EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 6, Problem 64CP
(a)
Interpretation Introduction
Interpretation:
The curved arrow must be shown for the Lewis acid mediated transformation of compound 1 to compound 2.
Concept Introduction :
The Lewis acids are those which can accept lone pair of electrons. These may enhance the reactivity of groups like oxygen by coordinating with it.
(b)
Interpretation Introduction
Interpretation:
The curved arrow must be shown for the transformation of compound 2 to compound 3.
Concept Introduction :
The Cyclopropane ring is very strained ring which is very reactive towards ring opening reaction. This ring contains 49°28’ angle strain.
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Students have asked these similar questions
A difficult problem in the synthesis of PGF2α is the introduction of the OH group at C15 in the desired configuration. a. Label this stereogenic center as R or S. b. A well-known synthesis of PGF2α involves reaction of A with Zn(BH4)2, a metal hydride reagent similar in reactivity to NaBH4, to form two isomeric products, B and C. Draw their structures and indicate their stereochemical relationship. d. Suggest a reagent to convert A to the single stereoisomer X.
Draw the structure resulting from a reaction of:
1. diborane (B₂H6), followed by
2. alkaline hydrogen peroxide (NaOH / H₂O2)
with the following alkene.
.
Use the wedge/hash bond tools to indicate stereochemistry where it exists.
.
If a group is achiral, do not use wedged or hashed bonds on it.
• If the reaction produces a racemic mixture, just draw one stereoisomer.
Compound F may be synthesised by the method below
Compound A
Compound F
HCI
CH3OH
H₂SO4
Compound B
CH3 CH₂ CH₂
CI
NaOH
Compound E K₂Cr₂O7
H₂SO4
Compound C
K₂Cr₂O7
H₂SO4
Compound D
a. Draw the structural formulas of compounds A, C, D, E and F in the boxes provided above.
b. Draw the isomer of compound B and explain which one would be the major product and
why.
c. When 2-chloropropane treated with NaOH and 1-chloropropane treated with NaOH
separately produce two different functional groups. Provide both reactions and explain the
two different functional groups produced.
Chapter 6 Solutions
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
Ch. 6.1 - Prob. 1LTSCh. 6.1 - Prob. 1PTSCh. 6.1 - Prob. 2ATSCh. 6.2 - Prob. 3CCCh. 6.3 - Prob. 4CCCh. 6.3 - Prob. 5CCCh. 6.4 - Prob. 6CCCh. 6.6 - Prob. 7CCCh. 6.7 - Prob. 2LTSCh. 6.7 - Prob. 8PTS
Ch. 6.7 - Prob. 9PTSCh. 6.7 - Prob. 10ATSCh. 6.8 - Prob. 3LTSCh. 6.8 - Prob. 11PTSCh. 6.8 - Prob. 12ATSCh. 6.9 - Prob. 4LTSCh. 6.9 - Prob. 13PTSCh. 6.9 - Prob. 14ATSCh. 6.10 - Prob. 5LTSCh. 6.10 - Prob. 15PTSCh. 6.10 - Prob. 16ATSCh. 6.11 - Prob. 6LTSCh. 6.11 - Prob. 17PTSCh. 6.11 - Prob. 18ATSCh. 6 - Prob. 19PPCh. 6 - Prob. 20PPCh. 6 - Prob. 21PPCh. 6 - Prob. 22PPCh. 6 - Prob. 24PPCh. 6 - Prob. 25PPCh. 6 - Prob. 26PPCh. 6 - Prob. 27PPCh. 6 - Prob. 28PPCh. 6 - Prob. 29PPCh. 6 - Prob. 30PPCh. 6 - Prob. 31PPCh. 6 - Prob. 32PPCh. 6 - Prob. 33PPCh. 6 - Prob. 34PPCh. 6 - Prob. 35PPCh. 6 - Prob. 36PPCh. 6 - Prob. 37PPCh. 6 - Prob. 38PPCh. 6 - Prob. 39PPCh. 6 - Prob. 40PPCh. 6 - Prob. 41PPCh. 6 - Prob. 43ASPCh. 6 - Prob. 44ASPCh. 6 - Prob. 45ASPCh. 6 - Prob. 46ASPCh. 6 - Prob. 47ASPCh. 6 - Prob. 48ASPCh. 6 - Prob. 49ASPCh. 6 - Prob. 50IPCh. 6 - Prob. 51IPCh. 6 - Prob. 52IPCh. 6 - Prob. 53IPCh. 6 - Prob. 54IPCh. 6 - Prob. 55IPCh. 6 - Prob. 56IPCh. 6 - Prob. 57IPCh. 6 - Prob. 58IPCh. 6 - Prob. 59IPCh. 6 - Prob. 60IPCh. 6 - Prob. 61IPCh. 6 - Prob. 62CPCh. 6 - Prob. 64CP
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