Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 2, Problem 28P
Does the overlap of two p orbitals in the fashion shown correspond to a
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Draw the valence bond diagram representing chemical bonding in the molecule of HCONH2 , showing atomic and hybridized orbitals as boxes, valence electrons as arrows in the boxes, and chemical bonds as lines connecting the boxes. Note that the lone pair on N occupies an unhybridized 2p orbital due to the contribution of resonance structure.
Harry creates a compound that contains only 1 pi (π) bond in total. The central atom has 4s2, 3d10, and 4p5. There are only 3 surrounding atoms with the electron configuration: 1s2 2s2 2p5. What is the formula and VSEPR shape for this compound? Explain how this is possible with respect to hybridized orbitals and how electrons are moved around to create this compound.
Identify the compound with the greatest number of σ bonds.
Chapter 2 Solutions
Organic Chemistry - Standalone book
Ch. 2.4 - Prob. 1PCh. 2.7 - Prob. 2PCh. 2.8 - Identify the orbital overlaps of all of the bonds...Ch. 2.9 - The hydrocarbon shown, called vinylacetylene, is...Ch. 2.12 - Prob. 5PCh. 2.12 - Prob. 6PCh. 2.13 - Prob. 7PCh. 2.14 - Refer to Table 2.2 as needed to answer the...Ch. 2.15 - Prob. 9PCh. 2.15 - Prob. 10P
Ch. 2.16 - Prob. 11PCh. 2.17 - Prob. 12PCh. 2.18 - Prob. 13PCh. 2.20 - Prob. 14PCh. 2.21 - Match the boiling points with the appropriate...Ch. 2.22 - Write a balanced chemical equation for the...Ch. 2.22 - Using the data in Table 2.3, estimate the heat of...Ch. 2.22 - Prob. 18PCh. 2.22 - Prob. 19PCh. 2.23 - Prob. 20PCh. 2.23 - Which of the following reactions requires an...Ch. 2 - The general molecular formula for alkanes is...Ch. 2 - Prob. 23PCh. 2 - Prob. 24PCh. 2 - Prob. 25PCh. 2 - What is the hybridization of each carbon in...Ch. 2 - Prob. 27PCh. 2 - Does the overlap of two p orbitals in the fashion...Ch. 2 - Prob. 29PCh. 2 - Aphids secrete an alarm pheromone having the...Ch. 2 - All the parts of this problem refer to the alkane...Ch. 2 - Prob. 32PCh. 2 - Prob. 33PCh. 2 - Prob. 34PCh. 2 - From among the 18 constitutional isomers of C8H18,...Ch. 2 - Give the IUPAC name for each of the following...Ch. 2 - Using the method outlined in Section 2.16, give an...Ch. 2 - Prob. 38PCh. 2 - Write a balanced chemical equation for the...Ch. 2 - The heats of combustion of methane and butane are...Ch. 2 - In each of the following groups of compounds,...Ch. 2 - Given H for the reaction H2(g)+12O2(g)H2O(l)...Ch. 2 - Prob. 43PCh. 2 - Prob. 44PCh. 2 - Prob. 45PCh. 2 - Prob. 46PCh. 2 - Prob. 47PCh. 2 - Compound A undergoes the following reactions:...Ch. 2 - Prob. 49PCh. 2 - Some Biochemical Reactions of Alkanes Alkanes...Ch. 2 - Prob. 51DSPCh. 2 - Some Biochemical Reactions of Alkanes Alkanes...Ch. 2 - Prob. 53DSP
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- Explain why a o bond formed by overlap of an s orbital with an sp orbital of carbon is stronger than a o bond formed by overlap of an s orbital with a p orbital of carbon. Because s orbital of carbon is more symmetrical than p orbital of carbon atom. The electron density of the large lobe of an sp orbital is less than the electron density of a lobe of a p orbital. Therefore, the overlap of an s orbital with an sp orbital forms a weaker bond than the overlap of an orbital with ap orbital. The electron density of the large lobe of an sp orbital is less than the electron density of a lobe of a p orbital. Therefore, the overlap of an s orbital with an sp3 orbital forms a stronger bond than the overlap of an s orbital with a p orbital. The electron density of the large lobe of an sp orbital is greater than the electron density of a lobe of ap orbital. Therefore, the overlap of an s orbital with an sp orbital forms a stronger bond than the overlap of an s orbital with ap orbital.arrow_forwardWhat orbitals are used to form each of the C–C and C – H bonds in CH3CH2CH3 (propane)? How many σ bonds are present in this molecule?arrow_forwardExplain why a σ bond formed by overlap of an s orbital with an sp3 orbital of carbon is stronger than a σ bond formed by overlap of an s orbital with a p orbital of carbon.arrow_forward
- Oxygenated hydrocarbons (compounds containing carbón, hydrogen, and oxygen) are common components of biofuels. The combustion of three isomers of C3H,0 (shown below) were studied to investigate the effects of structure on combustion speed and efficiency (Fuel 2010, 89, 2864-2872). Identify the number of sp3-hybridized carbon atoms in each of these isomers. Structure The number of sp3-hybridized carbon atoms (CH3)2CO HaCHOH CH3CH2CHOarrow_forwarda) Which atom is most likely to be protonated on the structure below? Explain. b) Which atomic/hybrid orbitals are combining to form the indicated bonds? H₂N OHarrow_forwardDetermine the hybridization state of each carbon atom in nemotin. HC ||| = C I с = ||| C T CH || C CH :0: CH :O: || с CH₂ CH₂arrow_forward
- According to valence bond theory, what is the total number of sp2 hybridized orbitals on all the atoms in formaldehyde, CH2O? Sketch and explain why. According to valence bond theory, how many lone pairs of electrons reside in sp hybridized orbitals in formaldehyde? explain why?arrow_forwardWhat orbital would the lone pair on the central oxygen of ozone (O3)be located?arrow_forwardIndicate what kind of bonding orbital is formed when the following atomic or hybridized atomic orbitals are combined as shown for each pair of orbitals described below. Please write out your answers using words (options: sigma, pi, or no bond formed). A: an sp3 orbital and an s orbital B: two pz orbitals in a side-to-side fashion C: two px orbitals in a head-to-head fashion D: a px orbital and a pz orbitalarrow_forward
- 2) a) Consider the following molecule . Given what you have learned about hybridization theory, draw an image or images explaining the bonding situation in this molecule. I want you to draw out all of the orbitals, hybrid orbitals and how they overlap to form the bonds in the molecule. Indicate the % s or p character in the given atomic and hybrid orbitals. Which C-C bond or bonds are the longest? In a paragraph or so explain the image or images you just drew. b) Lastly, consider the molecule below. Indicate the Molecular formula, the molar mass, label the hybridization of each atom except for hydrogen, indicate any chiral centers with a *, which bond or bonds are the shortest, identify by name of each functional group with an arrow pointing to the group.arrow_forwardExplain why a s bond formed by overlap of an s orbital with an sp3 orbital of carbon is stronger than a s bond formed by overlap of an s orbital with a p orbital of carbon.arrow_forwardWhat is the hybridization of the highlighted atoms in the following structure? What are your estimates for the bond angles around these highlighted atoms? in what kind of orbital does the lone pair of electrons on the nitrogen reside?arrow_forward
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