Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 13, Problem 13.41UKC
a.
Interpretation Introduction
Interpretation:
IUPAC name for the compound A has to be given.
Concept Introduction:
IUPAC rules for naming
- Longest carbon chain is identified that contains the carboxyl group. Name of the parent
alkane is changed by replacing the “-e” by the suffix “-oic acid”. - Substituents present in the longest carbon chain is entered before the carboxylic acid name. If same substituents are present, then the respective Greek prefix is added before the substituents name.
- Locants are added and the substituents are entered in alphabetical order.
b.
Interpretation Introduction
Interpretation:
Isomer for the compound A has to be drawn that has same
c.
Interpretation Introduction
Interpretation:
Isomer for the compound A has to be drawn that has different functional group.
d.
Interpretation Introduction
Interpretation:
Product that is formed when compound A is treated with
Concept Introduction:
Water soluble salts are obtained as products when a carboxylic acid reacts with base such as sodium hydroxide. Carboxylic acid is converted into carboxylate ion by the transfer of proton to the base. On removal of proton from the carboxylic acid, the conjugate base is formed. Hydroxide ion from base and proton from the acid combines to form neutral water molecule.
e.
Interpretation Introduction
Interpretation:
The product that is formed when the compound A reacts with ethanol in presence of sulfuric acid has to be drawn.
Concept Introduction:
In presence of acid, the carboxylic acid and an alcohol reacts to form ester as product. Acid acts as a catalyst in this reaction. This is known as Fischer esterification reaction. Esterification reaction is an example of substitution reaction because, the
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Answer each question for A and B depicted in the ball-and-stick models.a. What is the IUPAC name for each compound?b. What product is formed when each compound is treated with NaOH?c. Name the products formed in part (b).d. Draw the structure of an isomer that is at least 105 times less acidic than each compound.
Draw the eight constitutional isomers having the molecular formula C5H11Cl.a. Give the IUPAC name for each compound (ignoring R and S designations).b. Classify each alkyl halide as 1°, 2°, or 3°.c. Label any stereogenic centers.d. For each constitutional isomer that contains a stereogenic center, draw all possible stereoisomers, and label each stereogenic center as R or S.
Draw the eight constitutional isomers having the molecular formula C5H11Cl.
a.Give the IUPAC name for each compound (ignoring R and S designations).
b.Classify each alkyl halide as 1°, 2°, or 3°.
c.Label any stereogenic centers.
d.For each constitutional isomer that contains a stereogenic center, draw all possible stereoisomers, and label each stereogenic center as R or S.
Chapter 13 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 13.1 - Draw out each compound to clearly show what groups...Ch. 13.1 - Prob. 13.2PCh. 13.2 - Prob. 13.3PCh. 13.2 - Give the structure corresponding to each IUPAC...Ch. 13.2 - Prob. 13.5PCh. 13.2 - Give the structure corresponding to each name. a....Ch. 13.3 - Which compound in each pair has the higher boiling...Ch. 13.3 - Rank the following compounds in order of...Ch. 13.4 - Which compounds are -hydroxy acids? tartaric acid...Ch. 13.4 - Prob. 13.10P
Ch. 13.5 - Prob. 13.11PCh. 13.5 - Prob. 13.12PCh. 13.5 - Prob. 13.13PCh. 13.6 - Prob. 13.14PCh. 13.6 - Prob. 13.15PCh. 13.6 - Prob. 13.16PCh. 13.6 - Prob. 13.17PCh. 13.6 - Prob. 13.18PCh. 13.6 - Prob. 13.19PCh. 13.7 - Prob. 13.20PCh. 13.7 - Prob. 13.21PCh. 13.7 - Prob. 13.22PCh. 13.7 - Prob. 13.23PCh. 13.7 - Prob. 13.24PCh. 13.8 - Prob. 13.25PCh. 13.8 - Prob. 13.26PCh. 13.8 - Prob. 13.27PCh. 13.8 - Draw the product formed when each ammonium salt is...Ch. 13.8 - Prob. 13.29PCh. 13.9 - Prob. 13.30PCh. 13.9 - Prob. 13.31PCh. 13.9 - Prob. 13.32PCh. 13.9 - Why is the boiling point of CH3CONH2(221C) higher...Ch. 13.9 - Prob. 13.34PCh. 13.9 - Prob. 13.35PCh. 13.10 - Prob. 13.36PCh. 13 - Prob. 13.37UKCCh. 13 - Prob. 13.38UKCCh. 13 - Prob. 13.39UKCCh. 13 - Prob. 13.40UKCCh. 13 - Prob. 13.41UKCCh. 13 - Prob. 13.42UKCCh. 13 - Prob. 13.43UKCCh. 13 - Prob. 13.44UKCCh. 13 - Prob. 13.45UKCCh. 13 - Prob. 13.46UKCCh. 13 - Prob. 13.47UKCCh. 13 - Prob. 13.48UKCCh. 13 - Prob. 13.49UKCCh. 13 - Prob. 13.50UKCCh. 