EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Question
Chapter 9.2, Problem 6E
Interpretation Introduction
Interpretation: The reason for consuming only a catalytic amount of ABCN(1) in this reaction needs to be explained.
Concept introduction: In the chlorination reaction using sulfuryl chloride, ABCN (1) acts as an initiator only.
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Is this reaction a feasible method of removing SO2? Why or why not?
1. Explain why it is important to keep water out of this reaction. What would happen if water got into the reaction mixture? (Note: A small amount of KOH was also added to this reaction).
2. You may have noticed that the reaction was perform at a temperature (85 degrees celsius in a 35 mL microwave reaction vessel) that was higher than the boiling point of methanol (64.7 degrees celsius), how is this possible?
a. Write two reaction paths for the production of monochlorodecane (C10H21CI) by reaction of
Decane (C10H22) with molecular chlorine (Cl2).
Decene (C10H20) with hydrogen chloride (HCI).
b. What type of reaction occurs in both (i) and (ii) above?
i.
ii.
Chapter 9 Solutions
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
Ch. 9.2 - Prob. 1ECh. 9.2 - Prob. 2ECh. 9.2 - Prob. 3ECh. 9.2 - Prob. 4ECh. 9.2 - Prob. 5ECh. 9.2 - Prob. 6ECh. 9.2 - Prob. 7ECh. 9.2 - Prob. 8ECh. 9.2 - Prob. 9ECh. 9.2 - Prob. 10E
Ch. 9.2 - Prob. 11ECh. 9.2 - Prob. 12ECh. 9.2 - Prob. 13ECh. 9.2 - Prob. 14ECh. 9.2 - Prob. 15ECh. 9.2 - Prob. 16ECh. 9.2 - Prob. 17ECh. 9.2 - Prob. 18ECh. 9.2 - Prob. 19ECh. 9.2 - Prob. 20ECh. 9.2 - Prob. 21ECh. 9.2 - Prob. 22ECh. 9.2 - Prob. 23ECh. 9.2 - Prob. 24ECh. 9.3 - Prob. 1ECh. 9.3 - Prob. 2ECh. 9.3 - Prob. 3ECh. 9.3 - Prob. 4ECh. 9.3 - Prob. 5ECh. 9.3 - Prob. 6ECh. 9.3 - Prob. 7ECh. 9.3 - Prob. 8ECh. 9.3 - Prob. 9ECh. 9.3 - Prob. 10ECh. 9.3 - Prob. 11ECh. 9.3 - Prob. 12ECh. 9.3 - Prob. 13ECh. 9.3 - Prob. 14E
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