a) N, N-Dimethylaniline
Interpretation:
The structure corresponding to the systematic name N, N-Dimethylaniline.
Answer to Problem 48AP
The IUPAC names given for the
Explanation of Solution
The longest carbon chain containing the double bond to be chosen. Based on the name of the parent compound – the
The IUPAC names given for the amines have the following structures.
b) (Cyclohexylmethyl) amine.
Interpretation:
The structure corresponding to the systematic name (Cyclohexylmethyl) amine.
Answer to Problem 48AP
The IUPAC names given for the amines have the following structures.
Explanation of Solution
The longest carbon chain containing the double bond to be chosen. Based on the name of the parent compound – the alkene name ends with the suffix –ene. The chain is to be numbered from the end that gives the lowest number to the carbon in double bond. Substituents are to be numbered according to their positions in the chain and listed alphabetically. The position of the double bond is indicated by giving the number of the first alkene carbon before the name of the parent name. If more than one double bond is present, their positions are indicated with the suffixes -diene, -triene and so on. The isomer that has similar groups on each carbon on the same side of the double bond is called as the cis isomer. The isomer that has similar groups on each carbon on the opposite side of the double bond is called as thetrans isomer.
The IUPAC names given for the amines have the following structures.
c) N-Methylcyclohexylamine
Interpretation:
The structure corresponding to the systematic name N-Methylcyclohexylamine.
Answer:
The IUPAC names given for the amines have the following structures.
Explanation:
The longest carbon chain containing the double bond to be chosen. Based on the name of the parent compound – the alkene name ends with the suffix –ene. The chain is to be numbered from the end that gives the lowest number to the carbon in double bond. Substituents are to be numbered according to their positions in the chain and listed alphabetically. The position of the double bond is indicated by giving the number of the first alkene carbon before the name of the parent name. If more than one double bond is present, their positions are indicated with the suffixes -diene, -triene and so on. The isomer that has similar groups on each carbon on the same side of the double bond is called as the cis isomer. The isomer that has similar groups on each carbon on the opposite side of the double bond is called as thetrans isomer.
Conclusion:
The IUPAC names given for the amines have the following structures.
Answer to Problem 48AP
The IUPAC names given for the amines have the following structures.
Explanation of Solution
The longest carbon chain containing the double bond to be chosen. Based on the name of the parent compound – the alkene name ends with the suffix –ene. The chain is to be numbered from the end that gives the lowest number to the carbon in double bond. Substituents are to be numbered according to their positions in the chain and listed alphabetically. The position of the double bond is indicated by giving the number of the first alkene carbon before the name of the parent name. If more than one double bond is present, their positions are indicated with the suffixes -diene, -triene and so on. The isomer that has similar groups on each carbon on the same side of the double bond is called as the cis isomer. The isomer that has similar groups on each carbon on the opposite side of the double bond is called as thetrans isomer.
The IUPAC names given for the amines have the following structures.
d) (2-Methylcyclohexyl) amine.
Interpretation:
The structure corresponding to the systematic name (2-Methylcyclohexyl) amine.
Answer to Problem 48AP
The IUPAC names given for the amines have the following structures.
Explanation of Solution
The longest carbon chain containing the double bond to be chosen. Based on the name of the parent compound – the alkene name ends with the suffix –ene. The chain is to be numbered from the end that gives the lowest number to the carbon in double bond. Substituents are to be numbered according to their positions in the chain and listed alphabetically. The position of the double bond is indicated by giving the number of the first alkene carbon before the name of the parent name. If more than one double bond is present, their positions are indicated with the suffixes -diene, -triene and so on. The isomer that has similar groups on each carbon on the same side of the double bond is called as the cis isomer. The isomer that has similar groups on each carbon on the opposite side of the double bond is called as thetrans isomer.
The IUPAC names given for the amines have the following structures.
e) 3-(N, N-Dimethylamino)propanoic acid.
Interpretation:
The structure corresponding to the systematic name 3-(N, N-Dimethylamino)propanoic acid.
Answer to Problem 48AP
The IUPAC names given for the amines have the following structures.
Explanation of Solution
The longest carbon chain containing the double bond to be chosen. Based on the name of the parent compound – the alkene name ends with the suffix –ene. The chain is to be numbered from the end that gives the lowest number to the carbon in double bond. Substituents are to be numbered according to their positions in the chain and listed alphabetically. The position of the double bond is indicated by giving the number of the first alkene carbon before the name of the parent name. If more than one double bond is present, their positions are indicated with the suffixes -diene, -triene and so on. The isomer that has similar groups on each carbon on the same side of the double bond is called as the cis isomer. The isomer that has similar groups on each carbon on the opposite side of the double bond is called as thetrans isomer.
The IUPAC names given for the amines have the following structures.
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Chapter 24 Solutions
Organic Chemistry
- Draw and name compounds that meet these descriptions:(a) Three different amides with the formula C5H11NO(b) Three different esters with the formula C6H12O2arrow_forward1. Draw structures corresponding to the following IUPAC names: (a) 4-Methylpentanoic acid (b) o-Hydroxybenzoic acid (c) 2,2-Dimethylpropanoyl chloride (d) trans-2-Methylcyclohexanecarboxamide (e) p-Methylbenzoic anhydride (f) p-Bromobenzonitrilearrow_forwardQuestion -S1arrow_forward
- (a) Draw the structures for the eight constitutional isomers of molecular formula C 4H 11N. (b) Give the systematic name for each amine. (c) Identify the chirality center present in one of the amines.arrow_forwardUsing the data in Appendix C, determine which of the following bases is strong enough to deprotonate acetonitrile (CH3CN), so that equilibrium favors the products: (a) NaH; (b) Na2CO3; (c) NaOH; (d) NaNH2; (e) NaHCO3.arrow_forwardBecause amines are basic, they can often accept a proton. Draw the protonated structure of n-propylamine.arrow_forward
- Compounds that contain an N-H group associate by hydrogen bonding. (a) Do you expect this association to be stronger or weaker than that of compounds containing an O-H group? (b) Based on your answer to part (a), which would you predict to have the higher boiling point, 1-butanol or 1-butanamine?arrow_forwardDetermine the IUPAC name of compound A and give the abbreviated (topological) structure of compound B:arrow_forwardWhich of the following is a tertiary amine? C) N-H CH₂ N-CH₂ H₂C b) NH₂ CH₂ CH₂ H₂CH N CH, d) H₂c-c CH, C-CH₂ CHarrow_forward
- Draw the structure of the following compounds which parent names have been traced to a common name; (a)5-methyl-4-nitroimidazole (b)2-chloro-4-methoxythiazole.arrow_forwardThere are eight primary amines with the molecular formula C5H13N . (a) Name and draw a structural formula for each amine. (b) Which of these amines are chiral?arrow_forwardGive the following amine an IUPAC name: CH;-N-CH3 CH3-CH-CH3 Name:arrow_forward
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning