Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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of the following molecules could be considered aromatic? Assume all of the compounds are planar.
T: Are these proper Lewis structures?
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NH₂
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Determine if the following compounds are aromatic, non-aromatic, or anti-aromatic. Show a structure that helps to support your classification. This structure should not just redraw the compound; show lone pairs, resonance, and/or contributing π bonds as part of your explanation.
1. Which of the following structures is considered aromatic?
Chapter 19 Solutions
Chemistry: An Atoms-Focused Approach
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- Which of the following molecules could be considered aromatic? Assume all of the compounds are planar. ^ N H₂ Cyclopentadiene is especially acidic for a hydrocarbon. Use a diagram to explain why.arrow_forward3. What are the factors that confer Aromaticity to an organic molecule?arrow_forward3. Justify aromaticity (or lack thereof) in the biological molecules below. H2N NH2 H H `NH2 `NH2 N- NH N. `NH ADP ADP N. `NH2 H ОН ОН ОН ОН adenine guanine cytosine thymine NAD+ NADH H OH H3C. H3C. CH30. CH30 10 10 H3C 'N' N. H3C N. CH30 CH30 N' CH2 OH CH2 H H-C-OH H -OH- ubiquinone ubiquinol H-C-OH H- -он Н-С—он H Ċ-OH CH2 CH2 ADP ADP FAD FADH2arrow_forward
- Biphenyl has the following structure.(a) Is biphenyl a (fused) polynuclear aromatic hydrocarbon?(b) How many pi electrons are there in the two aromatic rings of biphenyl? How does this number compare with that for naphthalene?arrow_forward6. (Chapter 15-Q37) Indole is an aromatic heterocyclic that has a benzene ring fused to a pyrrole ring. Answer the following questions. Indole 6(a) What is the hybridization of N in this molecule? = 6(b) How many pi electrons N contributes to the ring? = 6() Which orbitals contribute to form a sigma bond between N and H in this molecule? = 6(c) What is the electronic relationship of Indole to naphthalene? Give the answer by comparing number of rings and number of pi electrons in both compounds, write x rings, y pi electrons=|arrow_forwardRefer to the attached picture for the following questions Which aromatic structures contain functional groups which are electron-donating?In which structure do you expect two products after alkylation?arrow_forward
- How many resonant structures can be written for each of the following aromatic hydrocarbons? (a) Anthracene, (b) Phenanthrene, (c) Naphthacenearrow_forwardWhat is Resonance Theory? Sate five conclusions that can be drawn from the theory. State the two main experiments that were used to establish the extra stability of the benzene molecule. What are the factors that confer Aromaticity to an organic molecule? i. State the effects of substituents on a benzene derivative towards further aromatic substitution. Based on the above suggest the various types of substituents that can be attached to Benzene. What are the various ways by which alkenes may be synthesized? i. Give two examples each of Unsymmetrical alkenes and reagents. Give two examples of reactions of alkenes that result in Anti-Markonikov’s addition productsarrow_forward2) which are of the following are ions aromatic Species? DO AQarrow_forward
- Which of the following compounds is NOT an aromatic molecule? S. IZarrow_forwardRefer to the attached picture for the following questions Which among the five aromatic molecules will have the least ability to undergo molecular stacking?Which aromatic structures contain functional groups which are electron-withdrawing?arrow_forwardமத்தம் Which of the following ions is aromatic?arrow_forward
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