Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter 2, Problem 2.51P
Interpretation Introduction
Interpretation:
It is to be explained that
Concept introduction:
The compounds with strong intermolecular forces have higher boiling points. The strength of the intermolecular interactions increases in the following order:
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The following amines have the same molecular formula (C5H13N), but their boiling points are significantly different.
Explain why.
H
`NH2
2-Methylbutan-1-amine
Boiling point = 97 °C
N-Methylbutan-2-amine
Boiling point = 84 °C
N-Ethyl-N-methylethan-1-amine
Boiling point = 65 °C
The following molecular formulas represent saturated amine compounds or unsaturated amine compounds that contain
C=C bonds. Determine whether each compound is saturated and how many
C=C bonds are present.
a C,H1N
This amine is
c and contains C=C bond(s).
b C,H12N2
correct
lamine is
and contains
C-C bond(s).
€ CH,N
This amine is
and contains
C=C bond(s).
4. The amine reactant can be dissolved in water. Like ammonia, amines can interact with water molecules. Draw
sketches below to clearly show one solute molecule interacting with at least THREE solvent molecules. (Your Lewis
structures of water molecules must be complete, with all bonds and lone pairs.)
ammonia
an amine with one of the butyl substituents
Chapter 2 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
Ch. 2 - Prob. 2.1PCh. 2 - Prob. 2.2PCh. 2 - Prob. 2.3PCh. 2 - Prob. 2.4PCh. 2 - Prob. 2.5PCh. 2 - Prob. 2.6PCh. 2 - Prob. 2.7PCh. 2 - Prob. 2.8PCh. 2 - Prob. 2.9PCh. 2 - Prob. 2.10P
Ch. 2 - Prob. 2.11PCh. 2 - Prob. 2.12PCh. 2 - Prob. 2.13PCh. 2 - Prob. 2.14PCh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16PCh. 2 - Prob. 2.17PCh. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - Prob. 2.23PCh. 2 - Prob. 2.24PCh. 2 - Prob. 2.25PCh. 2 - Prob. 2.26PCh. 2 - Prob. 2.27PCh. 2 - Prob. 2.28PCh. 2 - Prob. 2.29PCh. 2 - Prob. 2.30PCh. 2 - Prob. 2.31PCh. 2 - Prob. 2.32PCh. 2 - Prob. 2.33PCh. 2 - Prob. 2.34PCh. 2 - Prob. 2.35PCh. 2 - Prob. 2.36PCh. 2 - Prob. 2.37PCh. 2 - Prob. 2.38PCh. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Prob. 2.41PCh. 2 - Prob. 2.42PCh. 2 - Prob. 2.43PCh. 2 - Prob. 2.44PCh. 2 - Prob. 2.45PCh. 2 - Prob. 2.46PCh. 2 - Prob. 2.47PCh. 2 - Prob. 2.48PCh. 2 - Prob. 2.49PCh. 2 - Prob. 2.50PCh. 2 - Prob. 2.51PCh. 2 - Prob. 2.52PCh. 2 - Prob. 2.53PCh. 2 - Prob. 2.54PCh. 2 - Prob. 2.55PCh. 2 - Prob. 2.56PCh. 2 - Prob. 2.57PCh. 2 - Prob. 2.58PCh. 2 - Prob. 2.59PCh. 2 - Prob. 2.60PCh. 2 - Prob. 2.61PCh. 2 - Prob. 2.62PCh. 2 - Prob. 2.63PCh. 2 - Prob. 2.64PCh. 2 - Prob. 2.65PCh. 2 - Prob. 2.66PCh. 2 - Prob. 2.67PCh. 2 - Prob. 2.68PCh. 2 - Prob. 2.69PCh. 2 - Prob. 2.70PCh. 2 - Prob. 2.71PCh. 2 - Prob. 2.72PCh. 2 - Prob. 2.1YTCh. 2 - Prob. 2.2YTCh. 2 - Prob. 2.3YTCh. 2 - Prob. 2.4YTCh. 2 - Prob. 2.5YTCh. 2 - Prob. 2.6YTCh. 2 - Prob. 2.7YTCh. 2 - Prob. 2.8YTCh. 2 - Prob. 2.9YTCh. 2 - Prob. 2.10YTCh. 2 - Prob. 2.11YTCh. 2 - Prob. 2.12YTCh. 2 - Prob. 2.13YTCh. 2 - Prob. 2.14YTCh. 2 - Prob. 2.15YTCh. 2 - Prob. 2.16YTCh. 2 - Prob. 2.17YTCh. 2 - Prob. 2.18YTCh. 2 - Prob. 2.19YTCh. 2 - Prob. 2.20YT
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- When amines are reacted with bases, they form ammonium salts. Is that true or false?arrow_forwardDraw the skeletal ("line") structure of a secondary amine with 4 carbon atoms, and no double or triple bonds.arrow_forwardDraw structural formulas for Q.) The four primary (1°) amines with the molecular formula C4H11N.arrow_forward
- The C-N distance in an amide bond is approximately 1.32 Å. A typical C-N single bond is 1.45Å, while a typical C=N double bond is 1.25 Å. Explain this observation and describe how thebonding in amides restricts the conformations amides can adopt.arrow_forwardBecause amines are basic, they can often accept a proton. Draw the protonated structure of n-propylamine.arrow_forwardExplain why CH3 CH2 CH2NH2 is a Brønsted base. Its water solutions are basic. All substances containing nitrogen atoms are Brønsted bases. This amine is a proton donor. This amine can ассеpt a proton from a proton donor.arrow_forward
- TRUE OR FALSE (a) There are three amines with the molecular formula C3H9N. (b) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (c) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (d) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (e) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (f) The molecular formula of the smallest carboxylic acid is C2H4O2.arrow_forwardWhich is a primary amine? O (CH3), CHÍNH, OKCH,CHN OKHANH O (CH₂)₂N*Crarrow_forwardwhich is false? Enantiomers of amines are separable (resolvable). Amines are chiral. Shape of amines is trigonal pyramid. N in amines is sp3 hybridized.arrow_forward
- Draw the structures for the four amines of molecular formula C 3H 9N. Give the systematic name for each amine.arrow_forward(i) The table shows the structures and boiling points of three amines, which are structural isomers of C3H,N. Amine CH,CH,CH,NH, (CH,),CHNH, (CH,),N Skeletal formula `NH, NH2 Boiling point/°c 48-49°C 33-34 °C 3-4°C Explain the difference in the boiling points of the three amines. ....arrow_forwardIn most amines, the nitrogen atom is sp3 hybridized, with a pyramidal structure and bond angles close to 109°. In urea, both nitrogen atoms are found to be planar, with bond angles close to 120°. Explain this surprising finding. (Hint: Consider resonance forms and the overlap needed in them.)arrow_forward
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