World of Chemistry, 3rd edition
World of Chemistry, 3rd edition
3rd Edition
ISBN: 9781133109655
Author: Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher: Brooks / Cole / Cengage Learning
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Chapter 13, Problem 13A
Interpretation Introduction

Interpretation:

Whether Charles’s law can be used to determine absolute zero has to be explained.

Concept Introduction:

Charles’s law: The volume of a given amount of gas is proportional to its temperature (in K) of the gas at constant pressure.

The relationship between volume of a gas and temperature is expressed as-

  VTor,VT = Constant When P is constant.

Expert Solution & Answer
Check Mark

Answer to Problem 13A

If the lines in volume vs. temperature in Kelvin graph extrapolate to zero volume at the same temperature which is -273 °C. This temperature -273 °C is the lowest possible thermodynamic temperature when when the volume of a gas is zero. Therefore, this temperature is defined as absolute zero on the Kelvin scale which is derived from the Charles’s law.

Explanation of Solution

Charles’s law: The volume of a given amount of gas is proportional to its temperature (in K) of the gas at constant pressure.

The relationship between volume of a gas and temperature is expressed as-

  VTor,VT = Constant When P is constant.

  World of Chemistry, 3rd edition, Chapter 13, Problem 13A

If the lines in volume vs. temperature in Kelvin graph extrapolate to zero volume at the same temperature which is -273 °C. This temperature -273 °C is the lowest possible thermodynamic temperature when when the volume of a gas is zero. Therefore, this temperature is defined as absolute zero on the Kelvin scale which is derived from the Charles’s law.

Chapter 13 Solutions

World of Chemistry, 3rd edition

Ch. 13.2 - Prob. 4RQCh. 13.2 - Prob. 5RQCh. 13.2 - Prob. 6RQCh. 13.2 - Prob. 7RQCh. 13.2 - Prob. 8RQCh. 13.3 - Prob. 1RQCh. 13.3 - Prob. 2RQCh. 13.3 - Prob. 3RQCh. 13.3 - Prob. 4RQCh. 13.3 - Prob. 5RQCh. 13 - Prob. 1ACh. 13 - Prob. 2ACh. 13 - Prob. 3ACh. 13 - Prob. 4ACh. 13 - Prob. 5ACh. 13 - Prob. 6ACh. 13 - Prob. 7ACh. 13 - Prob. 8ACh. 13 - Prob. 9ACh. 13 - Prob. 10ACh. 13 - Prob. 11ACh. 13 - Prob. 12ACh. 13 - Prob. 13ACh. 13 - Prob. 14ACh. 13 - Prob. 15ACh. 13 - Prob. 16ACh. 13 - Prob. 17ACh. 13 - Prob. 18ACh. 13 - Prob. 19ACh. 13 - Prob. 20ACh. 13 - Prob. 21ACh. 13 - Prob. 22ACh. 13 - Prob. 23ACh. 13 - Prob. 24ACh. 13 - Prob. 25ACh. 13 - Prob. 26ACh. 13 - Prob. 27ACh. 13 - Prob. 28ACh. 13 - Prob. 29ACh. 13 - Prob. 30ACh. 13 - Prob. 31ACh. 13 - Prob. 32ACh. 13 - Prob. 33ACh. 13 - Prob. 34ACh. 13 - Prob. 35ACh. 13 - Prob. 36ACh. 13 - Prob. 37ACh. 13 - Prob. 38ACh. 13 - Prob. 39ACh. 13 - Prob. 40ACh. 13 - Prob. 41ACh. 13 - Prob. 42ACh. 13 - Prob. 43ACh. 13 - Prob. 44ACh. 13 - Prob. 45ACh. 13 - Prob. 46ACh. 13 - Prob. 47ACh. 13 - Prob. 48ACh. 13 - Prob. 49ACh. 13 - Prob. 50ACh. 13 - Prob. 51ACh. 13 - Prob. 52ACh. 13 - Prob. 53ACh. 13 - Prob. 54ACh. 13 - Prob. 55ACh. 13 - Prob. 56ACh. 13 - Prob. 57ACh. 13 - Prob. 58ACh. 13 - Prob. 59ACh. 13 - Prob. 60ACh. 13 - Prob. 61ACh. 13 - Prob. 62ACh. 13 - Prob. 63ACh. 13 - Prob. 64ACh. 13 - Prob. 65ACh. 13 - Prob. 66ACh. 13 - Prob. 67ACh. 13 - Prob. 68ACh. 13 - Prob. 69ACh. 13 - Prob. 70ACh. 13 - Prob. 71ACh. 13 - Prob. 72ACh. 13 - Prob. 73ACh. 13 - Prob. 74ACh. 13 - Prob. 75ACh. 13 - Prob. 76ACh. 13 - Prob. 1STPCh. 13 - Prob. 2STPCh. 13 - Prob. 3STPCh. 13 - Prob. 4STPCh. 13 - Prob. 5STPCh. 13 - Prob. 6STPCh. 13 - Prob. 7STPCh. 13 - Prob. 8STPCh. 13 - Prob. 9STPCh. 13 - Prob. 10STP
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