Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 3, Problem 3.91AP
(a)
Interpretation Introduction
Interpretation:
Lone pairs have to added to the nitrogen and oxygen atoms. The shape of nitrogen and oxygen around the indicated atom in the given molecule has to be given.
The given molecule is,
(b)
Interpretation Introduction
Interpretation:
Lone pairs have to added oxygen atoms. The shape of carbon around the indicated atom in the given molecule has to be given.
The given molecule is,
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Draw three resonance structures for N3-. This species has its three atoms bonded sequentially in the following fashion: N-N-N. Draw your resonance structures so that the atoms in them are bonded together in this order. Select the most important resonance structure for this species based on the formal charges on the atoms of the three resonance structures you have drawn. Now select the statement from the multiple choices which is true about this most important resonance structure.In the most important resonance structure of N3- :
a) The leftmost bond (between N and N) is a single bond.
b) The rightmost bond (between N and N) is a single bond.
c) The formal charge on the leftmost (N) atom is -1.
d) The number of nonbonding pairs (lone pairs) of electrons on the leftmost (N) atom is 4.
e) The number of nonbonding (lone) pairs of electrons on the rightmost (N) atom is 4.
Distribute the electrons among the atoms, giving octets (or duets for hydrogen) to as many atoms as possible. Begin with the bonding electrons, and then proceed to lone pairs on terminal atoms, and finally to lone pairs on the central atom.
Draw three resonance structures for N3-. This species has its three atoms bonded sequentially in the following fashion: N-N-N. Draw your resonance structures so that the atoms in them are bonded together in this order. Select the most important resonance structure for this species based on the formal charges on the atoms of the three resonance structures you have drawn. Now select the statement from the multiple choices which is true about this most important resonance structure.In the most important resonance structure of N3- :
a) The leftmost bond (between N and N) is a single bond.b) The rightmost bond (between N and N) is a single bond.c) The formal charge on the leftmost (N) atom is -1.d) The number of nonbonding pairs (lone pairs) of electrons on the leftmost (N) atom is 4.e) The number of nonbonding (lone) pairs of electrons on the rightmost (N) atom is 4.
Chapter 3 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 3.1 - Predict whether the bonds in the following species...Ch. 3.2 - Write the ion symbol for an atom with the given...Ch. 3.2 - Prob. 3.4PCh. 3.2 - Prob. 3.5PCh. 3.2 - How many electrons and protons are contained in...Ch. 3.2 - Prob. 3.7PCh. 3.3 - Write the formula for the ionic compound formed...Ch. 3.3 - Prob. 3.9PCh. 3.4 - Prob. 3.10PCh. 3.4 - Give the symbol for each ion. a. stannous b....
Ch. 3.4 - Name each ionic compound. a. NaF b. MgO c. SrBr2...Ch. 3.4 - Name each ionic compound. a. CrCl3 b. PbS c. SnF4...Ch. 3.4 - Prob. 3.14PCh. 3.5 - List four physical properties of ionic compounds.Ch. 3.6 - Write the formula for the compound formed when K+...Ch. 3.6 - Prob. 3.17PCh. 3.6 - Name each compound. a. Na2CO3 b. Ca(OH)2 c....Ch. 3.6 - Prob. 3.19PCh. 3.7 - Use electron-dot symbols to show how a hydrogen...Ch. 3.7 - Prob. 3.21PCh. 3.8 - Draw a Lewis structure for each covalent molecule....Ch. 3.8 - Prob. 3.23PCh. 3.8 - Prob. 3.24PCh. 3.9 - Prob. 3.25PCh. 3.9 - Prob. 3.26PCh. 3.10 - Prob. 3.27PCh. 3.11 - Prob. 3.28PCh. 3.11 - Prob. 3.29PCh. 3.11 - Show the direction of the dipole in each bond....Ch. 3.12 - Prob. 3.31PCh. 3.12 - Prob. 3.32PCh. 3 - Which formulas represent ionic compounds and which...Ch. 3 - Which pairs of elements are likely to form ionic...Ch. 3 - Prob. 3.35UKCCh. 3 - Prob. 3.36UKCCh. 3 - Prob. 3.37UKCCh. 3 - Prob. 3.38UKCCh. 3 - Prob. 3.39UKCCh. 3 - Prob. 3.40UKCCh. 