An Introduction to Thermal Physics
An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 2.4, Problem 15P
To determine

To Justify: Accuracy of Stirling’s approximation for N=50

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2.3 (a) A classical harmonic oscillator p?, Kq? H + 2m 2 is in thermal contact with a heat bath at temperature T. Calculate the partition function for the oscillator in the canonical ensemble and show explicitly that • (E) = kgT, ((E – (E))²) = k¿T²
Problem 1: This problem concerns a collection of N identical harmonic oscillators (perhaps an Einstein solid) at temperature T. The allowed energies of each oscillator are 0, hf, 2hf, and so on. a) Prove =1+x + x² + x³ + .... Ignore Schroeder's comment about proving 1-x the formula by long division. Prove it by first multiplying both sides of the equation by (1 – x), and then thinking about the right-hand side of the resulting expression. b) Evaluate the partition function for a single harmonic oscillator. Use the result of (a) to simplify your answer as much as possible. c) Use E = - дz to find an expression for the average energy of a single oscillator. z aB Simplify as much as possible. d) What is the total energy of the system of N oscillators at temperature T?
Let's look at the term InN!. Compare its exact value with the more accurate one of Stirling's approximation, EANt InN!=N/N-N+ [N and to a lighter form. (~N! ~ N/NN-N₁₂₁₂ (N=1₂10₂100) Calculate the relative ellors of the approximations in all cases

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An Introduction to Thermal Physics

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