Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 6, Problem 24E
Interpretation Introduction

Interpretation:The reason of using a slash”/” between word conformers and same needs to be explained.

Concept introduction:

Conformational isomers are those isomers that can be converted to other form by rotation about a single bond.

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draw without the symbols like CHO
In this molecule’s other chair conformation, how many (non H) axial positions are there?
I don't understand why the first one and second one are cis and trans respectively. Wouldn't the first one be trans-1,2-dimethylcyclobutane because the torsional strain wouldn't allow the carbons to be in the same conformation. Meaning one of the carbons would be up and then the next would be down and so on. Since both methyl groups are equatorial and the first and second carbons are arranged up and down, wouldn't it be trans. Same logic for the second molecule. Carbon 1, which is attached to the methyl is down, carbon 3 which is attached to the methyl should be down also because of torsional strain, and since both methyl are in axial (or equatorial?), it would be cis. Or is it based off of the way the carbons are positioned in the picture?

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Organic Chemistry: A Guided Inquiry

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