Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 3, Problem 3.48UKC
(a)
Interpretation Introduction
Interpretation:
A Lewis structure of the molecule 1,1-dichloroethylene and tetrafluoroethylene has to be drawn.
(b)
Interpretation Introduction
Interpretation:
The polar bonds in tetrafluoroethylene and 1,1-dichloroethylene have to be labeled.
(c)
Interpretation Introduction
Interpretation:
The polarity of the molecule tetrafluoroethylene and 1,1-dichloroethylene has to be given.
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ii.
Answer true or false.
(a) A covalent bond is formed between two atoms whose difference in electronegativity is less
than 1.9.
(b) If the difference in electronegativity between two atoms is zero (they have identical
electronegativities), then the two atoms will not form a covalent bond.
(c) A covalent bond formed by sharing two electrons is called a double bond.
(d) In the hydrogen molecule (H2), the shared pair of electrons completes the valence shell of
each hydrogen.
(e) In the molecule CH4, each hydrogen has an electron configuration like that of helium, and
carbon has an electron configuration like that of neon.
(f) In a polar covalent bond, the more electronegative atom has a partial negative charge (8-)
and the less electronegative atom has a partial positive charge (&+).
(g) These bonds are arranged in order of increasing polarity C-H
Answer true or false.
(a) According to the Lewis model of bonding, atoms bond together in such a way that each atom par- ticipating in the bond acquires an outer-shell electron configuration matching that of the noble gas nearest to it in atomic number.
(b) Atoms that lose electrons to achieve a filled valence shell become cations and form ionic bonds with anions.
(c) Atoms that gain electrons to achieve filled valence shells become anions and form ionic bonds with cations.
(d) Atoms that share electrons to achieve filled valence shells form covalent bonds.
(e) Ionic bonds tend to form between elements on the left side of the Periodic Table, and covalent bonds tend to form between elements on the right side of the Periodic Table.
(f) Ionic bonds tend to form between a metal and a nonmetal.
(g) When two nonmetals combine, the bond between them is usually covalent.
(h) Electronegativity is a measure of an atom’s attrac- tion for the electrons it shares in a chemical bond with another…
Consider the formate ion, HCO2", which is the anion
formed when formic acid loses an H* ion. The H and
the two O atoms are bonded to the central C atom.
(a) Draw the best Lewis structure(s) for this ion.
(b) Are resonance structures needed to describe the
structure? Explain briefly
(c) Would you predict that the C-O bond lengths in
the formate ion would be longer or shorter relative to
those in CO2? Explain briefly
Chapter 3 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 3.1 - Predict whether the bonds in the following species...Ch. 3.2 - Write the ion symbol for an atom with the given...Ch. 3.2 - Prob. 3.4PCh. 3.2 - Prob. 3.5PCh. 3.2 - How many electrons and protons are contained in...Ch. 3.2 - Prob. 3.7PCh. 3.3 - Write the formula for the ionic compound formed...Ch. 3.3 - Prob. 3.9PCh. 3.4 - Prob. 3.10PCh. 3.4 - Give the symbol for each ion. a. stannous b....
Ch. 3.4 - Name each ionic compound. a. NaF b. MgO c. SrBr2...Ch. 3.4 - Name each ionic compound. a. CrCl3 b. PbS c. SnF4...Ch. 3.4 - Prob. 3.14PCh. 3.5 - List four physical properties of ionic compounds.Ch. 3.6 - Write the formula for the compound formed when K+...Ch. 3.6 - Prob. 3.17PCh. 3.6 - Name each compound. a. Na2CO3 b. Ca(OH)2 c....Ch. 3.6 - Prob. 3.19PCh. 3.7 - Use electron-dot symbols to show how a hydrogen...Ch. 3.7 - Prob. 3.21PCh. 3.8 - Draw a Lewis structure for each covalent molecule....Ch. 3.8 - Prob. 3.23PCh. 3.8 - Prob. 3.24PCh. 3.9 - Prob. 3.25PCh. 3.9 - Prob. 3.26PCh. 3.10 - Prob. 3.27PCh. 3.11 - Prob. 3.28PCh. 3.11 - Prob. 3.29PCh. 3.11 - Show the direction of the dipole in each bond....Ch. 3.12 - Prob. 3.31PCh. 3.12 - Prob. 3.32PCh. 3 - Which formulas represent ionic compounds and which...Ch. 3 - Which pairs of elements are likely to form ionic...Ch. 3 - Prob. 3.35UKCCh. 3 - Prob. 3.36UKCCh. 3 - Prob. 3.37UKCCh. 3 - Prob. 3.38UKCCh. 3 - Prob. 3.39UKCCh. 3 - Prob. 3.40UKCCh. 3 - Prob. 3.41UKCCh. 3 - Prob. 3.42UKCCh. 3 - Prob. 3.43UKCCh. 3 - Prob. 3.44UKCCh. 3 - Prob. 3.45UKCCh. 3 - Prob. 3.46UKCCh. 3 - (a) Translate each ball-and-stick model to a Lewis...Ch. 3 - Prob. 3.48UKCCh. 3 - Prob. 3.49APCh. 3 - How many protons and electrons are present in each...Ch. 3 - Prob. 3.51APCh. 3 - Prob. 3.52APCh. 3 - Prob. 3.53APCh. 3 - Give the ion symbol for each ion. a. barium ion b....Ch. 3 - Prob. 3.65APCh. 3 - Write the formula for the ionic compound formed...Ch. 3 - Prob. 3.67APCh. 3 - Prob. 3.68APCh. 3 - Name each ionic compound. a. Na2O b. BaS c. PbS2...Ch. 3 - Name each ionic compound. a. KF b. ZnCl2 c. Cu2S...Ch. 3 - Prob. 3.71APCh. 3 - Write formulas to illustrate the difference...Ch. 3 - Prob. 3.73APCh. 3 - Name each ionic compound. a. (NH4)2SO4 b. NaH2PO4...Ch. 3 - Prob. 3.75APCh. 3 - Prob. 3.76APCh. 3 - Prob. 3.77APCh. 3 - Label each statement as true or false. Correct any...Ch. 3 - Prob. 3.79APCh. 3 - Prob. 3.80APCh. 3 - Prob. 3.81APCh. 3 - Prob. 3.82APCh. 3 - Convert the 3-D model of oxalic acid into a Lewis...Ch. 3 - Convert the 3-D model of the general anesthetic...Ch. 3 - Prob. 3.85APCh. 3 - Prob. 3.86APCh. 3 - Prob. 3.87APCh. 3 - Prob. 3.88APCh. 3 - Prob. 3.89APCh. 3 - Prob. 3.90APCh. 3 - Prob. 3.91APCh. 3 - Prob. 3.92APCh. 3 - Prob. 3.93APCh. 3 - Prob. 3.94APCh. 3 - Rank the atoms in each group in order of...Ch. 3 - Prob. 3.96APCh. 3 - Prob. 3.97APCh. 3 - Prob. 3.98APCh. 3 - Prob. 3.99APCh. 3 - Which bond in each pair is more polarthat is, has...Ch. 3 - Prob. 3.101APCh. 3 - Prob. 3.102APCh. 3 - Isobutyl cyanoacrylate is used in medical glues to...Ch. 3 - Prob. 3.104APCh. 3 - Prob. 3.105CPCh. 3 - Prob. 3.106CP
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