General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Textbook Question
Chapter 26, Problem 38E
Supply condensed structural formulas for the following substances.
a. o-tert-butylphenol (an antioxidant in aviation gasoline)
b. 1 -phenylpropan-2-
c. 2-methylheptadecane (a sex pheromone of tiger moths-a chemical used for communication among members of the species) [Hint: Heptadeca means 17.]
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16. An atom or group of atoms that can give organic compounds distinct chemical and physical properties.
21. When a compound with the general formula R-COOH loses a proton, the product that remains is described with this term. Its general formula is R-COO-
24. A class of organic compounds in which three or more carbons form a ring structure. All of the carbon-to-carbon bonds are single bonds in this family of compounds.
One way of naming amines is to name in alphabetical order the alkyl groups attached to the nitrogen
atom, using the prefixes di- and tri- if the groups are the same. An example is isopropylamine,
whose formula is shown above. What are names for (a.), (b.), (c.), and (d.)?
H
NMe,
(a)
(b)
(c)
Me
(d)
Write bond-line formulas for:
(e.) propylamine, (f.) trimethylamine, and (g.) ethylisopropylmethylamine
Which amines in Problem 16 are (a.) primary amines, (b.) secondary amines, and (c) tertiary amines?
give the nomenclature or the structure of the following molecules of item #21 to #25.
Chapter 26 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 26 - Prob. 1ECh. 26 - Draw a structural formula for each of the...Ch. 26 - Prob. 3ECh. 26 - Write structural formulas corresponding to these...Ch. 26 - Prob. 5ECh. 26 - Prob. 6ECh. 26 - Prob. 7ECh. 26 - Prob. 8ECh. 26 - What is the relationship, if any, between the...Ch. 26 - Prob. 10E
Ch. 26 - Prob. 11ECh. 26 - Prob. 12ECh. 26 - Identify the chiral carbon atoms, ¡f any, in the...Ch. 26 - Prob. 14ECh. 26 - Identify the chiral carbon atoms, ¡f any, in the...Ch. 26 - Prob. 16ECh. 26 - Prob. 17ECh. 26 - Prob. 18ECh. 26 - Prob. 19ECh. 26 - By name or formula, give one example of each of...Ch. 26 - Prob. 21ECh. 26 - Prob. 22ECh. 26 - Prob. 23ECh. 26 - Prob. 24ECh. 26 - Prob. 25ECh. 26 - Prob. 26ECh. 26 - Prob. 27ECh. 26 - Prob. 28ECh. 26 - Prob. 29ECh. 26 - Prob. 30ECh. 26 - Prob. 31ECh. 26 - Prob. 32ECh. 26 - Prob. 33ECh. 26 - Prob. 34ECh. 26 - Does each of the following names convey sufficient...Ch. 26 - Prob. 36ECh. 26 - Prob. 37ECh. 26 - Supply condensed structural formulas for the...Ch. 26 - Prob. 39ECh. 26 - Prob. 40ECh. 26 - Classify the carbon atoms in, a. methylbutane, and...Ch. 26 - Classity the carbon atoms in a....Ch. 26 - Prob. 43ECh. 26 - Draw Newman projections for the staggered and...Ch. 26 - Draw the most stable conformation for the molecule...Ch. 26 - Prob. 46ECh. 26 - Prob. 47ECh. 26 - Prob. 48ECh. 26 - Prob. 49ECh. 26 - Prob. 50ECh. 26 - Prob. 51ECh. 26 - Prob. 52ECh. 26 - Prob. 53ECh. 26 - Prob. 54ECh. 26 - Prob. 55ECh. 26 - Prob. 56ECh. 26 - Draw suitable structural formulas to show that...Ch. 26 - Which of the following pairs of molecules are...Ch. 26 - Prob. 59ECh. 26 - Prob. 60ECh. 26 - Name the following molecules with the appropriate...Ch. 26 - Name the following molecules with the appropriate...Ch. 26 - Name the following molecules with the appropriate...Ch. 26 - Prob. 64ECh. 26 - Draw the structure for each of the following. a....Ch. 26 - Prob. 66ECh. 26 - Prob. 67ECh. 26 - Prob. 68ECh. 26 - Prob. 69ECh. 26 - Prob. 70ECh. 26 - Prob. 71ECh. 26 - Prob. 72ECh. 26 - Prob. 73ECh. 26 - Prob. 74ECh. 26 - Supply condensed or structural formulas for the...Ch. 26 - Prob. 76IAECh. 