Concept explainers
Interpretation:
The structure of three products formed from reaction of toluene with
Concept Introduction:
The electrophilic substitution reactions are the most common reactions of
These reactions occur in the presence of certain catalyst like
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General, Organic, and Biological Chemistry - 4th edition
- When the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction takes place: C6H5NH3+(aq)+CH3COO(aq)C6H5NH2(aq)+CH3COOH(aq) If Kafor C6H5NH3+ is 1.35105 and Kafor CH3COOH is 1.86105 , what is K for the reaction?arrow_forwardIn an esterification reaction, a carboxylic acid reacts with an excess of alcohol in acidic conditions to form an ester. Draw the structure of the ester product in the reaction between pentanoic acid and 1‑propanol.arrow_forwardWhen trans-2-chloro-1-cyclohexanol is treated with a base, cyclohexene oxide is the product. However, when cis-2-chloro-1-cyclohexanol is treated with a base, the product is cyclohexanone. 1. Write the equation for the reaction between trans-2-chloro-1-cyclohexanol and the base to yield the cyclohexene oxide. 2. Why doesn't the cis isomer yield the oxide? 3. Write the mechanism for each of the two reactionsarrow_forward
- Compound A has the molecular formula C7H12. Hydrogenation of compound A produces 2-methylhexane. Hydroboration-oxidation of compound A produces an aldehyde. Draw the structure of compound A.arrow_forwardPropane (CH3CH2CH3) reacts with bromine (Br2) in the presence of ultra-violet (UV) light. Â Draw the displayed formulae of one of the monobrominated organic products formed in this reaction.arrow_forward1,1-dichloropropane reacts with aqueous sodium hydroxide in a series of steps to give propanal. NAOH(aq) CH,CH,CHCI, CH,CH,CHO Which term describes the first step of this reaction? A addition B elimination C oxidation D substitutionarrow_forward
- When the aromatic hydrocarbon naphthalene, reacts with nitric and sulfuric acids, two compounds containing one nitro group are formed. Draw the structures of these two compounds.arrow_forwardComplete the following syntheses – they may be two- or three-step processes. Include any necessary catalysts or reaction conditions. c) Prepare methyl ethanoate from ethanol and methanolarrow_forward1,3-Propanediol, HOCH₂CH₂CH₂OH, is a diol used as a building block in the production of polymers for use in adhesives and coatings. Draw the condensed structure of the most oxidized product formed after the oxidation of 1,3-propanediol.arrow_forward
- Draw the structure and name the product formed if the following alcohols are oxidized. Assume an excess of the oxidizing agent is used. If the alcohol is not expected to react with a chemical oxidizing agent, write NR (no reaction).(a) CH3CH2CH2CH2OH(b) 2-butanol(c) 2-methyl-2-propanol(d) 2-methyl-1-propanolarrow_forward2. An unknown organic compound has the molecular formula C4H&O. It resists oxidation and it can be reduced with H2 to form an alcohol. Draw the structure for the compound and write equations for the reactions described. Name the reactant and product. 3. Draw the structures for 2,3-dimethylhexanal undergoing the following reactions: Oxidation Reduction with H2 Draw the structures for 2-methyl-3-hexanol undergoing the following reactions: Intramolecular dehydration Oxidation Rank the following from lowest to highest boiling point. Explain your ranking. Butanal, 1-butanol, butane Both ethane and ethanol contain 2 carbon atoms. Ethane is a gas at room temperature and is insoluble in water, whereas ethanol is a liquid at room temperature and is very soluble. Explain the reasons for the differences in the properties of these compounds.arrow_forwardThe foul odor of rancid butter is caused by butyric acid, CH3CH2CH2CO2H.(a) Draw the Lewis structure and determine the oxidation number and hybridization for each carbon atom in the molecule.(b) The esters formed from butyric acid are pleasant-smelling compounds found in fruits and used in perfumes. Draw the Lewis structure for the ester formed from the reaction of butyric acid with 2-propanol.arrow_forward
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