An Introduction to Thermal Physics
An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 2.4, Problem 24P

(a)

To determine

To Find: The height of the peak in the multiplicity function using Stirling’s method.

(b)

To determine

To Find: Derive the formula for the multiplicity function in the vicinity of the peak.

(c)

To determine

To Find: Width of the peak in the multiplicity function.

(d)

To determine

To Explain: Explain while flipping of coins getting head and tails.

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If V0 = 4 eV, E = 1 eV and L = 0.01 nm, determine the probability of a quantum-mechanical electron making its way through this barrier. Express your answer as a percentage. Note: You are being asked to provide a precise calculation, using correct boundary conditions at x = 0 and x = L, and not to use an approximation. Hints for part d) of question 4: The required calculation is very similar to the calculation of the transmission coefficient T for the Finite Potential Barrier given in lectures, but with a different wavenumber in the region to the right of the barrier. After applying the boundary conditions at x = 0 and x = L, you may choose to simplify the expression you find for the transmission coefficient, T. In doing this a useful result is that the modulus-squared of f = αβ e−kLˆ − α ∗β ∗ e kLˆ , where α ≡ ˆk + ik and β ≡ ˆk + iq, is given by |f| 2 = 4(ˆk 2 + k 2 )(ˆk 2 + q 2 ) sinh2 ( ˆkL) + 4ˆk 2 (k + q) 2 . You may use this result to obtain your answer.
Consider the "step" potential: V(x) = (a) Calculate the reflection coefficient, for the case E 0. (b) Calculate the reflection coefficient for the case E > Vo. (c) For a potential such as this, which does not go back to zero to the right of the barrier, the transmission coefficient is not simply |F12/A2 (with A the -Vo AV(x) Scattering from a "cliff" incident amplitude and F the transmitted amplitude), because the transmitted wave travels at a different speed. Show that T = E-Vo F1² E |A|² X for E> Vo. Hint: You can figure it out using Equation gantly, but less informatively-from the probability current ( What is T, for E Vo, calculate the transmission coefficient for the step potential, and check that T + R = 1.
(A) Consider a particle in a cubic box. What is the degeneracy of the level it hasenergy three times greater than that of the lowest level? (Explain the combinations of n that led you to the answer given).  (B) The addition of sodium to ammonia generates a solvated electron that is trapped in a cavity of 0.3 nm in diameter, formed by ammonia molecules. The solvated electron can be modeled as a particle that moves freely inside the cubic box with ammonia molecules in the cube surface. If the length of the box is 0.3 nm, what energy is needed for the electron undergo a transition from a lower energy state to the subsequent state?

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An Introduction to Thermal Physics

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