An Introduction to Thermal Physics
An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 2.6, Problem 31P

Fill in the algebraic steps to derive the Sackur-Tetrode equation (2.49)

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Problem 4.25 If electron, radius [4.138] 4πεmc2 What would be the velocity of a point on the "equator" in m /s if it were a classical solid sphere with a given angular momentum of (1/2) h? (The classical electron radius, re, is obtained by assuming that the mass of the electron can be attributed to the energy stored in its electric field with the help of Einstein's formula E = mc2). Does this model make sense? (In fact, the experimentally determined radius of the electron is much smaller than re, making this problem worse).
Give only typing answer with explanation and conclusion The Einstein-A coefficient for a particular rovibrational transition of CO2 is 220 s−1. In the absence of collisions, what is the characteristic lifetime of the upper state? Compare this with the Na transition near 589.6nm which has an Einstein-A coefficient of 6.14×10^7 s−1.
1-5. In a strictly steady state situation, both the ions and the electrons will follow the Boltzmann relation n; = no exp (-4,6/KT,) For the case of an infinite, transparent grid charged to a potential 6, show that the shielding distance is then given approximately by ne 1 AD €o KT, KT,. Show that Ap is determined by the temperature of the colder species.

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An Introduction to Thermal Physics

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