(a)
Interpretation:Considering the spectral data for cyclohxene, the absorptions which are associated with the carbon-carbon double bond and the vinylic hydrogen atoms should be specified.
Concept Introduction : The analysis of the interaction of infrared light with a molecule is termed as infrared spectroscopy. The main use of infrared spectroscopy is the identification of
(b)
Interpretation:To assign the various resonances to the hydrogen nuclei that is responsible for them in
Concept Introduction : Nuclear magnetic resonance (NMR) is a spectroscopy technique that works on the basis that the nucleus of the atoms absorbs
(c)
Interpretation:To assign various resonances to carbon nuclei responsible for them in the
Concept Introduction : Carbon-13 NMR has several merits over proton NMR in terms of its power to explainbiochemical and organic structures. Carbon-13 NMR provides information relatedto the backbone of molecules instead of the periphery. In addition, the chemical shift range for Carbon-13 for most organic compounds is around 200 ppm related with 10 to 15 ppm for the proton.
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EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
- 5. MULTISTEP SYNTHESIS: Provide a synthesis for the formation of the following compounds using benzene as a starting material and any other reagents you need. Use numbers in your answer for the proper sequence of reagents that you would use. Note: you are only being asked to provide the reagents to prepare each of these compounds from benzene. a. -Brarrow_forwardWrite the reaction involved in Ferrox Test. a. What is the species responsible? b. Why is phenol negative in Ferrox Test? Based on the theoretical result, what is the order of reactivity of primary, secondary, and tertiary alcohols in the Lucas Test? a. Lucas Reagent contains ZnCl2 in HCl. What is the role of ZnCl2? What reagents are used in the esterification of Alcohols and Phenols? a. Write the reaction involved in Primary Alcohol (Ethanol) and Acetyl Chloride b. Write the reaction involved in Phenol and Acetyl Chloride What is the purpose of the Chromic acid test? a. What are the reagents used? b. Write oxidation reaction of Primary Alcohols and Secondary Alcoholsarrow_forwardWhich of the following statements is correct?A. The haloform reaction proceeds under very difficult conditions and the yield is very low.B. The haloform reaction is used only for the identification of compounds containing secondary alcohol groups.C. Methyl ketones or alcohols are oxidized by halogens in acidic solutions to give carboxylic acids and the corresponding haloform product.D. Enolate anions react rapidly with halogens to give alpha-halocarbonyl compounds.arrow_forward
- Which of the following statements is correct? A. The haloform reaction proceeds under very difficult conditions and the yield is very low. B. The haloform reaction is used only for the identification of compounds containing secondary alcohol groups. C. Methyl ketones or alcohols are oxidized by halogens in acidic solutions to give carboxylic acids and the corresponding haloform product. D. Enolate anions react rapidly with halogens to give alpha-halocarbonyl compounds.arrow_forwardexplain some of the hazards (name at least three) involved in the Friedel-Crafts Acylation: Synthesis of 4-methoxyacetophenone from anisole experiment. What are some necessary safety precautions when working with aluminum chloride? List compounds that react in a hazardous manner with aluminum chloride and are therefore incompatible. What hazardous by-products are formed in this experiment? Why is it necessary to perform this experiment in the fume hood?arrow_forwardMaterials • 1-butanol • 2-butanol • 2-methyl-2-propanol • 3 mol/L H2SO4 (aq) • 3 mol/L NaOH • 0.01 mol/L KMNO4 • concentrated (12 mol/L) HCl (aq) for demonstration use only • distilled water • 10 mL graduated cylinders or graduated medicine droppers • test tubes • test-tube rack Procedure Part 1: The comparison of three isomeric alcohols reactions with potassium permanganate 1. Construct an observation table with the following headings. Alcohol Observations at 1 minute Observations at 5 mins 1-Butanol 2-Butanol 2-Methylpropanolarrow_forward
- In a Grignard synthesis of benzoic acid experiment, a student determines that their crude product was a mixture of benzoic acid and benzene. Describe a series of extractions using the following solvents and solutions to get pure benzoic acid or its salt in an ether solution. A. Methyl tert-butyl ether (MTBE) B. 3M HCl C. 3M NaOHarrow_forward1. Summarize the essential properties of nucleophilic acyl substitution. 2. Select one carboxylic acid that can be used in clinical diagnostic testing, nutritional research, or pharmacological studies. Give an explanation as to how the molecular property influences the bulk property of the carboxylic acid.arrow_forwardNitration of furan with acetylnitrate leads to 2,5-dinitrofuran. Mononitration can be done by A. carrying out the reaction at higher temperature. B. using nitric acid instead of acetyl nitrate. C. carrying out the nitration in the presence of pyridine D. using concentrated nitric acid/sulfuric acid instead of acetyl nitrate.arrow_forward
- What are the major products from the reaction of methyl butanoate with diisobutylaluminum hydride at negative seventy-eight degrees Celsius, followed by acidic work-up? a. butanal and methanol b. butanal and ethanol c. butanoate and methane d. butyric acid and methanol e. butanoate and hydrogen gasarrow_forwardExplain the experimental procedure of the laboratory preparation of the synthesis of benzyl chloride from phenol (paragraph form) Explain the chemistry behind the synthesis of benzyl chloride from phenol (paragraph form)arrow_forwardThe following tests or reagents could differentiate 2,3-dimethylheptane and 2,3-dimethylhepta-1,5-diene EXCEPT a. Baeyer's Test b. Br2 in water under dark conditions c. Friedel-Crafts Alkylation Test d. Combustion The following statements about anthracene are true EXCEPT: a. It gives a negative result in Baeyer's test b. It produces a yellow, smoky, sooty flame c. It is insoluble in cold H2SO4. d. It reacts with bromine under dark conditions.arrow_forward
- Macroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole