EBK ORGANIC CHEMISTRY-PRINT COMPANION (
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 1.12, Problem 29ATS
Interpretation Introduction

Interpretation: Whether diphenyl ether exhibits molecular dipole moment or not should be identified and if it does then the direction of the net molecular dipole moment must be indicated.

Concept Introduction: The arrangement of electron pairs is identified according to VSEPR (Valence Shell Electron Pair Repulsion) theory wherein all the electron pairs are aligned in such a way that they are at maximum distance from each other. The structure of every molecule in VSEPR is explained by considering the steric number (combination of lone pairs and σ -bonds involved in molecule).

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4. Octatetraene, C8H10, is an 8-membered linear carbon chain with alternating single and double bonds. As a result, each carbon is left with an unhybridized p-orbital containing one electron. This problem will take you through steps to construct and fill the molecular orbital diagram for octatetraene based on the way these different p-orbitals can come together.  a)  The various molecular orbitals formed from octatetraene’s 8 unhybridized p-orbitals are shown on the next page. Draw the nodal planes for each molecular orbital.  Hint: A nodal plane is a line through the molecule that denotes the sites of destructive interference. An example is shown below with ethylene.  b)  Based  on  the  nodal  planes,  arrange  the  energy  levels  corresponding  to  the  8  molecular orbitals  on  the  energy  level  diagram  (label  them using  the  numbering  provided  on  the  left side of the molecular orbitals) on the next page, in order of lowest to highest energy. c) Populate your molecular…
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