Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Textbook Question
Chapter 24.9, Problem 20P
Draw an orbital picture of thiazole. Assume that both the nitrogen and sulfur atoms are sp2-hybridized, and show the orbitals that the lone pairs occupy.
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Chapter 24 Solutions
Organic Chemistry
Ch. 24.1 - Name the following compounds:Ch. 24.1 - Prob. 2PCh. 24.1 - Prob. 3PCh. 24.3 - Prob. 4PCh. 24.3 - The benzylammonium ion (C6H5CH2NH3+) has pKa =...Ch. 24.4 - Prob. 6PCh. 24.5 - Prob. 7PCh. 24.6 - Prob. 8PCh. 24.6 - Prob. 9PCh. 24.6 - Show two methods for the synthesis of dopamine, a...
Ch. 24.6 - Prob. 11PCh. 24.6 - Prob. 12PCh. 24.6 - Prob. 13PCh. 24.7 - Prob. 14PCh. 24.7 - Prob. 15PCh. 24.8 - Prob. 16PCh. 24.8 - Propose syntheses of the following compounds from...Ch. 24.8 - How would you prepare the following compounds from...Ch. 24.8 - Prob. 19PCh. 24.9 - Draw an orbital picture of thiazole. Assume that...Ch. 24.9 - Prob. 21PCh. 24.9 - Prob. 22PCh. 24.9 - Which nitrogen atom in the hallucinogenic indole...Ch. 24.9 - Prob. 24PCh. 24.10 - Prob. 25PCh. 24.SE - Name the following amines, and identify each as...Ch. 24.SE - The following compound contains three nitrogen...Ch. 24.SE - Name the following amine, including R, S...Ch. 24.SE - Prob. 29VCCh. 24.SE - Predict the product(s) for each reaction below and...Ch. 24.SE - Predict the product(s) and provide the complete...Ch. 24.SE - Prob. 32MPCh. 24.SE - Predict the product(s) and provide the mechanism...Ch. 24.SE - The diazotization of aniline first involves the...Ch. 24.SE - Prob. 35MPCh. 24.SE - Prob. 36MPCh. 24.SE - Prob. 37MPCh. 24.SE - Prob. 38MPCh. 24.SE - Choline, a component of the phospholipids in cell...Ch. 24.SE - Prob. 40MPCh. 24.SE - -Amino acids can be prepared by the Strecker...Ch. 24.SE - Prob. 42MPCh. 24.SE - Prob. 43MPCh. 24.SE - Prob. 44MPCh. 24.SE - Propose a mechanism for the following reaction:Ch. 24.SE - Prob. 46MPCh. 24.SE - Name the following compounds:Ch. 24.SE - Prob. 48APCh. 24.SE - Prob. 49APCh. 24.SE - Prob. 50APCh. 24.SE - Histamine, whose release in the body triggers...Ch. 24.SE - Prob. 52APCh. 24.SE - Prob. 53APCh. 24.SE - Prob. 54APCh. 24.SE - Prob. 55APCh. 24.SE - Prob. 56APCh. 24.SE - Prob. 57APCh. 24.SE - Prob. 58APCh. 24.SE - Prob. 59APCh. 24.SE - Prob. 60APCh. 24.SE - Show the products from reaction of p-bromoaniline...Ch. 24.SE - Prob. 62APCh. 24.SE - How would you prepare the following compounds from...Ch. 24.SE - Prob. 64APCh. 24.SE - Phenacetin, a substance formerly used in...Ch. 24.SE - Prob. 66APCh. 24.SE - Draw the structure of the amine that produced the...Ch. 24.SE - Fill in the missing reagents a-e in the following...Ch. 24.SE - Prob. 69APCh. 24.SE - Prob. 70APCh. 24.SE - Deduce the structure of the compound with formula...Ch. 24.SE - Prob. 72APCh. 24.SE - Prob. 73APCh. 24.SE - Prob. 74APCh. 24.SE - Prob. 75APCh. 24.SE - Prob. 76APCh. 24.SE - Propose a structure for the product with formula...Ch. 24.SE - Prob. 78APCh. 24.SE - Prob. 79APCh. 24.SE - Prob. 80APCh. 24.SE - Prob. 81APCh. 24.SE - Prob. 82APCh. 24.SE - Prob. 83APCh. 24.SE - Prob. 84AP
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- Draw electron configuration diagrams for carbon in an unhybridized, sp3 -hybridized state, sp2 -hybridized state, and sp-hybridized state.arrow_forwardWhich compound contains an sp2-hybridized carbon atom?arrow_forwardWhen looking at the hybridized orbital diagram, we can see which orbitals( and their electrons) will lead to sigma, pi and lone pair of electrons. Indicate where you would find each of the following :arrow_forward
- What are the hybridizations of the Carbons indicated by the arrows?arrow_forwardWhich of the following compounds contains the greatest number of sp2 hybridized carbon atoms?arrow_forwardSpecify the hybridization (sp, sp2, sp3, sp2d, sp3d, spd2 etc.) of the circled atoms in the structures below a. Hybridization of the circled carbon is _______________; of the circled nitrogen is b.Hybridization of the circled (C=O) oxygen is _____________; of the circled (C-N-C) nitrogen is ______________; of the circled sulfur is c.Hybridization of the circled carbon on the left of C≡C is _____________;of the circled (CH2) carbon is ______________; of the circled (Si=O) silicon is______________; of the circled (C=O) oxygen isarrow_forward
- Identify all of the carbon atoms that are sp2-hybridized in the following molecule:arrow_forward2,4-dimethy/-2,3-pentadiene has the following line diagram structure (with hydrogens drawn in). Explain with PICTURES of the sigma and pi bonds and with words why this molecule does not actually have a planar arrangement of methyl groups. Include an electron diagram of the hybridization of the central carbon atom.arrow_forwardWhat is the hybridization at each (sp, sp2, sp3) also find molecular geometry (bent, trigonal pyramidal, trigonal planar, terahedral) around the following atoms in N-methylacrylamide? a) C1 b) N c) C4arrow_forward
- How many unhybridized orbitals can you find in an sp2 carbon? How many hybridized orbitals can you find in an sp2 carbon?arrow_forwardThe nitrogen atom in diethylamine is —— hybridized and has a CNC bond angle of almost ——. A. sp3, 120 degrees B. sp3, 108 C. sp2, 120 D. sp2, 108 E. sp, 180arrow_forward1) Draw the schematic representation of the Nitrogen orbitals in pyridinearrow_forward
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