7th Edition

ISBN: 9780321803221

Author: Paula Y. Bruice

Publisher: Prentice Hall

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Aldehydes and ketones are organic compounds that have a carbonyl group, C = O, as their functional group. They both differ in the placement of this carbonyl group in their structures.

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Textbook Question

Chapter 16, Problem 59P

a. Rank the following esters in order of decreasing reactivity in the first slow step of a nucleophilic acyl substitution reaction (formation of the tetrahedral intermediate):

Chapter 16, Problem 59P, a. Rank the following esters in order of decreasing reactivity in the first slow step of a

b. Rank the tame esters in order of decreasing reactivity in the second slow step of a nucleophilic acyl substitution reaction (collapse of the tetrahedral intermediate).

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Chapter 16, Problem 58P

Chapter 16, Problem 60P

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Chapter 16 Solutions

Organic Chemistry

Ch. 16.1 - The aromas of many flowers and fruits are due to...Ch. 16.1 - Prob. 2P Ch. 16.1 - Name the following:Ch. 16.1 - Prob. 4P Ch. 16.2 - Prob. 5P Ch. 16.2 - Which is longer, the carbon-oxygen single bond in...Ch. 16.2 - There are three carbon-oxygen bonds in methyl...Ch. 16.2 - Prob. 8P Ch. 16.4 - Prob. 9P Ch. 16.4 - Prob. 10P

Ch. 16.5 - a. What is the product of the reaction of acetyl...Ch. 16.6 - a. Which compound has the stretching vibration for...Ch. 16.6 - Using the pKa values listed in Table 15.1, predict...Ch. 16.6 - Is the following statement true or false? If the...Ch. 16.7 - What is the product of an acyl substitution...Ch. 16.8 - PROBLEM 16 Starting with acetyl chloride, what...Ch. 16.8 - Prob. 18P Ch. 16.9 - We saw that it is necessary to use excess amine in...Ch. 16.9 - Prob. 20P Ch. 16.9 - a. state three factors that cause the uncatalyzed...Ch. 16.10 - Prob. 23P Ch. 16.10 - Using the mechanism for the acid-catalyzed...Ch. 16.10 - Prob. 25P Ch. 16.10 - Prob. 27P Ch. 16.10 - Write the mechanism for the acid-catalyzed...Ch. 16.10 - Write the mechanism for the acid-catalyzed...Ch. 16.11 - Prob. 30P Ch. 16.12 - Prob. 31P Ch. 16.12 - Prob. 32P Ch. 16.13 - Prob. 34P Ch. 16.13 - Which has a higher melting point, glyceryl...Ch. 16.13 - Draw the structure of an optically inactive fat...Ch. 16.13 - Draw the structure of an optically active fat...Ch. 16.14 - Show how each of the following esters could he...Ch. 16.14 - Prob. 39P Ch. 16.15 - Prob. 40P Ch. 16.15 - Which of the following reactions leads to the...Ch. 16.16 - Prob. 42P Ch. 16.16 - Prob. 43P Ch. 16.18 - Prob. 44P Ch. 16.18 - Prob. 45P Ch. 16.19 - Prob. 46P Ch. 16.19 - Which alkyl halides from the carboxylic acids...Ch. 16.20 - Prob. 49P Ch. 16.20 - Prob. 50P Ch. 16.20 - Prob. 51P Ch. 16.21 - Prob. 52P Ch. 16.21 - Prob. 53P Ch. 16.22 - How could you synthesize the following compounds...Ch. 16 - Prob. 55P Ch. 16 - Name the following:Ch. 16 - Prob. 57P Ch. 16 - What compound are obtained from the fallowing...Ch. 16 - a. Rank the following esters in order of...Ch. 16 - Because bromocyclohexane is a secondary alkyl...Ch. 16 - a. Which compound would you expect to have a...Ch. 16 - How could you use 1H NMR spectroscopy to...Ch. 16 - Prob. 63P Ch. 16 - a. When a carboxylic acid is dissolved in...Ch. 16 - Rank the following compounds in order of...Ch. 16 - Prob. 66P Ch. 16 - Prob. 67P Ch. 16 - Prob. 68P Ch. 16 - A compound with molecular formula C5H10O2 gives...Ch. 16 - Prob. 70P Ch. 16 - Prob. 71P Ch. 16 - Prob. 72P Ch. 16 - Two products, A and B, are obtained from the...Ch. 16 - Prob. 74P Ch. 16 - Prob. 75P Ch. 16 - Prob. 76P Ch. 16 - Prob. 77P Ch. 16 - When treated with an equivalent of methanol,...Ch. 16 - a. Identify the two products obtained from the...Ch. 16 - Prob. 80P Ch. 16 - Identity the major and minor products of the...Ch. 16 - Prob. 82P Ch. 16 - When a compound with molecular formula C11H14O2...Ch. 16 - Prob. 84P Ch. 16 - Prob. 85P Ch. 16 - The 1H NMR spectra for two esters with molecular...Ch. 16 - Show how the following compounds could be prepared...Ch. 16 - Prob. 88P Ch. 16 - Prob. 89P Ch. 16 - Prob. 90P Ch. 16 - The intermediate shown here is formed during the...Ch. 16 - Prob. 92P Ch. 16 - Propose a mechanism that accounts for the...Ch. 16 - Catalytic antibodies catalyze a reaction by...Ch. 16 - Prob. 95P

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