The IUPAC name of reaction products when methyl butanoate undergoes ester hydrolysis under acidic conditions has to be written. Concept Introduction: Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification. Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis. Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

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Answer 1

Question

Chapter 16, Problem 16.129EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl butanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl propanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

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Explain why heat is needed in the hydrolysis of esters

1. Which of the following structural features is possessed by aldehydes but not ketones? a. At least one hydroxyl group is bonded to the carbonyl carbon atom. b. At least one hydrogen atom is bonded to the carbonyl carbon atom. c. The carbonyl carbon atom is bonded to two other carbon atoms. d. The carbonyl carbon atom is part of a ring structure. 2. What is the IUPAC name of the following compound in the attached photo? a. 3-chloro-4-nitrobenzoic acid b. 2-chloro-4-carboxynitrobenzene c. 2-nitro-5-carboxychlorobenzene d. 2-chloro-1-nitro-4-benzoic acid 3. Which of the following is the correct bond-line structure for CH3C≡C(CH2)2CH(CH3)2? a. Structure I b. Structure II c. Structure III d. Structure IV

Draw the organic product formed when these compounds undergo a substitution reaction butanoic acid and 2-propanol acetic acid and methylamine formic acid and 2-methyl-1-propanol

Answer 2

Question

Chapter 16, Problem 16.129EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl butanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl propanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

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Answer 3

Question

Chapter 16, Problem 16.129EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl butanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl propanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Expert Solution & Answer

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Answer 4

Question

Chapter 16, Problem 16.129EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl butanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl propanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Expert Solution & Answer

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Answer 5

Chapter 16, Problem 16.129EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl butanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl propanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 6

Chapter 16, Problem 16.129EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl butanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 7

Chapter 16, Problem 16.129EP

(a)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl butanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when methyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl propanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl propanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The IUPAC name of reaction products when isopropyl ethanoate undergoes ester hydrolysis under acidic conditions has to be written.

Concept Introduction:

Breaking of the carbon‑oxygen single bond present between the “acid part” and “alcohol part” is one of the important reactions of ester. This process of breaking the bond between the carbon‑oxygen is known as ester hydrolysis or saponification. The condition prevails in the reaction determines it as ester hydrolysis of saponification.

Ester hydrolysis takes place in ester when it is treated with strong acid or enzymes as catalyst. Reverse of esterification reaction is the ester hydrolysis.

Saponification is the reaction that ester undergoes when a strong base is used to give the product as carboxylic acid salt and alcohol.

Answer 14

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Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 16.1 - Prob. 1QQ Ch. 16.1 - Prob. 2QQ Ch. 16.1 - Prob. 3QQ Ch. 16.1 - Prob. 4QQ Ch. 16.1 - Prob. 5QQ Ch. 16.2 - Prob. 1QQ Ch. 16.2 - Prob. 2QQ Ch. 16.2 - Prob. 3QQ Ch. 16.2 - Prob. 4QQ Ch. 16.2 - Prob. 5QQ

Solution Summary: The author explains the IUPAC name of reaction products when methyl butanoate undergoes ester hydrolysis under acidic conditions.

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Chapter 16 Solutions