To write the mechanism for an uncatalyzed hydrolysis of methyl propionate. Concept introduction: The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid . The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction . When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester. The general reaction of an ester to produce in presence of only water is written as,

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Answer 1

Question

Chapter 16.9, Problem 20P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

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Write a mechanism for each of the following reactions: a. the uncatalyzed hydrolysis of methyl propionate. b. the aminolysis of phenyl formate, using methylamine.

Write the mechanism for the following reactions: 1. the acid-catalyzed hydrolysis of an imine to a carbonyl compound and a primary amine 2. the acid-catalyzed hydrolysis of an enamine to a carbonyl compound and a secondary amine a. How do the two mechanisms differ?

22. The stability of carbocation can be accounted by which of the following structural effect? a. hyperconjugation b. inductive effect d. both a andb C. resonance 23. Secondary amines are more basic than primary amines because of what structural effect? a. hyperconjugation b. inductive effect C. resonance d. steric effect

Answer 2

Question

Chapter 16.9, Problem 20P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

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Answer 3

Question

Chapter 16.9, Problem 20P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

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Answer 4

Question

Chapter 16.9, Problem 20P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

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Answer 5

Chapter 16.9, Problem 20P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

Answer 6

Chapter 16.9, Problem 20P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

Answer 7

Chapter 16.9, Problem 20P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

Answer 8

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

Answer 9

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16.1 - The aromas of many flowers and fruits are due to...Ch. 16.1 - Prob. 2P Ch. 16.1 - Name the following:Ch. 16.1 - Prob. 4P Ch. 16.2 - Prob. 5P Ch. 16.2 - Which is longer, the carbon-oxygen single bond in...Ch. 16.2 - There are three carbon-oxygen bonds in methyl...Ch. 16.2 - Prob. 8P Ch. 16.4 - Prob. 9P Ch. 16.4 - Prob. 10P

Solution Summary: The author explains the mechanism for an uncatalyzed hydrolysis of methyl propionate.

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