13 - Prob. 13.51APCh. 13 - Prob. 13.52APCh. 13 - Prob. 13.53APCh. 13 - Draw the structure of a compound of molecular...Ch. 13 - Prob. 13.55APCh. 13 - Prob. 13.56APCh. 13 - Give an acceptable name for each compound.Ch. 13 - Prob. 13.58APCh. 13 - Prob. 13.59APCh. 13 - Prob. 13.60APCh. 13 - Prob. 13.61APCh. 13 - Prob. 13.62APCh. 13 - Prob. 13.63APCh. 13 - Give an acceptable name for each amine or amide....Ch. 13 - Draw the structure corresponding to each name. a....Ch. 13 - Draw the structure corresponding to each name. a....Ch. 13 - Prob. 13.67APCh. 13 - Draw the structure of each amine or ammonium salt....Ch. 13 - Prob. 13.69APCh. 13 - Which compound in each pair is more water soluble?...Ch. 13 - Prob. 13.71APCh. 13 - Prob. 13.72APCh. 13 - Prob. 13.73APCh. 13 - Prob. 13.74APCh. 13 - Prob. 13.75APCh. 13 - Prob. 13.76APCh. 13 - Prob. 13.77APCh. 13 - Prob. 13.78APCh. 13 - Prob. 13.79APCh. 13 - Prob. 13.80APCh. 13 - Prob. 13.81APCh. 13 - Prob. 13.82APCh. 13 - Prob. 13.83APCh. 13 - Prob. 13.84APCh. 13 - Prob. 13.85APCh. 13 - Prob. 13.86APCh. 13 - Prob. 13.87APCh. 13 - Draw the products of each acid-base reaction.Ch. 13 - Prob. 13.89APCh. 13 - Prob. 13.90APCh. 13 - Prob. 13.91APCh. 13 - Prob. 13.92APCh. 13 - Ritalin is the trade name for methylphenidate, a...Ch. 13 - Prob. 13.94APCh. 13 - Prob. 13.95CPCh. 13 - Prob. 13.96CPCh. 13 - Prob. 13.97CPCh. 13 - Prob. 13.98BTCCh. 13 - Prob. 13.99BTCCh. 13 - Prob. 13.100BTC
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Draw the products of each combustion reaction.arrow_forwardAnswer the following questions about the carbohydrate erythrulose, an ingredient in sunless tanning agents. erythrulose a. Does erythrulose contain an aldehyde or ketone? b. Classify each hydroxyl group as 1 °, 2 °, or 3 °. c. What product is formed when erythrulose is treated with Tollens reagent? d. What product is formed when erythrulose is treated with K 2Cr 2O 7?arrow_forwardk Draw the products of the two step reaction sequence shown below. Ignore inorganic byproducts. If the reaction results in a mixture of ortho and para isomers, draw only the para-product. AICI 3 CH3C(=O)CI (1 equiv) Select to Draw Q I I I I I Problem 36 of 19 Please select a drawing or reagent from the question areaarrow_forward
- Answer each question using the ball-and-stick model of compound A.a.Give the IUPAC name for A, including R,S designations for stereogenic centers. b.Classify A as a 1°, 2°, or 3° alcohol. c.Draw a stereoisomer for A and give its IUPAC name. d.Draw a constitutional isomer that contains an OH group and give its IUPAC name. e.Draw a constitutional isomer that contains an ether and give its IUPAC name. f.Draw the products formed (including stereochemistry) when A is treated with each reagent: [1] NaH; [2] H2SO4; [3] POCl3, pyridine; [4] HCl; [5] SOCl2, pyridine; [6] TsCl, pyridinearrow_forwardb. a. C. HO Draw the products of each reaction. COOH COOH + NaOCH3 OH OH H₂SO4 H₂SO4arrow_forwardAnswer each question using the ball-and-stick model of compound A. a. Give the IUPAC name for A, including R,S designations for stereogenic centers. b. Classify A as a 1°, 2°, or 3° alcohol. c. Draw a stereoisomer for A and give its IUPAC name. d. Draw a constitutional isomer that contains an OH group and give its IUPAC name. e. Draw a constitutional isomer that contains an ether and give its IUPAC name. f. Draw the products formed (including stereochemistry) when A is treated with each reagent: [1] NaH; [2] H2SO4; [3] POCI,, pyridine; [4] HCl; [5] SOCI, pyridine; [6] TSCI, pyridine. Aarrow_forward
- Draw the products formed when phenol(C6H5OH) is treated with each reagent. Give an explanation. d. (CH3CH2)2CHCOCl, AlCl3 j. product in (d), then NH2NH2, – OHarrow_forwardGive the IUPAC name for each compound. CH3 CH2CH3 Br a. PHCH(CH3)2 b. С. d.arrow_forwardMaltose is a carbohydrate present in malt, the liquid obtained from barley and other grains. Although maltose has numerous functional groups, its reactions are explained by the same principles we have already encountered.a. Label the acetal and hemiacetal carbons.b. What products are formed when maltose is treated with each of these reagents: [1] H3O+; [2] CH3OH and HCl; [3] excess NaH, then excess CH3I?c. Draw the products formed when the compound formed in Reaction [3] of part (b) is treated with aqueous acid.The reactions in parts (b) and (c) are used to determine structural features of carbohydrates like maltose.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License