Interpretation:
When each of the given
Concept introduction:
舧 Electrophiles are electron-deficient species, which has positive or partially positive charge. Lewis acids are electrophiles, which accept electron pair.
舧 Nucleophiles are electron-rich species, which has negative or partially negative charge. Lewis bases are nucleophiles, which donate electron pair.
舧 Substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon or a
舧 Elimination reaction: A reaction in which two substituent groups are detached and a double bond is formed is called elimination reaction.
舧 Addition reaction: It is the reaction in which unsaturated bonds are converted to saturated molecules by the addition of molecules.
舧 Sandmeyer reaction is an organic reaction in which the amine group of a primary
舧 Hydride shift is defined as the rearrangement of hydrogen atoms.
舧 Nitrous acid
舧 Nitrous acid is used to make diazonium salts from amines.
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Organic Chemistry
- Draw a structural formula for each amine and amine derivative. (a) N,N-Dimethylaniline (b) Triethylamine (c) tert-Butylamine (d) 1,4-Benzenediamine (e) 4-Aminobutanoic acid (f) (R)-2-Butanamine (g) Benzylamine (h) trans-2-Aminocyclohexanol (i) 1-Phenyl-2-propanamine (amphetamine) (j) Lithium diisopropylamide (LDA) (k) Benzyltrimethylammonium hydroxide (Triton B)arrow_forwardDraw the structure of the product that will be formed when each of the following amines reacts with sodium nitrite and hydrochloric acid, followed by cuprous chloride. (d) N,N-dipropylanilinearrow_forwardPredict the products from the reactions of the following amines with sodium nitrite indilute HCl.(a) cyclohexanaminearrow_forward
- From the given structures which is(a) amide that will release a secondary amine upon hydrolysis? (b) product of hydrolysis of MSO (c) a tertiary amide and (d) a diketonearrow_forwardDraw the structure of the product that will be formed when each of the following amines reacts with sodium nitrite and hydrochloric acid, followed by cuprous chloride. (a) propylaminearrow_forwardFollowing are structural formulas for two enamines. Me Me క (a) (b) Draw structural formulas for the secondary amine and carbonyl compound from which each enamine is derived.arrow_forward
- 2) Predict the products formed when the following amides are treated with bromine and sodium hydroxide (Hoffman Reaction). a) PHCH2CH2CONH2 b) NH2CO(CH2)4CONH2 NH2 c)arrow_forwardShow how you might utilize the reduction of an amide, oxime, or a nitrile to carry out each of the following transformations (a)Benzoic acid to N-ethyl-N-benzylamine (b)1-Bromopentane to hexylamine (c)Propanoic acid to tripropylamine (d)2-Butanone to sec-butylaminearrow_forwardWhich of the following is the most basic amine? A benzylamine B) N-ethylethanamine (c) pyridine (D) none of the choicesarrow_forward
- 1. Draw structures for the following: (a) N,N-dimethylpentanamide (b) Acetamide(c) 2,3-dimethylpentanamide (d) N-ethylbenzamidearrow_forwardDraw the struetre of the following three isomeic amides with chemical feruula CHNO. Amide #1: (E)-N,N-dimethyl-2-butenamide Amide #2: (7)-N-methyl-3-pentenamide Amide #3: (7)-3-hexenamide C'onsider Z sterenchemistry of alkenes. • Draw one structure per sketcher. Add additional sketchers asing the drop-down memu in the hottom right comer. Sepamte structares with - signs from the drop-down mena. O00. IF ChemDoodle ChemDoodie ChemDoodle just the first one is what I could really use help on Amide #1: (E)-N,N-dimethyl-2-butenamidearrow_forwardThe –NHCOR group of an amide is an activating group, but it is not as strongly activating as NH2. (a) Explain why it is an activating group. (b) Explain why it is less activating than NH2.arrow_forward
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning