Essential Organic Chemistry, Global Edition
Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 12.7, Problem 19P

(a)

Interpretation Introduction

Interpretation:

It should be determined that the amide used to produce Benzylmethylamine on reaction with LiAlH4.

Concept introduction:

LiAH4 (Lithium aluminium hydride):

Lithium aluminium hydride is used as a reducing agent.

Lithium aluminium hydride is reduced the amide as an amine which is shown below.

Essential Organic Chemistry, Global Edition, Chapter 12.7, Problem 19P , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

It should be determined that the amide used to produce Ethylamine on rection with LiAlH4.

Concept introduction:

LiAH4 (Lithium aluminium hydride):

Lithium aluminium hydride is used as a reducing agent.

Lithium aluminium hydride is reduced the amide as an amine which is shown below.

Essential Organic Chemistry, Global Edition, Chapter 12.7, Problem 19P , additional homework tip  2

(c)

Interpretation Introduction

Interpretation:

It should be determined that the amide used to produce Diethylamine on rection with LiAlH4.

Concept introduction:

LiAH4 (Lithium aluminium hydride):

Lithium aluminium hydride is used as a reducing agent.

Lithium aluminium hydride is reduced the amide as an amine which is shown below.

Essential Organic Chemistry, Global Edition, Chapter 12.7, Problem 19P , additional homework tip  3

(d)

Interpretation Introduction

Interpretation:

It should be determined that the amide used to produce Triethylamine on rection with LiAlH4.

Concept introduction:

LiAH4 (Lithium aluminium hydride):

Lithium aluminium hydride is used as a reducing agent.

Lithium aluminium hydride is reduced the amide as an amine which is shown below.

Essential Organic Chemistry, Global Edition, Chapter 12.7, Problem 19P , additional homework tip  4

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What amides would you react with LiAlH4 to form the following amines?a. benzylmethylamine c. diethylamineb. ethylamine d. triethylamine
a.Primary amides tend to exist as dimers in the solid and liquid state. b.Dimethylacetamide, CH3CON(CH3)2 has a higher boiling point than acetamide. c.Nitrile is often classified as an acid derivative because it is hydrolyzed to a -COOH. d.Esters have lower boiling points than ketones of comparable molecular masses. Whice are correct?
It is a component of nylon 66. a. Phthalic acid b. Lauric acid O c. Benzoic acid d. Adipic acid e. Ethanoic acid Primary amine can be prepared by a. Reacting an alkyl halide with sodium azide. b. Reacting an amide with water under heat. O c. Reacting alkyl halide with NaCN followed by LiAlH4 in ether, then with water. O d. Reacting carboxylic acid with R-NH2 and NaBH4. Which of the following will give a positive reaction with Tollen's reagent? a. All of the above b. Butanone O c. 3-pentanone Od. Pentanal O e. Butanal
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