EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 9.2, Problem 15E
Interpretation Introduction
Interpretation: The relative reactivity of the H atoms in 1-chlorobutane needs to be determined depending on the percentage calculation of dichlorobutane formed in the reaction.
Concept introduction: 1-Chlorobutane has a chemical formula as
Following are the isomeric products formed when a 1-chlorobutane is monochlorinated using sulfuryl chloride with ABCN as the catalytic agent:
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
The following table indicates the yield percent values of nitration products and toluene bromination. Explain the difference between the performance percentages of the products of bromination.
Draw the structure of the following three isomeric acid chlorides with chemical formula C6H₂CIO.
• Use the wedge/hash bond tools to indicate stereochemistry where it exists.
• Consider E/Z stereochemistry of alkenes.
• In cases where there is more than one answer, just give one.
Acid chloride #1: cis-3-methylcyclobutanecarbonyl chloride
//.
| [ ]#
?
ChemDoodle
Calculate the theoretical yield and percent yield of the product formed from.
Reaction between 1.005g Tetraphenylcyclopentadienone and 1.203 Maleic Anhydride with 15mL of xylene
The yield obtained was 1.097g.
What is the name of the product?
Chapter 9 Solutions
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
Ch. 9.2 - Prob. 1ECh. 9.2 - Prob. 2ECh. 9.2 - Prob. 3ECh. 9.2 - Prob. 4ECh. 9.2 - Prob. 5ECh. 9.2 - Prob. 6ECh. 9.2 - Prob. 7ECh. 9.2 - Prob. 8ECh. 9.2 - Prob. 9ECh. 9.2 - Prob. 10E
Ch. 9.2 - Prob. 11ECh. 9.2 - Prob. 12ECh. 9.2 - Prob. 13ECh. 9.2 - Prob. 14ECh. 9.2 - Prob. 15ECh. 9.2 - Prob. 16ECh. 9.2 - Prob. 17ECh. 9.2 - Prob. 18ECh. 9.2 - Prob. 19ECh. 9.2 - Prob. 20ECh. 9.2 - Prob. 21ECh. 9.2 - Prob. 22ECh. 9.2 - Prob. 23ECh. 9.2 - Prob. 24ECh. 9.3 - Prob. 1ECh. 9.3 - Prob. 2ECh. 9.3 - Prob. 3ECh. 9.3 - Prob. 4ECh. 9.3 - Prob. 5ECh. 9.3 - Prob. 6ECh. 9.3 - Prob. 7ECh. 9.3 - Prob. 8ECh. 9.3 - Prob. 9ECh. 9.3 - Prob. 10ECh. 9.3 - Prob. 11ECh. 9.3 - Prob. 12ECh. 9.3 - Prob. 13ECh. 9.3 - Prob. 14E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Using the relative reactivity values shown below, estimate the %yield of each of the two monobrominated product of butanearrow_forwardFree-radical chlorination of hexane gives very poor yields of 1-chlorohexane, while cyclohexane can be converted to chlorocyclohexane in good yield. What ratio of reactants (cyclohexane and chlorine) would you use for the synthesis of chlorocyclohexane?arrow_forwardHOCH2CH2OH O: H* Br2 (excess) 7. NaOCH3 C6H5 CH3OH 5. 6.arrow_forward
- Photochemical chlorination of 2,2,4-trimethylpentane gives you four isomeric monochlorides A. Write the structural formular for these four isomers B. The two chlorides make up 65% of the monochlorides fraction. Asumming that all the primary hyrogens in 2,2,4-trimethylpentane are reactive, estimate the percentage of each of the two primary chlorides in the product mixturearrow_forwardQuestion 3 Provide the reagents necessary to carry out the following conversion. O. Br O 1. CH3CH2COCI/AICI3; 2. HNO3/H2SO4; 3. Fe/HCl; 4. NaNO2/HCI/< 5°C; 5. CH3CH2OH/heat O 1. HNO3/H2SO4; 2. Cl2/FeCl3; 3. Fe/HCI; 4. NANO2/HCI/< 5°C; H2S04 O 1. HNO3/H2SO4; 2. Br2/FeBr3; 3. Fe/HCI; 4. NaNO2/HCI/< 5°C; 5. CH3CH2C O 1. CH3CH2COCI/AICI3; 2. HNO3/H2SO4; 3. Fe/HCl; 4. CH3CH2OH/heatarrow_forward39. Which of the following reactions will produce the highest percentage yield of 1-butene. C,H5OK*/C,H;OH A. CH;CH2CH(N*(CH3);)CH3 alc. KOH B. CH3CH2CHCICH3 conc. H2SO4 С. CH;СНОНСH-CH; heat NaOC,H5 D. CH3CHBrCH2CH3 СН,ОНarrow_forward
- How much product will be formed if 0.024 moles of benzaldehyde react with 0.012 moles of acetone? [Hint: think, what is the limiting reagent here] If you isolated 2.62 g of pure product, what is the % yield in this reaction? Show all the calculations.arrow_forwardConsidering the stoichiometry of the reaction (balance the equation!), what is the net oxidation state difference of the carbons in benzophenone c to benzopinacol? Remember that you have to calculate the oxidation state of the carbons in the product (benzopinacol) and subtract the oxidation state of the carb the reactants (benzophenones). The shortcut is to only calculate the oxidation states of the carbons that seem to have changed their bonding Give a whole number answer with no units. OH hv Ph Ph OH Ph Ph Ph Ph OH Answer:arrow_forwardPlease help with 4c, 4d, and 4e. We havent learned kaw of equivalents so please do 4c a different way. thank youarrow_forward
- [Review Topics] [References] Use the References to access important values if needed for this question. Draw the product that would form when 3,3-dimethyl-1-butene reacts with chlorine. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. . In cases where there is more than one answer, just draw one. Sn [F ChemDoodle An error has been detected in your answer. Check for typos, miscalculations etc. before submitting your answer. C Draw the product that would fa Previousarrow_forwardBr CH3 Br2 CH3CHCHCH2ČHCH3 Br OH 1. Hg(OAc)2, H20 2. NABH4 CH3CH2CH2CHCH3 HCI CH3CHCHCH2CH2CH2CH3 ČH3 CH3 -CH3 H/Pdarrow_forwardAssuming that benzaldehyde is the limiting reagent for the synthesis of stilbene, that stilbene is the limiting reagent for the synthesis of stilbene dibromide, and that stilbene dibromide is the limiting reagent for the synthesis of diphenylacetylene; what is the overall % yield of diphenylacetylene from benzaldehyde given the percentage yield of each step of the reaction sequence as follows? Give only two significant digits. If the answer is a whole number with two digits, do not include the decimal. 52% 87% benzaldehyde → stilbene → stilbene dibromide 41% Answer: diphenylacetylene Notes: For our multi-step synthesis we cannot just calculate the yield based on starting amount of benzaldehyde and final amount of diphenylacetylene because your group may have been supplemented with commercial material at one or more steps. In truth most chemist use an excess of the least expensive reagent to increase their yield. So in our case benzyltriphenylphosphonium chloride should probably be our…arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Macroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole
Macroscale and Microscale Organic Experiments
Chemistry
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
Publisher:Brooks Cole