Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Which would you expect to have the higher boiling point, the hydrocarbon fuel butane, C4H10, or the organic solvent acetone. (CH3)2CO?
Which of the following would be expected to have the lowest vapor pressure at room temperature?
ethanol, bp = 78°C
methanol, bp = 65°C
water, bp = 100°C
acetone, bp = 56°C
Based on the type or types of intermolecular forces, predictthe substance in each pair that has the higher boiling point:(a) propane (C3H8) or n-butane (C4H10), (b) diethyl ether(CH3CH2OCH2CH3) or 1-butanol (CH3CH2CH2CH2OH),(c) sulfur dioxide (SO2) or sulfur trioxide (SO3), (d) phosgene(Cl2CO) or formaldehyde (H2CO).
Chapter 19 Solutions
Chemistry: An Atoms-Focused Approach
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- 5-106 The normal boiling point of hexane, C6H14, is 69°C, and that of pentane, C5H12, is 36°C. Predict which of these compounds has a higher vapor pressure at 20°C.arrow_forwardOn the basis of intermolecular attractions, explain the differences in the boiling points of n butane (1 C) and chloroethane (12 C), which have similar molar masses.arrow_forwardSilane SiH4, phosphine (PH3), and hydrogen sulfide (H2S) melt at 185 C, 133 C, and 85 C, respectively. What does this suggest about the polar character and intermolecular attractions of the three compounds?arrow_forward
- 5-86 Using the phase diagram of water (Figure 5-20), describe the process by which you can sublime 1 g of ice at-10°C and at 1 atm pressure to water vapor at the same temperature.arrow_forwardIn each of the following groups of substances, pick the one that has the given property. Justify your answer. a. highest boiling point: HBr, Kr, or Cl2 b. highest freezing point: H2O, NaCl, or HF c. lowest vapor pressure at 25C: Cl2, Br2, or I2 d. lowest freezing point: N2, CO, or CO2 e. lowest boiling point: CH4, CH3CH3, or CH3CH2CH3 f. highest boiling point: HF, HCl, or HBr g.arrow_forwardFor each of the following pairs, choose the member with the lower boiling point. Explain your reason in each case. (a) NaCl or PCl3 (b) NH3 or AsH3 (c) C3H7OH or C2H5OCH3 (d) HI(g) or HCl(g)arrow_forward
- (a) How do the structures of these molecules account for these differences in boiling point? Provide a full account of the structures and their influence on the differences in this physical property. Name Boiling Point methane -161.6 °C methanol 64.7 °C propane -42 °C propan-1-ol 97 °Carrow_forwardThe boiling points of noble gases (Groups 8A elements) increase going from top to bottom of the column. True or False?arrow_forward3) Which of the following compounds has the higher boiling point Justify your answer. INclude drawings where appropriate. CHICHỊCH CENT CH3 11 CH₂ CN(CH₂)₂arrow_forward
- Which compound has a higher boiling point: butane, C4 H10, or hexane, C6H4?arrow_forwardThe following compounds, represented with ball-and-stick models, have the same molecular formulas (C5H12). Which would you expect to have a higher boiling point? Select the single best answer. ×arrow_forwardWhich one of the following compounds has the highest boiling point? I II III IV V IV O H OH || V ||| OHarrow_forward
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