(a)
Interpretation: Considering the mono-chlorination of heptane using ABCN (1) and sulfuryl chloride, the structures and names of the possible mono-chlorination products that could be produced, needs to be written.
Concept Introduction: Heptane, being a main component of gasoline, has a chemical formula of
(b)
Interpretation: Considering the mono-chlorination of heptane using ABCN (1) and sulfuryl chloride, the center(s) of chirality, if any, that are present in the isomers derived in Part a, needs to be circled.
Concept Introduction: When an atom is bonded to four other groups, such that the group is held in space with this atom becoming the stereocenter, and the mirror image of the bond is non-superimposable, then this atom is called chiral center or chirality center.
(c)
Interpretation: The structure of each sample needs to be determined using the 1H and 13C NMR spectroscopic data.
Concept Introduction: Stereoscopic imaging is used to view and understand three dimensional images and record the same, such that the viewer will also be able to see and understand the depth of the image.
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EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
- Draw the structure(s) of the major organic product(s) of the following reaction. H SILL KMnO, / aqueous H₂SO, • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. . Do not include lone pairs in your answer. They will not be considered in the grading. ● If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. ChemDoodleⓇ n[F 66arrow_forwardDraw the structure of the molecule indicated by the IUPAC name provided. Indicate stereochemistryarrow_forwardDo saturated and unsaturated hydrocarbons show similar observable positive results in all tests?arrow_forward
- Draw the structure of the major organic product(s) of the reaction. H3C 1. DIBAH, toluene 2. H,0+ DIBAH = diisobutylaluminum hydride, [(CH3),CHCH2],ÁIH • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu.arrow_forwarda. Name the following structure. Use the correct stereochemistry notation where needed. ** Name b. Draw the structure of (3R,5S)-4-isopropyl-3,5-dimethylheptane. ( Structurearrow_forwardDraw the structure of the organic product(s) of the reaction between (S)-3-methylhexan-2-one and ethylmagnesium bromide, followed by acidification. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the sign from the drop-down menu. My 3 32 00-05 OO° [] +▾ ChemDoodleⓇarrow_forward
- complete the tablearrow_forward1. Why is purification necessary when doing organic synthesis? What are examples of purification methods? Will purification be done in this experiment? 2. Is purification also done in natural product experiments? What for? 3. What is the difference of the terms “purification” and “characterization”?arrow_forwardAnswer number 19, 20, and 21.arrow_forward
- Draw the organic product(s) of the following reactions including stereochemistry when it is appropriate. H₂ Lindlar catalyst H3C-CEC-CH3 • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Consider E/Z stereochemistry of alkenes. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. + ▾ 53 ChemDoodleⓇ On [F 6barrow_forward1. Write the structure of the aminal or hemiaminal intermediate and the imine product formed in the reaction of Acetaldehyde and benzylamine, C6HSCH2NH2. 2. Write the structure of the hemiaminal intermediate and the enamine product formed in the reaction of 3-Pentanone and pyrrolidine. 3. Identify the alkene formed in the following reaction 'H. (CeHs)»P- 4. Predict the principal organic product for the following reaction. K2Cr2O7 H2SO4, H20 H. 5. What is the expected chemical shift for the aldehyde hydrogen in 'H NMR and aldehyde carbon in 13C NMR?arrow_forwardDraw the structure of the organic product of the reaction between cyclohexene and H₂, Pd/C. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. Separate multiple products using the + sign from the drop-down menu. . In cases where there is more than one answer, just draw one.arrow_forward
- Macroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole