The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis - trans isomerism are to be stated. Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis -isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond. To determine: The compounds that have same physical properties.

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Answer 1

Question

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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What are structural isomers? What is thesmallest alkane that has a structural isomer?Draw structures to illustrate the isomers.

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1. Describe how geometric isomers are different from structural isomers. 2. Why is it possible for alkenes and cylcoalkanes to have cis-trans isomers but not alkanes? 3. How are cis-trans isomers shown in diagrams?

Answer 2

Question

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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Answer 3

Question

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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Answer 4

Question

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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Answer 5

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

Answer 6

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

Answer 7

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

Answer 8

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

Answer 9

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

Answer 10

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

Answer 11

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - What is a hydrocarbon? What is the difference...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Summarize the nomenclature rules for alkanes,...Ch. 21 - What functional group distinguishes each of the...Ch. 21 - Distinguish between isomerism and resonance....Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains that structural isomerism occurs when two compounds have the same number of atoms but the spatial arrangement is different from each other.

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Chapter 21 Solutions