Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Question
Chapter 2.16, Problem 11P
Interpretation Introduction
Interpretation:
The structure and IUPAC names of all the
Concept introduction:
An alkyl group is a substituent that one hydrogen is missing from its corresponding
A primary alkyl group has a primary carbon atom at the potential point of attachment.
A secondary alkyl group has a secondary carbon atom at the potential point of attachment.
A tertiary alkyl group has a tertiary carbon atom at the potential point of attachment.
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1. (a) Draw the structures of the eight isomeric pentyl
alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol
system.
(c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl
alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and
a tertiary alcohol of the formula C,H13OH.
Draw all possible structure(s) and give the IUPAC systematic name(s) of an alkane or cycloalkane with the formula C8H18 that has only
primary hydrogen atoms.
Draw the structure(s).
Draw the line structures and give the names of the simplest straight chain alkenes (the double bond between C1 – C2) containing seven to twelve carbons.
Chapter 2 Solutions
Organic Chemistry - Standalone book
Ch. 2.4 - Prob. 1PCh. 2.7 - Prob. 2PCh. 2.8 - Identify the orbital overlaps of all of the bonds...Ch. 2.9 - The hydrocarbon shown, called vinylacetylene, is...Ch. 2.12 - Prob. 5PCh. 2.12 - Prob. 6PCh. 2.13 - Prob. 7PCh. 2.14 - Refer to Table 2.2 as needed to answer the...Ch. 2.15 - Prob. 9PCh. 2.15 - Prob. 10P
Ch. 2.16 - Prob. 11PCh. 2.17 - Prob. 12PCh. 2.18 - Prob. 13PCh. 2.20 - Prob. 14PCh. 2.21 - Match the boiling points with the appropriate...Ch. 2.22 - Write a balanced chemical equation for the...Ch. 2.22 - Using the data in Table 2.3, estimate the heat of...Ch. 2.22 - Prob. 18PCh. 2.22 - Prob. 19PCh. 2.23 - Prob. 20PCh. 2.23 - Which of the following reactions requires an...Ch. 2 - The general molecular formula for alkanes is...Ch. 2 - Prob. 23PCh. 2 - Prob. 24PCh. 2 - Prob. 25PCh. 2 - What is the hybridization of each carbon in...Ch. 2 - Prob. 27PCh. 2 - Does the overlap of two p orbitals in the fashion...Ch. 2 - Prob. 29PCh. 2 - Aphids secrete an alarm pheromone having the...Ch. 2 - All the parts of this problem refer to the alkane...Ch. 2 - Prob. 32PCh. 2 - Prob. 33PCh. 2 - Prob. 34PCh. 2 - From among the 18 constitutional isomers of C8H18,...Ch. 2 - Give the IUPAC name for each of the following...Ch. 2 - Using the method outlined in Section 2.16, give an...Ch. 2 - Prob. 38PCh. 2 - Write a balanced chemical equation for the...Ch. 2 - The heats of combustion of methane and butane are...Ch. 2 - In each of the following groups of compounds,...Ch. 2 - Given H for the reaction H2(g)+12O2(g)H2O(l)...Ch. 2 - Prob. 43PCh. 2 - Prob. 44PCh. 2 - Prob. 45PCh. 2 - Prob. 46PCh. 2 - Prob. 47PCh. 2 - Compound A undergoes the following reactions:...Ch. 2 - Prob. 49PCh. 2 - Some Biochemical Reactions of Alkanes Alkanes...Ch. 2 - Prob. 51DSPCh. 2 - Some Biochemical Reactions of Alkanes Alkanes...Ch. 2 - Prob. 53DSP
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- draw structural formulas for all isomeric alkanes with molecular formula C7H16. Predict which isomer has the lowest boiling point and which has the highest boiling point.arrow_forwardWrite a balanced equation for the incomplete combustion of each alkane: (a) CH 3CH 2CH 3; (b) CH 3CH 2CH 2CH 3.arrow_forward8. a) C3H$C1 has several structural isomers containing an alkene functional group. Complete the table by stating the systematic names and drawing the structural formulae of THREE structural isomers of C3H$Cl. Systematic Name Structural Formula b) A chemical test can be performed quickly in a school laboratory to distinguish between cyclohexanol and 1-methylcyclohexanol. Identify the reagent used in this test and describe the expected observations.arrow_forward
- (1) Write a complete chemical equation showing reactants, products, and catalysts needed (if any) for the following reaction and (2) Draw and name the organic compound found in every reaction. (a) Complete hydrogenation of 2-Methylhexa-1,5-diene (b) Complete halogenation (Br2) of 3-Ethyl-2,2-dimethylhept-3-ene (c) Reaction of (4E)-2.4-Dimethylhexa-1,4-diene with a mole of water (d) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr (e) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide (f) Formation of Gilman reagent using isopropyl bromide (g) Ozonolysis of 3,3-Dimethyloct-4-yne (h) Complete halogenation (Cl2) of 3-Ethyl-5-methyl-1,6,8-decatriyne (i) Partial hydrogenation using Lindlar's Catalyst 2,2,5,5-Tetramethylhex-3-yne (i) Reaction of 3.4-Dimethylcyclodecyne with sodium amidearrow_forwardGive the structures and IUPAC names of all constitutional isomers of C6H14. What is the structure of 3-ethyl-2,4,6-trimethyloctane? What is the structure of 3-ethyl-3-methylpentane?arrow_forwardWrite a complete chemical equation showing reactants, products, and catalysts needed (if any) for the following reaction and (2) Draw and name the organic compound found in every reaction.(Use condensed structural formula) (a) Complete hydrogenation of 2-Methylhexa-1,5-diene (b) Complete halogenation (Br2) of 3-Ethyl-2,2-dimethylhept-3-ene(c) Reaction of (4E)-2,4-Dimethylhexa-1,4-diene with a mole of waterarrow_forward
- Name and draw structural formulas for all alkenes with the molecular formula C5H10. As you draw these alkenes, remember that cis and trans isomers are different compounds and must be counted separatelyarrow_forwardWrite the balanced chemical equation for the complete combustion of ethane. Reactants Products C2H6 (g) + → Formulate (skeletal formula) the main products for the oxidation and dehydration reactions of the following compound: Reactant Oxidation product Dehydration products | OH CH3―CH2―CH―CH2―CH3arrow_forward(5c-201-5) Draw a skeleton structure and give the IUPAC name of a molecule with one alcohol group, 5 total carbons, and one methyl substituent group.arrow_forward
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