In aqueous solution, propanamide exhibit basic behavior or not has to be indicated. Concept Introduction: Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions. Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 1

Question

Chapter 17, Problem 17.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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The hydrolysis of an amide in acidic conditions forms A. a carboxylate salt and an alcohol B. a carboxylate salt and an amine C. an alcohol and an amine salt (an ammonium ion) D. a carboxylic acid and an amine salt (an ammonium ion)

Complete this table for different amine compounds. Chemical propylamine quaternary ammonium ion methylphenylamine Molecular formula C3H9N C₂H7N C5H13N C4H10N Structural formula (CH3)3N (CH3)2NH CH 3 I (CH₂) 11 | H3C(CH2) 11 -N-(CH₂)11CH3 NHCH3 (CH₂)11 CH3 CH3CH2CH2-NH-CH3 + Classification Tertiary Quaternary Tertiary Secondary

Ester compounds often have a sweet, pleasant odor. Many characteristic fruit scents are largely due to the natural presence of one or more ester compounds. As such, artificial scents for foods are often composed of complex mixtures of various esters. The exact identity and ratio of ingredients that compose a particular scent are closely guarded secrets in the food and fragrance industry. Suppose that you are a chemist working for a company that i creating a new line of air fresheners. The company is considering three scents: apple, pear, and pineapple. The project manager has asked you to prepare the ester compounds that are largely responsible for these scents. The structural formulas for these ester compounds are shown here: Alcohols for Air Freshener Project Molar mass Density Cost, per (g/mL) Reagent (g/mol) 1.00 L methanol 32.04 0.79 $46.20 ethanol 46.07 0.79 $112.00 1-propanol 60.10 0.80 $72.70 1-butanol 74.12 0.81 $72.60 Use the structural formulas of the alcohols and…

Answer 2

Question

Chapter 17, Problem 17.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 3

Question

Chapter 17, Problem 17.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 4

Question

Chapter 17, Problem 17.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

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Answer 5

Chapter 17, Problem 17.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 6

Chapter 17, Problem 17.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 7

Chapter 17, Problem 17.123EP

(a)

Interpretation Introduction

Interpretation:

In aqueous solution, propanamide exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 8

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 9

(b)

Interpretation Introduction

Interpretation:

In aqueous solution, 1-propanamine exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 10

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 11

(c)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 12

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 13

(d)

Interpretation Introduction

Interpretation:

In aqueous solution, the given compound exhibit basic behavior or not has to be indicated.

Concept Introduction:

Amines are a class of organic compounds. They are derivatives of ammonia. Similar to the nitrogen atom in ammonia, the amine nitrogen also has a lone pair of electrons on it. This means that amines can act as proton acceptors. When an amine is added to water a proton is transferred to the nitrogen atom. The resulting solution is a basic solution. This contains ammonium ions and hydroxide ions.

Amides have a carbonyl group bonded to the nitrogen atom. The carbonyl carbon atom pulls the lone pair of electrons present on the nitrogen strongly. Hence, the nitrogen atom cannot act as a proton acceptor. Amides are not basic in nature.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 17.1 - Prob. 1QQ Ch. 17.1 - Prob. 2QQ Ch. 17.2 - Prob. 1QQ Ch. 17.2 - Prob. 2QQ Ch. 17.2 - Prob. 3QQ Ch. 17.2 - Prob. 4QQ Ch. 17.3 - Prob. 1QQ Ch. 17.3 - Prob. 2QQ Ch. 17.3 - Prob. 3QQ Ch. 17.3 - Prob. 4QQ

Solution Summary: The author explains that amines are a class of organic compounds. They are derivatives of ammonia.

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Chapter 17 Solutions