General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 18, Problem 36P
Give an acceptable name for each
a.
b.
C.
d.
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C. Amides
1. Amidation
a. Acetic acid + ammonia
Amide hydrolysis in basic conditions forms
A. a carboxylic acid and an amine
B. a carboxylate salt and an amine
3. an ester and an amine
4. a carboxylic acid and an amine salt
3. Give the pharmacological property of the following alkaloids. Where do they naturally occur?
a. morphine
b. quinine
c. berberine
4. What are the chemical tests used in identifying alkaloids?
Chapter 18 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 18.1 - Prob. 18.1PPCh. 18.1 - Prob. 18.1PCh. 18.1 - Prob. 18.2PCh. 18.1 - Prob. 18.3PCh. 18.2 - Prob. 18.2PPCh. 18.2 - Prob. 18.4PCh. 18.2 - Prob. 18.5PCh. 18.3 - Prob. 18.3PPCh. 18.4 - Decaffeinated coffee is produced by extracting the...Ch. 18.4 - Prob. 18.7P
Ch. 18.5 - Prob. 18.8PCh. 18.5 - Naloxone is a drug used to treat overdoses of...Ch. 18.6 - Prob. 18.4PPCh. 18.6 - Prob. 18.10PCh. 18.6 - Prob. 18.11PCh. 18.6 - Name each ammonium salt. a. ( CH3 NH3)+Cl b. [( CH...Ch. 18.6 - Prob. 18.6PPCh. 18.6 - Prob. 18.12PCh. 18.7 - Prob. 18.13PCh. 18.7 - Prob. 18.14PCh. 18.8 - Prob. 18.15PCh. 18.8 - Prob. 18.16PCh. 18.8 - Prob. 18.17PCh. 18.8 - Prob. 18.18PCh. 18.9 - Prob. 18.19PCh. 18.9 - Prob. 18.20PCh. 18.9 - Prob. 18.21PCh. 18.10 - Prob. 18.22PCh. 18 - Prob. 23PCh. 18 - Prob. 24PCh. 18 - Prob. 25PCh. 18 - Prob. 26PCh. 18 - Prob. 27PCh. 18 - Prob. 28PCh. 18 - Prob. 29PCh. 18 - Prob. 30PCh. 18 - Prob. 31PCh. 18 - Prob. 32PCh. 18 - Give an acceptable name for each amine. a. b.Ch. 18 - Give an acceptable name for each amine. a. b.Ch. 18 - Give an acceptable name for each amine. a. b. c....Ch. 18 - Give an acceptable name for each amine. a. CH3(...Ch. 18 - Prob. 37PCh. 18 - Prob. 38PCh. 18 - Prob. 39PCh. 18 - Prob. 40PCh. 18 - Prob. 41PCh. 18 - Prob. 42PCh. 18 - Prob. 43PCh. 18 - Prob. 44PCh. 18 - Which compound in each pair has the higher boiling...Ch. 18 - Which compound in each pair has the higher boiling...Ch. 18 - Draw the hydrogen-bonding interactions that occur...Ch. 18 - Prob. 48PCh. 18 - Prob. 49PCh. 18 - Which compound has the higher water solubility:...Ch. 18 - Prob. 51PCh. 18 - Prob. 52PCh. 18 - Draw the products of each acid-base reaction. a....Ch. 18 - Draw the products of each acid-base reaction. a....Ch. 18 - Prob. 55PCh. 18 - Prob. 56PCh. 18 - What type of nitrogen heterocycle occurs in both...Ch. 18 - Only one of the N atoms in nicotine has a trigonal...Ch. 18 - Prob. 59PCh. 18 - Prob. 60PCh. 18 - Why are aqueous solutions of an alkaloid slightly...Ch. 18 - Prob. 62PCh. 18 - Prob. 63PCh. 18 - Explain why patients with Parkinson’s disease...Ch. 18 - Prob. 65PCh. 18 - Prob. 66PCh. 18 - Prob. 67PCh. 18 - Prob. 68PCh. 18 - Locate the atoms of 2-phenylethylamine in the...Ch. 18 - Locate the atoms of 2-phenylethylamine in the...Ch. 18 - Give an example of an antihistamine. Explain how...Ch. 18 - Give an example of an anti-ulcer drug, and explain...Ch. 18 - Prob. 73PCh. 18 - Prob. 74PCh. 18 - Prob. 75PCh. 18 - Prob. 76PCh. 18 - Prob. 77PCh. 18 - Prob. 78PCh. 18 - Prob. 79PCh. 18 - Why do some antihistamines cause drowsiness while...Ch. 18 - Prob. 81PCh. 18 - Prob. 82PCh. 18 - Compare the structures of morphine and heroin....Ch. 18 - Prob. 84CP
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- Name each amine. a. CH3-CH2-N-CH2-CH, Harrow_forwardName each amine. b. CH;-CH2-CH2-N-CH, H CH3 c. CH3-CH2-CH;-N-CH,-CH;-CH2-CH;arrow_forwardErythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. What functional group Erythronolide B does contain? a. b. H₂CH₂C C. H₂C 1 H₂C 2 3 4 O Amide d. Amine OH Erythronolide B Ketone Aldehyde a CH₂ b C d CH₂ OH JCH₂ 'OH OHarrow_forward
- 35. Which of these generic structures denotes an amine? 35. A. R-CI B. R-OH C. R-O-R' D. R-NH-R' E. RCH F. RCOH G. RCRarrow_forwardName each amine. CH;-CH,-N-CH,-CH, b. CH3-CH,-CH2-N-CH3 H CH3 CH3-CH2-CH2-N-CH2-CH;-CH2-CH3arrow_forwardCompound C4H11N is a a.secondary amine b.primary amine c.tertiary aminearrow_forward
- Why are tertiary amines not soluble in water? O a. Primary amine cannot hydrogen bond with water. O b. Amines are non polar compounds. O c. Tertiary amine cannot hydrogen bond with water O d. Secondary amine cannot hydrogen bond with water. Clear my choicearrow_forwardH. What type of amine is the functional group above (The R is a carbon group) R a. primary Ob. tertiary Oc. secondaryarrow_forward1. Which is more reactive? a. carboxylic acid b. acid anhydride c. acid halide d. amides e. esters 2. Removal of water? a. carboxylic acid b. acid anhydride c. acid halide d. amides e. esters 3. Condensation of alcohol and RCOOH? a. carboxylic acid b. acid anhydride c. acid halide d. amides e. estersarrow_forward
- 1. Is C10H140 an aldehyde or ketone? 2. Aspartic acid belongs to: a. carboxylic acid b. acid anhydride c. acid halide d. amides e. esters 3. Which is least reactive? a. carboxylic acid b. acid anhydride c. acid halide d. amides e. estersarrow_forwardReduction of an alkyl azide results in the formation of —-. A. an imine B. an oxime C. a tertiary amine D. a secondary amine E. a primary aminearrow_forwarda.Primary amides tend to exist as dimers in the solid and liquid state. b.Dimethylacetamide, CH3CON(CH3)2 has a higher boiling point than acetamide. c.Nitrile is often classified as an acid derivative because it is hydrolyzed to a -COOH. d.Esters have lower boiling points than ketones of comparable molecular masses. Whice are correct?arrow_forward
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