An Introduction to Thermal Physics
An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 2.6, Problem 39P

Compute the entropy of a mole of helium at room temperature and atmospheric pressure, pretending that all the atoms are distinguishable. Compare to the actual entropy, for indistinguishable atoms, computed in the text.

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Compute the entropy of a mole of helium at room temperature and atmospheric pressure, pretending that all the atoms are distinguishable. Compare to the actual entropy, for indistinguishable atoms, computed in the text.
For one component gas that is confined in a box with volume V. V We can get the entropy of the gas as S = Nk, In where N is the total number of atoms, a is the radius of the atom. Can you guess (or work out) how it is obtained?
Starting with the Clausius Inequality, ∂S ≥ ∂q/T, can you prove that, under conditions of constant pressure and entropy, for the total entropy to increase, ∂H ≤ 0 J?

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An Introduction to Thermal Physics

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