Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 11, Problem 45P
Interpretation Introduction
Interpretation:
The product formation for the reaction of a tertiary amine with acyl chloride has to be explained.
Concept introduction:
Amines are nitrogen-containing organic compounds. The general formula of amines is
General examples:
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Students have asked these similar questions
An aqueous solution of a primary or secondary amine reacts with an acyl chloride to form an amide as the major product. However, if the amine is tertiary, an amide is not formed. What product is formed? Explain.
Explain why
CH3 CH2 CH2NH2
is a Brønsted
base.
Its water
solutions
are basic.
All
substances
containing
nitrogen
atoms are
Brønsted
bases.
This
amine is a
proton
donor.
This
amine can
ассеpt a
proton
from a
proton
donor.
From the given structures which is(a) amide that will release a secondary amine upon hydrolysis? (b) product of hydrolysis of MSO (c) a tertiary amide and (d) a diketone
Chapter 11 Solutions
Essential Organic Chemistry, Global Edition
Ch. 11.1 - The aromas of many flowers and fruits are due to...Ch. 11.1 - Name the following compounds:Ch. 11.1 - Prob. 3PCh. 11.2 - Prob. 4PCh. 11.2 - Prob. 5PCh. 11.4 - a. What is the product of the reaction of acetyl...Ch. 11.4 - Prob. 7PCh. 11.5 - Using the pKa values listed in Table 11.1, predict...Ch. 11.6 - Starting with acetyl chloride, what neutral...Ch. 11.6 - Prob. 10P
Ch. 11.7 - Prob. 11PCh. 11.8 - Prob. 13PCh. 11.8 - Using the mechanism for the acidcatalyzed...Ch. 11.8 - Prob. 15PCh. 11.8 - Prob. 16PCh. 11.8 - Prob. 17PCh. 11.9 - Prob. 18PCh. 11.10 - Show how each of the following esters could be...Ch. 11.11 - Which of the following reactions would lead to the...Ch. 11.12 - Prob. 22PCh. 11.12 - Prob. 23PCh. 11.13 - Prob. 24PCh. 11.13 - Prob. 25PCh. 11.14 - Prob. 26PCh. 11.14 - Prob. 27PCh. 11.14 - Prob. 28PCh. 11.15 - Prob. 29PCh. 11.15 - How would you synthesize the following compounds...Ch. 11 - Write a structure for each of the following a. N,N...Ch. 11 - Prob. 32PCh. 11 - Which ester is more reactive, methyl acetate or...Ch. 11 - What products would be formed from the reaction of...Ch. 11 - What products would be obtained from the following...Ch. 11 - Prob. 36PCh. 11 - a. Which compound would you expect to have a...Ch. 11 - a. List the following esters in order of...Ch. 11 - D. N. Kursanov, a Russian chemist, proved that the...Ch. 11 - Prob. 40PCh. 11 - Using an alcohol for one method and an alkyl...Ch. 11 - Prob. 42PCh. 11 - Prob. 44PCh. 11 - Prob. 45PCh. 11 - Prob. 46PCh. 11 - Prob. 47PCh. 11 - Prob. 48PCh. 11 - Prob. 49PCh. 11 - Show how the following compounds could be prepared...Ch. 11 - Prob. 51PCh. 11 - Prob. 52PCh. 11 - Prob. 53P
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Similar questions
- What is the hybridization of the C and N in this amide ?arrow_forwardAmines as Bases. Explain ?arrow_forwardSketch the product, Then writeh the IUPAC NAME OF THE AMINE PRODUCT and the dominant Intermolecular force for the product. CH, NH, + H -CI O CH3-NH3*Cr, methylammonium chloride (Amine Product: H-Bond) O CH3-CH3-NH3*Cl', ethylammonium chloride (Amine Product: H-Bond) O CH3-NH3*, methylammonium ion (Amine Product: Dipole-Dipole) +. O CH3-NH3*CI , ethylammonium chloride (Amine Product: H-Bond) O CH3-NH3*CI', ethylammonium chloride (Amine Product: Dipole-Dipole) CH3-NH3*Cl", methylammonium chloride (Amine Product: lonic)arrow_forward
- Because amines are basic, they can often accept a proton. Draw the protonated structure of n-propylamine.arrow_forwardFollowing amines can be classified as -- and ---, respectively. HN-CH3 H3C-CH3 'N' H primary amine, secondary amine secondary amine, ammonium salt secondary amine, primary amine secondary amine, tertiary aminearrow_forwardClassify each amine as a primary, secondary, or tertiary.arrow_forward
- Which of the following compounds is WILL NOT form an amide in a reaction with a carboxylic acid derivative? O ammonia O tertiary amine O primary amine secondary aminearrow_forwardThe structure of Amines are classified as primary (1), secondary (2), and tertiary (3) that concept that seemed difficult to you at first, but then after working on the concept, you were able to master it. Include a description of what made the concept difficult at first, and then discuss what you did in order to better understand the concept.arrow_forwardClassify each of the molecules below. CH3 O || CH3 -N−CH2−NH–CH2–NH2 primary amide secondary amide tertiary amide not an amide at all CH3 NH- - CH₂ - CH3 primary amide secondary amide tertiary amide not an amide at all O || CH3 CH3 C-N-CH2−NH– -CH3 primary amide secondary amide tertiary amide not an amide at allarrow_forward
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