3 - Prob. 3.41UKCCh. 3 - Prob. 3.42UKCCh. 3 - Prob. 3.43UKCCh. 3 - Prob. 3.44UKCCh. 3 - Prob. 3.45UKCCh. 3 - Prob. 3.46UKCCh. 3 - (a) Translate each ball-and-stick model to a Lewis...Ch. 3 - Prob. 3.48UKCCh. 3 - Prob. 3.49APCh. 3 - How many protons and electrons are present in each...Ch. 3 - Prob. 3.51APCh. 3 - Prob. 3.52APCh. 3 - Prob. 3.53APCh. 3 - Give the ion symbol for each ion. a. barium ion b....Ch. 3 - Prob. 3.65APCh. 3 - Write the formula for the ionic compound formed...Ch. 3 - Prob. 3.67APCh. 3 - Prob. 3.68APCh. 3 - Name each ionic compound. a. Na2O b. BaS c. PbS2...Ch. 3 - Name each ionic compound. a. KF b. ZnCl2 c. Cu2S...Ch. 3 - Prob. 3.71APCh. 3 - Write formulas to illustrate the difference...Ch. 3 - Prob. 3.73APCh. 3 - Name each ionic compound. a. (NH4)2SO4 b. NaH2PO4...Ch. 3 - Prob. 3.75APCh. 3 - Prob. 3.76APCh. 3 - Prob. 3.77APCh. 3 - Label each statement as true or false. Correct any...Ch. 3 - Prob. 3.79APCh. 3 - Prob. 3.80APCh. 3 - Prob. 3.81APCh. 3 - Prob. 3.82APCh. 3 - Convert the 3-D model of oxalic acid into a Lewis...Ch. 3 - Convert the 3-D model of the general anesthetic...Ch. 3 - Prob. 3.85APCh. 3 - Prob. 3.86APCh. 3 - Prob. 3.87APCh. 3 - Prob. 3.88APCh. 3 - Prob. 3.89APCh. 3 - Prob. 3.90APCh. 3 - Prob. 3.91APCh. 3 - Prob. 3.92APCh. 3 - Prob. 3.93APCh. 3 - Prob. 3.94APCh. 3 - Rank the atoms in each group in order of...Ch. 3 - Prob. 3.96APCh. 3 - Prob. 3.97APCh. 3 - Prob. 3.98APCh. 3 - Prob. 3.99APCh. 3 - Which bond in each pair is more polarthat is, has...Ch. 3 - Prob. 3.101APCh. 3 - Prob. 3.102APCh. 3 - Isobutyl cyanoacrylate is used in medical glues to...Ch. 3 - Prob. 3.104APCh. 3 - Prob. 3.105CPCh. 3 - Prob. 3.106CP
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- Write the Lewis structure for nitrosyl fluoride, FNO. Using only a periodic table, identify (a) which is the longer bond. (b) which is the stronger bond. (c) which is the more polar bond.arrow_forwardUse Lewis symbols to show the reaction of atoms to form hydrogen selenide. H2Se. Indicate bonding pairs and lone pairs in the electron-dot formula of this compound.arrow_forwardAspirin is made from salicylic acid, which has this Lewis structure: (a) Which is the longest carbon-carbon bond? (b) Which is the strongest carbon-oxygen bond? (c) Draw resonance structures for this molecule.arrow_forward
- Add lone pairs to the N and O atoms to give octets and then determine the shape around each indicated atom.arrow_forwardWhat determines which atoms are the central atoms? How do you adjust the number of electrons to form a cation? What about an anion? What causes some molecules with the same number of electron domains to have different shapes? Would they cause the real bond angle to be larger or smaller? Why? Which of the following elements should you expect to form an incomplete octet: H, He, Be, B, C, O? Why? Which of the following elements are good candidates to form an expanded octet: N, F, Ne, P, S, Cl, Ar? Why? What things must you consider when determining if a molecule is polar or non-polar?arrow_forwardASK YOUR TEACHER Draw three resonance structures for N2O. This species has its three atoms bonded sequentially in the following fashion: N-N-O. Draw your resonance structures so that the atoms in them are bonded together in this order. Select the most important resonance structure for this species based on the formal charges on the atoms of the three resonance structures you have drawn. Now select the statement from the multiple choices which is true about this most important resonance structure.In the most important resonance structure of N2O : a) The leftmost bond (between N and N) is a triple bond.b) The rightmost bond (between N and O) is a double bond.c) The formal charge on the leftmost (N) atom is +1.d) The number of nonbonding pairs (lone pairs) of electrons on the leftmost (N) atom is 4.e) The number of nonbonding (lone) pairs of electrons on the rightmost (O) atom is 2.arrow_forward
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