A name for given compound needs to be assigned. Concept Introduction: Nomenclature of epoxides : Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods. First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged. Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

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Answer 1

Question

Chapter 13.7, Problem 12CC

(a)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

(b)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

(c)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

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IDENTIFY THE CONFIGURATION OF EACH CHIRAL CENTER IN THE FOLLOWING COMPOUNDS.

Name the given compound. Make sure you include the appropriate configuration for each of the chiral centers.

Name the functional groups and circle any chiral centers in these molecules?

Answer 2

Question

Chapter 13.7, Problem 12CC

(a)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

(b)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

(c)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

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Answer 3

Question

Chapter 13.7, Problem 12CC

(a)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

(b)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

(c)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

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Answer 4

Question

Chapter 13.7, Problem 12CC

(a)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

(b)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

(c)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

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Answer 5

Chapter 13.7, Problem 12CC

(a)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

(b)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

(c)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

Answer 6

Chapter 13.7, Problem 12CC

(a)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

Answer 7

Chapter 13.7, Problem 12CC

(a)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

Answer 8

(b)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

Answer 9

(b)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

Answer 10

(c)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

Answer 11

(c)

Interpretation Introduction

Interpretation: A name for given compound needs to be assigned.

Concept Introduction: Nomenclature of epoxides: Epoxides are cyclic ethers having an oxygen atom incorporated in three-membered ring system having up to four R groups. Due to ring strain, they are more reactive than other ethers. The simplest epoxide does not have any R group and known as ethylene oxide. Naming is done by two methods.

First method- Parent alkane chain is identified and oxygen is considered as substituent on that chain. Location of epoxide group is written with two numbers with suffix epoxy. While naming, epoxy substituents are alphabetically arranged.

Second method: Oxirane ring is considered as parent and groups attached to it are considered as substituents.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 13.2 - Prob. 1LTS Ch. 13.2 - Prob. 1PTS Ch. 13.2 - Prob. 2PTS Ch. 13.2 - Prob. 3ATS Ch. 13.4 - Prob. 4CC Ch. 13.5 - Prob. 2LTS Ch. 13.5 - Prob. 5PTS Ch. 13.5 - Prob. 6ATS Ch. 13.5 - Prob. 7CC Ch. 13.5 - Prob. 8CC

Solution Summary: The author explains that epoxides are cyclic ethers with an oxygen atom incorporated in three-membered ring system having up to four R groups. Naming is done by two methods.

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