EBK ORGANIC CHEMISTRY-PRINT COMPANION (
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 1.13, Problem 11LTS
Interpretation Introduction

Interpretation: The compound that has higher boiling point should be identified amongst neopentane or 3-hexanol.

Concept Introduction: The temperature at which transition of a substance takes place from liquid to gaseous state is said to be its boiling point. At boiling point, the vapor pressure and applied pressure on the liquid become equal. There is a direct relationship between the interaction present in molecule and the boiling point of the molecule. The molecule that has stronger interaction between its atoms/molecules possess higher boiling point and vice-versa.

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Ethanol (CH3CH2OH) and dimethyl ether (CH3OCH3) are constitutional isomers. (a) Predict which of the two has the higher boiling point. (b) Predict which of the two is more soluble in water.
Cyclopentane has a higher boiling point than pentane even though both compounds have the same number of carbons (49 °C vs. 36 °C). Can you suggest a reason for this phenomenon?
thanol (CH3CH2OH) and dimethyl ether (CH3OCH3) are constitutional isomers. Q) Predict which of the two is more soluble in water.
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