structure of these 4 compounds: * 4-ethylcycloheptene * 4,4-dimethylpent-2-ene * 3-chloro-2,7-dimethylnon-4-yne (Cl- Chloro branch) * 1-cyclohexylbut-2-ynearrow_forward
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