Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Write the general formula for an alkane, a cycloalkane, and a bicycloalkane. How do these general formulas differ?
When an alkane is composed of both a ring and a long chain, what determines whether a compound is named as an acyclic alkane or a cycloalkane?
Which among the following statements is FALSE about alkanes and cycloalkanes? Choices:All alkanes produce CO2 and water vapour upon complete combustion.Cyclic alkanes exhibit bond strain in the sp3-sp3 sigma bonds.Alkanes undergo substitution reactions.The empirical formula of all alkanes is CnH2n+2
Chapter 19 Solutions
Chemistry: An Atoms-Focused Approach
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- How does the structure of a cycloalkane differ from that of a straight-chain or branched-chain alkane?arrow_forwardIs the general formula of a cycloalkanes the same as the general formula of an alkane, CnH2n+2? Draw any structural diagram to illustrate your answer.arrow_forwardDistinguish between isomerism and resonance. Distinguish between structural and geometric isomerism. When writing the various structural isomers, the most difficult task is identifying which are different isomers and which are identical to a previously written structurethat is, which are compounds that differ only by the rotation of a carbon single bond. How do you distinguish between structural isomers and those that are identical? Alkenes and cycloalkanes are structural isomers of each other. Give an example of each using C4H8. Another common feature of alkenes and cycloalkanes is that both have restricted rotation about one or more bonds in the compound, so both can exhibit cis- trans isomerism. What is required for an alkene or cycloalkane to exhibit cis-trans isomerism? Explain the difference between cis and trans isomers. Alcohols and ethers are structural isomers of each other, as are aldehydes and ketones. Give an example of each to illustrate. Which functional group in Table 21-4 can be structural isomers of carboxylic acids? What is optical isomerism? What do you look for to determine whether an organic compound exhibits optical isomerism? 1-Bromo-1-chloroethane is optically active whereas 1-bromo-2-chloroethane is not optically active. Explain.arrow_forward
- Which of the following cycloalkanes could show geometric isomerism? For each that could, draw structural formulas, and name both the cis- and the trans- isomers. a. c. b. d.arrow_forwardWhat is the difference in bonding and in the general molecular formula between an alkene and an alkane with the same number of carbon atoms?arrow_forwardSummarize the nomenclature rules for alkanes, alkenes, alkynes, and aromatic compounds. Correct the following false statements regarding nomenclature of hydrocarbons. a. The root name for a hydrocarbon is based on the shortest continuous chain of carbon atoms. b. The suffix used to name all hydrocarbons is -ane. c. Substituent groups are numbered so as to give the largest numbers possible. d. No number is required to indicate the positions of double or triple bonds in alkenes and alkynes. e. Substituent groups get the lowest number possible in alkenes and alkynes. f. The ortho- term in aromatic hydrocarbons indicates the presence of two substituent groups bonded to carbon- 1 and carbon-3 in benzene.arrow_forward
- Write the molecular formula of each alkane.arrow_forwardWhen the molecular formulas for cyclic and noncyclic alkanes with the same number of carbon atoms are compared it is always found that the cycloalkane has?arrow_forwardAlkenes and alkynes react similarly to each other. Hydrogenation, halogenation, and hydration reactions are all types of addition reactions in which the reagent adds across the multiple bond of the reactant • Hydrogenation is the addition of hydrogen gas in the presence of a catalyst such as platinum, palladium, or nickel. • Halogenation involves a reaction with a halogen such as Cl₂ or Br₂ to produce a dihaloalkane or dihaloalkene product. Hydration reactions take place when alkenes or alkynes react with water in the presence of a strong acid catalyst to yield an alcohol. ▼ Part A Predict the product of the reaction of 1-butene with bromine. Enter the IUPAC name. ▸ View Available Hint(s) Submit ▾ Part B An alkyne undergoes hydrogenation to produce an alkane as follows: 04 RC=CR + 2H₂ Q Pd catalyst alkane Predict the product and draw it. Draw the molecule by placing atoms on the grid and connecting them with bonds. Include all hydrogen atoms. To add an R group, double click an while…arrow_forward
- Draw and name the five cycloalkane structures of formula C5H10. Can any of these structures give rise to geometric (cis-trans) isomerism? If so, show the cis and trans stereoisomersarrow_forwardHalogenoalkanes undergo two different types of reaction, substitution and elimination reactions depending on the conditions. Use the reaction between 2-bromopropane and sodium hydroxide to explain the chemical reactions of haloalkanes. You must include the following in your explanation: Describe what change is taking place to the halogenoalkane and the product(s) formed. The reaction equations The conditions under which the reactions occur.arrow_forwardPetroleum products such as kerosene and gasoline are separated using fractional distillation. Each of them has their own properties and usage. Why can't we use one petroleum product as a substitute for the other when they are composed majority of alkanes?arrow_forward
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