EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 9.2, Problem 13E
(a)
Interpretation Introduction
Interpretation: Using a relative reactivity for 1° to 2° hydrogen atoms of
Concept Introduction: A hydrogen that is bonded to the primary carbon is called a 1o hydrogen and the hydrogen that is bonded to the secondary carbon is called a 2o hydrogen.
(b)
Interpretation Introduction
Interpretation: Using a relative reactivity for 1° to 2° hydrogen atoms of
Concept Introduction: When a chemical compound reacts with other compounds, its relative activity is defined as relative reactivity.
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What is the relationship between bioaccumulation of organic contaminants and Log KOW? Assuming no biotransformation, what BCF would you expect for each of the PAHs listed below? Why?
a. Benzene (Log KOW = 2.1)
b. Benzo[a]pyrene (Log KOW = 6.0)
c. Ovalene (Log KOW = 10.5)
7. Butylenes are industrially recovered from:
a- Diene basic petrochemicals.
e- B-B fraction of steam cracking by
b- Selective extraction.
d- All of these.
distillation.
8. The solvent used for extractive distillation of butadiene are:
a- Acrylonitrile.
e- Acetonitrile.
b- Нехane.
d- None of these.
What is the experimental yield (grams and percentage)
Experiment: Oxidation of -Chlorotoluene to o-Chlorobenzoic acid
materials used
dissolved 3.35 g of KMnO4
1.20 mL of 2-chlorotoluene was added to the mixture
3.0 mL of concentrated hydrochloric acid (pH~2)
10 mL of toluene
-The crystals were isolated by vacuum filtration-
Product Characterization
1.15 g of the crude product
0.93 g of the final product
M.p. (final): 139-141 oC
Chapter 9 Solutions
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
Ch. 9.2 - Prob. 1ECh. 9.2 - Prob. 2ECh. 9.2 - Prob. 3ECh. 9.2 - Prob. 4ECh. 9.2 - Prob. 5ECh. 9.2 - Prob. 6ECh. 9.2 - Prob. 7ECh. 9.2 - Prob. 8ECh. 9.2 - Prob. 9ECh. 9.2 - Prob. 10E
Ch. 9.2 - Prob. 11ECh. 9.2 - Prob. 12ECh. 9.2 - Prob. 13ECh. 9.2 - Prob. 14ECh. 9.2 - Prob. 15ECh. 9.2 - Prob. 16ECh. 9.2 - Prob. 17ECh. 9.2 - Prob. 18ECh. 9.2 - Prob. 19ECh. 9.2 - Prob. 20ECh. 9.2 - Prob. 21ECh. 9.2 - Prob. 22ECh. 9.2 - Prob. 23ECh. 9.2 - Prob. 24ECh. 9.3 - Prob. 1ECh. 9.3 - Prob. 2ECh. 9.3 - Prob. 3ECh. 9.3 - Prob. 4ECh. 9.3 - Prob. 5ECh. 9.3 - Prob. 6ECh. 9.3 - Prob. 7ECh. 9.3 - Prob. 8ECh. 9.3 - Prob. 9ECh. 9.3 - Prob. 10ECh. 9.3 - Prob. 11ECh. 9.3 - Prob. 12ECh. 9.3 - Prob. 13ECh. 9.3 - Prob. 14E
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