26 - Prob. 77IAECh. 26 - Prob. 78IAECh. 26 - Prob. 79IAECh. 26 - Prob. 80IAECh. 26 - Combustion of a 0.1908 g sample of a compound gave...Ch. 26 - Prob. 82IAECh. 26 - In the monochiorination of hydrocarbons, a...Ch. 26 - A particular colorless organic liquid is known to...Ch. 26 - Prob. 85IAECh. 26 - Give the systematic names, including any...Ch. 26 - Prob. 87IAECh. 26 - Prob. 88IAECh. 26 - Levomethadyl acetate (shown below) is used in the...Ch. 26 - Thiamphenicol (shown below) is an antibacterial...Ch. 26 - Prob. 91IAECh. 26 - Prob. 92IAECh. 26 - Prob. 93IAECh. 26 - Prob. 94IAECh. 26 - Prob. 95IAECh. 26 - For each of the following molecules (a) draw the...Ch. 26 - Prob. 97FPCh. 26 - Prob. 98SAECh. 26 - Explain the important distinctions between each...Ch. 26 - Describe the characteristics of each of the...Ch. 26 - The compound isoheptane is best represented by the...Ch. 26 - Prob. 102SAECh. 26 - Prob. 103SAECh. 26 - Prob. 104SAECh. 26 - Assign configurations, R or S, to the chiral...Ch. 26 - Consider the following pairs of structures In each...Ch. 26 - Prob. 107SAECh. 26 - Prob. 108SAECh. 26 - Prob. 109SAECh. 26 - Prob. 110SAECh. 26 - Prob. 111SAE
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- 1. Give two organic compounds. The first compound must be a synthetic or man-made organic compound and the second compound must be a natural product or organic compound from natural sources (medicinal plant, coral, animal such as snail or microorganism such as bacteria or fungi). Compounds must have equal to or more than twenty carbon atoms. 2. Your chosen organic compound must have application in the management of human health or veterinary medicine. (for example for the treatment of pain or bacterial infection in human and animal).arrow_forwardBONUS. What is a functional group? Explain why it is helpful for organic chemists to classify molecules according to their functional groups?arrow_forwarda) Organic compounds can be classified even based upon the functional groups and structural formulae. i. Which among the following is not an example of alicyclic compound? a) Cyclohexane b) Cyclohexene c) Acetic acidarrow_forward
- Differentiate cis/trans, and E/Z isomerism. What is the importance of isomerism in drug development, cite example.arrow_forwardWhich organic functional group? Carboxylic acid, amine, alcohol, aldehyde, ether, or ketone?arrow_forward6. Write the structure of the following compounds. a. 4 - ethyl - 2 - hexoneb. 2-ethyl - 3 – pentanoic acidarrow_forward
- 2. Some students confuse the ester and ether functional groups. Both linkages are formed by condensation reactions. a) Complete this statement: An ether linkage is formed by the condensation of: b) Use structures to show the condensation of cyclohexanol molecules to create the alternate synthesis product discussed in the report sheet of your Dehydration experiment (Lab 04).arrow_forwardGive the general structures of an ester, carboxylic acid, and alcohol. If you aregiven each sample or these compounds with comparable size, arrange thenaccording to decreasing boiling points.arrow_forwardQuestion 6 Identify the organic class to which the compound belongs based on the functional groups present. [Hint - Organic class such as Ester, Ether, Carboxylic acid, Aldehyde, Ketone, Amine, Amide, Alcohols, if more than on Functional group present identify both, left then right separated by;] HO-CH3 Paragraph B I U✓ A |||| 80 + v 11.arrow_forward
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