Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Textbook Question
Chapter 16.2, Problem 7P
There are three carbon-oxygen bonds in methyl acetate.
- a. What are their relative bond lengths?
- b. What are the relative infrared (IR) stretching frequencies of these bonds?
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True or False
1. Sample preparation of infrared spectroscopy uses KBr as the blank because Kbr has 100% transmittance at the IR wavelength range.
2. The electronegativity difference present in a dipole moment within a bond is directly proportional to the electromagnetic field produced.
3. The electromagnetic radiation that is emitted in infrared spectroscopy is not enough to excite electrons to an unoccupied molecular orbital.
2. According to the Beer-Lambert law absorbance is proportional
to concentration at each wavelength. In principle, one could
choose any wavelength for quantitative estimations of
concentration. However, we generally select the wavelength of
maximum absorbance for a given sample and use it in our
absorbance measurements. Especially, one should avoid the
steep portions of the spectrum. Why?
3. Which concentration range
a dilute or a concentrated one - is
chosen for accurate determinations of unknown concentrations?
Chapter 16 Solutions
Organic Chemistry
Ch. 16.1 - The aromas of many flowers and fruits are due to...Ch. 16.1 - Prob. 2PCh. 16.1 - Name the following:Ch. 16.1 - Prob. 4PCh. 16.2 - Prob. 5PCh. 16.2 - Which is longer, the carbon-oxygen single bond in...Ch. 16.2 - There are three carbon-oxygen bonds in methyl...Ch. 16.2 - Prob. 8PCh. 16.4 - Prob. 9PCh. 16.4 - Prob. 10P
Ch. 16.5 - a. What is the product of the reaction of acetyl...Ch. 16.6 - a. Which compound has the stretching vibration for...Ch. 16.6 - Using the pKa values listed in Table 15.1, predict...Ch. 16.6 - Is the following statement true or false? If the...Ch. 16.7 - What is the product of an acyl substitution...Ch. 16.8 - PROBLEM 16
Starting with acetyl chloride, what...Ch. 16.8 - Prob. 18PCh. 16.9 - We saw that it is necessary to use excess amine in...Ch. 16.9 - Prob. 20PCh. 16.9 - a. state three factors that cause the uncatalyzed...Ch. 16.10 - Prob. 23PCh. 16.10 - Using the mechanism for the acid-catalyzed...Ch. 16.10 - Prob. 25PCh. 16.10 - Prob. 27PCh. 16.10 - Write the mechanism for the acid-catalyzed...Ch. 16.10 - Write the mechanism for the acid-catalyzed...Ch. 16.11 - Prob. 30PCh. 16.12 - Prob. 31PCh. 16.12 - Prob. 32PCh. 16.13 - Prob. 34PCh. 16.13 - Which has a higher melting point, glyceryl...Ch. 16.13 - Draw the structure of an optically inactive fat...Ch. 16.13 - Draw the structure of an optically active fat...Ch. 16.14 - Show how each of the following esters could he...Ch. 16.14 - Prob. 39PCh. 16.15 - Prob. 40PCh. 16.15 - Which of the following reactions leads to the...Ch. 16.16 - Prob. 42PCh. 16.16 - Prob. 43PCh. 16.18 - Prob. 44PCh. 16.18 - Prob. 45PCh. 16.19 - Prob. 46PCh. 16.19 - Which alkyl halides from the carboxylic acids...Ch. 16.20 - Prob. 49PCh. 16.20 - Prob. 50PCh. 16.20 - Prob. 51PCh. 16.21 - Prob. 52PCh. 16.21 - Prob. 53PCh. 16.22 - How could you synthesize the following compounds...Ch. 16 - Prob. 55PCh. 16 - Name the following:Ch. 16 - Prob. 57PCh. 16 - What compound are obtained from the fallowing...Ch. 16 - a. Rank the following esters in order of...Ch. 16 - Because bromocyclohexane is a secondary alkyl...Ch. 16 - a. Which compound would you expect to have a...Ch. 16 - How could you use 1H NMR spectroscopy to...Ch. 16 - Prob. 63PCh. 16 - a. When a carboxylic acid is dissolved in...Ch. 16 - Rank the following compounds in order of...Ch. 16 - Prob. 66PCh. 16 - Prob. 67PCh. 16 - Prob. 68PCh. 16 - A compound with molecular formula C5H10O2 gives...Ch. 16 - Prob. 70PCh. 16 - Prob. 71PCh. 16 - Prob. 72PCh. 16 - Two products, A and B, are obtained from the...Ch. 16 - Prob. 74PCh. 16 - Prob. 75PCh. 16 - Prob. 76PCh. 16 - Prob. 77PCh. 16 - When treated with an equivalent of methanol,...Ch. 16 - a. Identify the two products obtained from the...Ch. 16 - Prob. 80PCh. 16 - Identity the major and minor products of the...Ch. 16 - Prob. 82PCh. 16 - When a compound with molecular formula C11H14O2...Ch. 16 - Prob. 84PCh. 16 - Prob. 85PCh. 16 - The 1H NMR spectra for two esters with molecular...Ch. 16 - Show how the following compounds could be prepared...Ch. 16 - Prob. 88PCh. 16 - Prob. 89PCh. 16 - Prob. 90PCh. 16 - The intermediate shown here is formed during the...Ch. 16 - Prob. 92PCh. 16 - Propose a mechanism that accounts for the...Ch. 16 - Catalytic antibodies catalyze a reaction by...Ch. 16 - Prob. 95P
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- What is the order of the punch and the energy diagram according to the T.O.M molecular theory of F2?arrow_forwardA. Choose the letter of the best answer. 1. What is a saturated hydrocarbon? A. Any compound consisting of carbon and hydrogen only. B. Any compound consisting of carbon and hydrogen and oxygen only. C. Any compound consisting of carbon and hydrogen only, in which some of the carbon atoms are joined to each other by double or triple bonds. D. Any compound consisting of carbon and hydrogen only, in which all the carbon atoms are joined to each other by single bonds. 2. What kind of hydrocarbon is C3H14? A. alkane C. alkyne B. alkene D. alcohol H. H H. 3. This molecule is an example of an... H. A. alkane C. alkyne B. alkene D. alcohol 4. Which is an example of an ether? А. CН3ОН B. CH3CH2CH2CI C. CH3CH2OCH2CH3 D. CH3CH2COOCH3 5. What is the simplest organic compound? A. methane C. ethanol B. acetone D. ethanearrow_forwardConsider the explanation in the Introduction regarding the determination of qrxn, and answer the following questions about the reactions that you will be performing in this experiment. Part A: How are qsoln and qrxn related to one another? A.)They are equal B.)They are unrelated C.)-qsoln = qrxn Part B) Consider the explanation in the Introduction regarding the determination of qrxn, and answer the following questions about the reactions that you will be performing in this experiment. Based on your answers to the previous questions, Will qrxn be a positive or negative quantity? A.) Positive B.) Negative C.) Zero Part C). A student observed that, when 0.243 g of magnesium was added to 100.0 g of hydrochloric acid, the temperature of the solution increased 11.2 °C. Without doing any calculations, what observations can you make to determine if this reaction was endothermic or exothermic? Select the best pairing of reasonable observation and conclusion. Group of answer…arrow_forward
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IR Spectroscopy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=_TmevMf-Zgs;License: Standard YouTube License, CC-BY